Product ID:ALUMINUM REFERENCE STANDARD SOLUTION, SA-442
MSDS Date:10/06/1989
FSC:6810
NIIN:00N015365
MSDS Number: CDWDQ

FISHER SCIENTIFIC

1 REAGENT LN
FAIR LAWN, NJ 07410
US

Emergency Phone: 201-796-7100

Info Phone: 201-796-7100

Cage: 1B464

FISHER SCIENTIFIC CO. CHEMICAL MFG DIV

FAIRLAWN, NJ 07410-2802 US

Telephone: 201-796-7100

Cage: 1B464

CONCS OF ALUMINUM IN ORGANS. FOR EXAMPLE,

RTECS: 9999999ZZ

WASH IMMED W/LG

RTECS: 9999999ZZ

NO EVID OF CHEM REMAINS (AT LST 15-20 MIN).

RTECS: 9999999ZZ

(30-60 MIN). COVER W/STERILE BANDAGES. GET MED ATTN

RTECS: 9999999ZZ

DILUTE ACID IMMED BY DRINKING LG QTYS OF WATER/MILK.

RTECS: 9999999ZZ

MUST BE DILUTED APPROX 100 FOLD TO RENDER IT

RTECS: 9999999ZZ

ATTN IMMED. IF VOMIT OCCURS, KEEP HEAD BELOW HIPS TO

RTECS: 9999999ZZ

DISP. KEEP UNNEC PEOPLE AWAY. ISOLATE AREA; DENY

RTECS: 9999999ZZ

& FULL LENGTH FACESHIELD .

RTECS: 9999999ZZ

WATER

CAS: 7732-18-5

RTECS: ZC0110000

Fraction By Weight: 95.1%

OSHA PEL N/K

ACGIH TLV: N/K

MAY CAUSE SEV IRRIT, INFLAM, ULCERATION, NECROSIS &

RTECS: 9999999ZZ

COLLAPSE. PHOTOSENSIT RXNS POSS. CNTCT W/COMPRESSED

RTECS: 9999999ZZ

RETINA USUALLY NONIRRIT & DISAPPEAR IN 2 OR 3 YRS

RTECS: 9999999ZZ

CNTCT

RTECS: 9999999ZZ

W/IMPAIRMENT/PERM VISION LOSS. DROP SPLASHED IN EYE &

RTECS: 9999999ZZ

& CONJ EPITHELIUM. CNTCT W/COMPRESSED GAS MAY CAUSE

RTECS: 9999999ZZ

TOX. MASSIVE DOSES MAY CAUSE GI IRRIT & MAY BE TOX.

RTECS: 9999999ZZ

STOM W/CONSEQUENT PAIN, UNEASINESS, NAUS,

RTECS: 9999999ZZ

ALSO NEPHRITIS, FEVER & PERFORATION OF INTESTINAL

RTECS: 9999999ZZ

ING

RTECS: 9999999ZZ

ING

RTECS: 9999999ZZ

CONJ OR EFTS SIMILAR TO

RTECS: 9999999ZZ

MAY INTERFERE W/INTESTINAL ABSORPTION OF PHOSPHATES

RTECS: 9999999ZZ

ALUMINUM; (ALUMINUM METAL (ALUMINUM OTHER THAN POWDER))

CAS: 7429-90-5

RTECS: BD0330000

Fraction By Weight: 0.11%

OSHA PEL 15 MG/M3 DUST

ACGIH TLV: 10 MG/M3 DUST

HYDROCHLORIC ACID (SARA 302/313) (CERCLA)

CAS: 7647-01-0

RTECS: MW4025000

Fraction By Weight: 4.8%

OSHA PEL 5 PPM, C

ACGIH TLV: 5 PPM, C

EPA Report Quantity: 5000 LBS

DOT Report Quantity: 5000 LBS

LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:ACUTE: INHAL:ING 1:EFTS IF
DUST/PWDR/FUME FORMS. ING 2:GAS/FUMES @ 5-35PPM MAY CAUSE IRRIT &
BURNING OF THROAT, COUGH & CHOKING; 50-100PPM MAY BE BARELY
TOLERABLE FOR 1 HR. HIGH LEVELS MAY CAUSE INFLA M & OCCASNLY
ULCERATION OF NOSE, THROATOR LARYNX, BRONCH, PNEUM, PALPITATIONS &
HDCH. HIGHER CONCS (EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT
Effects of Overexposure:HLTH HAZ: MAY CAUSE NECROSIS OF TRACHEAL &
BRONCH EPITHELIUM, NASOSEPTAL PERFORATION, ATELECTASIS, EMPHYSEMA,
DMG TO PULM BLOOD VESSELS & LESIONS OF LIVER & OTHER ORGANS. DEATH
MAY BE DUE TO LARYNGEAL SPASM, BRONCHOPNEUM OR PULM EDEMA.
1300-2000PPM MAY BE DANGEROUS EVEN ON BRIEF EXPOS. RPTS OF REPRO
EFTS IN (SUPDAT)
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.

First Aid:INHAL:REMOVE TO FRESH AIR. IF BRTHG STOPS GIVE ARTF RESP.
MAINTAIN AIRWAY & BLOOD PRESS & ADMIN O*2 (BY QUALIFED PERS). KEEP
WARM & AT REST. TREAT SYMP & SUPPORTIVELY. GET MED ATTN.
SKIN:REMOVE CONTAM D CLTHG & SHOES IMMED. WASH AREA W/SOAP& LG AMTS
OF WATER UNTIL NO EVID OF CHEM REMAINS (AT LST 15-20 MIN). IN CASE
OF CHEM BURNS, COVER AREA W/STERILE DRESSING. BANDAGE SECURELY BUT
NOT TOO (ING 18)

Flash Point:NONFLAMMABLE
Extinguishing Media:DRY CHEM, CARBON DIOXIDE, HALON, WATER SPRAY OR
STANDARD FOAM. FOR LARGER FIRES USE WATER SPRAY, FOG OR STANDARD
FOAM.
Fire Fighting Procedures:NIOSH APPRVD SCBA & FULL PROT EQUIP . MOVE
CNTNRS FROM AREA IF POSS. COOL CNTNRS EXPOS TO FLAMES W/WATER FROM
SIDE UNTIL WELL AFTER FIRE IS OUT. (SUPDAT)
Unusual Fire/Explosion Hazard:NEGLIGIBLE FIRE HAZARD WHEN EXPOSED TO
HEAT OR FLAME.

Spill Release Procedures:DO NOT TOUCH SPILL MATL. STOP LEAK IF W/OUT
RISK. SM SPILL:TAKE UP W/ABSORB & PLACE INTO CNTNRS FOR DISP. SM
DRY SPILL:W/CLEAN SHOVEL PLACE MATL INTO CLEAN, DRY CNTNR & COVER.
MOVE CNTNRS FROM AREA. L G SPILLS:DIKE FAR AHEAD OF SPILL FOR
LATER(ING 24)
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

Handling and Storage Precautions:NONE SPECIFIED BY MANUFACTURER.
Other Precautions:MAY BURN BUT DOES NOT IGNITE READILY. FLAMMABLE,
POISONOUS GASES MAY ACCUMULATE IN TANKS AND HOPPER CARS. MAY IGNITE
COMBUSTIBLES (WOOD, PAPER, OIL, ETC).

Respiratory Protection:SPECIFIC RESPIRATOR SELECTED MUST BE BASED ON
CONTAM LEVELS FOUND IN WORK PLACE, MUST NOT EXCEED WORKING LIMITS
OF RESPIRATOR AND BE NIOSH APPROVED. FOR A LIST OF SPECIFIC
RESPIRATORS CONTACT NEHC (FP N).
Ventilation:PROVIDE LOCAL EXHAUST OR PROCESS ENCLOSURE VENTILATION TO
MEET PUBLISHED EXPOSURE LIMITS.
Protective Gloves:IMPERVIOUS GLOVES .
Eye Protection:ANSI APPRVD CHEM WORKERS GOGGS (ING 25)
Other Protective Equipment:ANSI APPROVED EYE WASH & DELUGE SHOWER .
WEAR APPROPRIATE PROTECTIVE (IMPERVIOUS) CLOTHING & EQUIPMENT.
Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health
FIRE FIGHT PROC: STAY AWAY FROM STOR TANK ENDS. EXTING USING AGENTS
INDICATED; DO NOT USE WATER DIRECTLY ON MATL. EFTS OF OVEREXP:
ANIMALS. SKIN: ING 1:SLIVER PENETRATING SKIN MAY FORM ALUMINIM
SALTS WHICH INDUCE LOC IRRIT & POSS SECONDARYINFECTIONS. CNTCT
W/ROUGH/SHARP EDGES MAY CAUSE CUTS/ABRASIONS. ING 2: (ING 4)

Boiling Pt:B.P. Text:212F,100C
Melt/Freeze Pt:M.P/F.P Text:32.0F,0.0C
Vapor Pres:14 @ 20C
Vapor Density:0.7
Spec Gravity:1.0
pH:ACIDIC
Evaporation Rate & Reference:>1 (ETHER =1)
Solubility in Water:SOLUBLE
Appearance and Odor:COLORLESS LIQUID.

Stability Indicator/Materials to Avoid:YES
BARIUM SULFATE, CHLORATES, METALS, OXIDIZERS (STRONG). FOR A COMPLETE
LIST OF MATLS TO AVOID CNTCT NEHC .
Stability Condition to Avoid:STABLE UNDER NORMAL TEMPERATURES AND
PRESSURES.
Hazardous Decomposition Products:THERMAL DECOMPOSITION PRODUCTS MAY
INCLUDE TOXIC AND CORROSIVE FUMES OF HYDROGEN CHLORIDE.

Waste Disposal Methods:DISPOSAL MUST BE IN ACCORDANCE WITH FEDERAL,
STATE AND LOCAL REGULATIONS .

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.