Product ID:JN101U
MSDS Date:03/11/1993
FSC:8010
NIIN:00N047785
MSDS Number: CDWHX

INTERNATIONAL PAINT POWDER COATINGS, INC

6003 ANTOINE DR
HOUSTON, TX 77091
US

Emergency Phone: 713-682-1711

Info Phone: 713-682-1711

Cage: 0TZS5

INTERNATIONAL PAINT INC

HOUSTON, TX 77091 US

Telephone: 713-684-1244

Cage: 0TZS5

HAVE RECENTLY BEEN REPORTED FROM MOUSE

RTECS: 9999999ZZ

EXPOS CONCS OF 2.5, 10.0 & 50.0 MG/M3. THESE RSLTS

RTECS: 9999999ZZ

RESPONSE (DMG & SUBSEQUENT DEATH OF CELLS),

RTECS: 9999999ZZ

SUGGEST FREQUENCY OF CHROMOSOMAL ABERRATIONS

RTECS: 9999999ZZ

BACKGROUND FREQUENCY IN THIS STUDY. GENERIC POWDER

RTECS: 9999999ZZ

SINGLE EXPOS LC50 OF > 11,600 MG/M3, MAX ATTAINABLE

RTECS: 9999999ZZ

DETERMINED TO BE > 1700 MG/M3, HIGHEST CONC TESTED.

RTECS: 9999999ZZ

SCREEN OF GENERIC POWDER COATING CONTAINING 9% TGIC

RTECS: 9999999ZZ

CHROMOSOMAL ABERRATIONS (GENETIC DMG) AT 800 MG/KG

RTECS: 9999999ZZ

RESPONSE TREND (IE, AS DOSE INCRD, FREQUENCY OF

RTECS: 9999999ZZ

TGIC POWDER ORAL STUDY. HOWEVER, WHEN OVERALL STUDY

RTECS: 9999999ZZ

DOSE RESPONSE TREND WAS OBSERVED IN 4.8% TGIC STUDY

RTECS: 9999999ZZ

DOSE-DEPENDENT TESTICULAR CYTOTOX RESPONSE (DMG &

RTECS: 9999999ZZ

POWDER COATINGS FORMULATED W/4.8% & 9% TGIC. FOR

RTECS: 9999999ZZ

S-TRIAZINE-2,4,6(1H,3H,5H)-TRIONE,

CAS: 2451-62-9

RTECS: XZ1994900

Fraction By Weight: <5%

OSHA PEL N/K

ACGIH TLV: N/K

CARBON BLACK

CAS: 1333-86-4

RTECS: FF5800000

Fraction By Weight: <5%

OSHA PEL 3.5 MG/M3

ACGIH TLV: 3.5 MG/M3

CALCIUM CARBONATE

CAS: 1317-65-3

RTECS: EV9580000

Fraction By Weight: <30%

OSHA PEL 15 MG/M3 TDUST

ACGIH TLV: 10 MG/M3 TDUST

2H-AZEPIN-2-ONE, HEXAHYDRO-; (CAPROLACTAM) (CERCLA)

CAS: 105-60-2

RTECS: CM3675000

Fraction By Weight: <5%

OSHA PEL N/K

ACGIH TLV: 1MG/M3 DUST/5 VAP

EPA Report Quantity: 1 LB

DOT Report Quantity: 1 LB

LIMITS SPECIFIED, & B) REMOVE VOLATILES PRDCED DURING

RTECS: 9999999ZZ

ON SURFACES COATED WITH THIS PRODUCT.

RTECS: 9999999ZZ

MALE MICE, LC50 (MEDIAN LETHAL CONC WHICH RSLTS IN

RTECS: 9999999ZZ

MG/M3. WHEN EXPOS WAS SPREAD > 5 DAYS, 6 HRS/DAY,

RTECS: 9999999ZZ

AMES

RTECS: 9999999ZZ

IN MOUSE SPERMATOGONIA (ORAL DOSING); & DOMINANT

RTECS: 9999999ZZ

SHOWN TO BE A SENSITIZER IN GUINEA PIG MAXIMIZATION

RTECS: 9999999ZZ

LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:YES OSHA:NO
Health Hazards Acute and Chronic:ACUTE: EYES: POWDER MAY CAUSE IRRIT.
SKIN: IRRIT MAY OCCUR IN SUSCEPTIBLE INDIVIDUALS. TOX IF ABSORBED
THRU SKIN. INHAL: POWDER MAY CAUSE IRRIT OF RESP TRACT & NOSEBLEEDS
IN SUSCEPTIBLE INDIVIDUALS. R PTD INHAL IN EXCESS OF TLV/PEL OVER
EXTENDED PERIOD OF TIME MAY RSLT IN INJURY TO RESP SYS. (EFFECTS OF
OVEREXPOSURE)
Explanation of Carcinogenicity:CARBON BLACK: IARC MONO ON EVAL OF
CARCIN RISK OF CHEMS TO MAN, VOL 65, PG 24-27, 1995: GROUP 2B.
ANIMAL: LUNG.
Effects of Overexposure:HLTH HAZ: INGEST: POWDER MAY CAUSE GI IRRIT.
TGIC IS TOX BY INGEST & IF ABSORBED THRU SKIN & HAS TESTED POS IN
SOME MUTAGENICITY TESTS. ANIMAL STUDIES W/TGIC SHOW THAT OVEREXP
CAN RSLT IN TOX EFTS TO TESTES, POSS EFTS ON LIVER & LUNGS & POSS
MALE REPRO EFTS. POWDER COATINGS MANUFACTURED FROM TGIC HAVE TESTED
(SUP DAT)
Medical Cond Aggravated by Exposure:PREEXISTING EYE, SKIN OR
RESPIRATORY DISORDERS.

First Aid:EYES: FLUSH IMMEDIATELY W/PLENTY OF WATER FOR AT LEAST 15
MINUTES & GET MEDICAL ATTENTION IMMEDIATELY. SKIN: REMOVE
CONTAMINATED CLOTHING. WASH SKIN W/PLENTY OF SOAP & WATER. LAUNDER
CLOTHES BEFORE RE USE. IF IRRITATION PERSISTS GET MEDICALATTENTION.
INHAL: REMOVE TO FRESH AIR. IF DISCOMFORT IS PRESENT/BREATHING IS
ABSENT, GET MEDICAL ATTENTION IMMEDIATELY. INGEST: CALL MD
IMMEDIATELY .

Extinguishing Media:CARBON DIOXIDE, DRY CHEMICAL, FOAM OR WATER FOG.
Fire Fighting Procedures:WEAR NIOSH APPROVED SCBA & FULL PROTECTIVE
EQUIPMENT . DO NOT ALLOW POWDER TO BE DISPERSED INTO THE AIR WHILE
EXTINGUISHING.
Unusual Fire/Explosion Hazard:COMBUSTIBLE DUST. WHEN SUSPENDED IN AIR
AS A DUST CLOUD, THIS PRODUCT IS A POTENTIAL FIRE & EXPLOSION
HAZARD. DECOMPOSITION & COMBUSTION PRODUCTS MAY BE TOXIC.

Spill Release Procedures:REMOVE ALL SOURCES OF IGNITION. AVOID
INHALATION OF DUST OR VAPORS FROM HEATED PRODUCT. VENTILATE AREA.
USE EXPLOSION-PROOF VACUUM EQUIPMENT FOR CLEAN UP.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

Handling and Storage Precautions:AVOID SKIN & EYE CONT. AVOID BRTHG
DUST/VAP FROM HEATED PROD DURING CURE, CUTTING OPERATIONS/DURING
BURNOFF.
Other Precautions:DO NOT USE NEAR SPKS, FLAMES/ANY OTHER IGNIT SOURCE.
DUST CLOUDS ARE A POTENTIAL FIRE & EXPLO HAZ. GROUND ALL EQUIP TO
PVNT BUILDUP OF STATIC ELEC. SINCE REMOVAL OF SHRINK WRAPPINGS FROM
CONTRS CAN GE NERATE SPKS OF STATIC ELEC, (SUP DAT)

Respiratory Protection:USE A RESPIRATOR APPROVED BY NIOSH AND IN
ACCORDANCE WITH 29CFR 1910.134 TO REMOVE PARTICULATES (AND VAPORS
IF THERE IS OVEREXPOSURE TO VAPORS GENERATED DURING THE PROCESSING
OF THIS PRODUCT).
Ventilation:PROVIDE SUFFICIENT VENT, IN VOL & PATTERN, TO A) KEEP TLV
OF HAZ INGS & LEL OF POWDER COATING ITSELF BELOW THE (ING 5)
Protective Gloves:CHEMICAL RESISTANT GLOVES.
Eye Protection:ANSI APPRVD CHEM WORKERS GOGGLES .
Other Protective Equipment:EMERGENCY EYEWASH AND DELUGE SHOWER MEETING
ANSI DESIGN CRITERIA . WEAR COVERALLS AND HEAD PROTECTION.
Work Hygienic Practices:REMOVE AND WASH SOILED CLOTHING BEFORE REUSE.
WASH HANDS BEFORE EATING, SMOKING, OR USING THE RESTROOM.
Supplemental Safety and Health
OTHER PREC: ENSURE SUCH OPERATIONS ARE CARRIED OUT IN SAFE AREA & IN
SAFE MANNER. GROUNDING & BONDING CONTRS IS REC WHEN TRANSFERRING
POWDERS TO AVOID STATIC CHARGE BUILDUP. EFTS OF OVEREXP: NEG IN SO
ME MUTAGENICITY TESTS BUT POS IN OTHERS. IN A 4 HR SINGLE EXPOS
INHAL TEST OF TRIGLYCIDYL ISOCYANURATE (TGIC) IN (ING 7)

Spec Gravity:>1.2
Evaporation Rate & Reference:SLOWER THAN ETHER
Appearance and Odor:FINE DRY POWDER

Stability Indicator/Materials to Avoid:YES
OXIDIZING AGENTS.
Stability Condition to Avoid:SPARKS, OPEN FLAME, HOT SURFACES, AND ALL
SOURCES OF HEAT AND IGNITION.
Hazardous Decomposition Products:CARBON MONOXIDE, CARBON DIOXIDE,
VARIOUS HYDROCARBON FRAGMENTS, CAPROLACTAM, HYDROGEN CYANIDE,
ISOCYANATES.

Waste Disposal Methods:DISPOSE IN ACCORDANCE WITH LOCAL, STATE AND
FEDERAL REGULATIONS. DO NOT INCINERATE UNOPENED CONTAINERS.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.