Product ID:DEICER WASHER FLUID, 2033-69
MSDS Date:09/22/1995
FSC:6850
NIIN:00N073233
MSDS Number: CDWTZ

PRESTONE PRODUCTS CORP

39 OLD RIDGEBURY RD
DANBURY, CT 06810-5109
US

Emergency Phone: 800-424-9300(CHEMTREC)

Info Phone: 203-830-7800

Preparer: JAMES OTTOWITZ

Cage: EO340

PRESTONE PRODUCTS CORPORATION

DANBURY, CT 06810 US

Telephone: 203-830-7865

Cage: EO340

3.2%

CAS: 67-56-1

RTECS: PC1400000

Fraction By Weight: 30-40%

OSHA PEL S, 200 PPM

ACGIH TLV: S,200PPM/250STEL; 95

EPA Report Quantity: 5000 LBS

DOT Report Quantity: 5000 LBS

36% LD50 (ORAL,

CAS: 107-21-1

RTECS: KW2975000

Fraction By Weight: 1-10%

OSHA PEL N/K

ACGIH TLV: C 50 PPM,VAPOR; 9495

EPA Report Quantity: 1 LB

DOT Report Quantity: 1 LB

NON-HAZARDOUS INGREDIENTS

Fraction By Weight: >1%

OSHA PEL N/K

ACGIH TLV: N/K

WATER

CAS: 7732-18-5

RTECS: ZC0110000

Fraction By Weight: 50-70%

OSHA PEL N/K

ACGIH TLV: N/K

PERCEPTION, REDUCTION OF VISUAL FIELDS &

RTECS: 9999999ZZ

KIDNEY & HEART MUSCLE INJURY HAVE BEEN DESCRIBED.

RTECS: 9999999ZZ

METHANOL & THE ONSET OF SYMPS. SEV KIDNEY DMG FOLLOWS

RTECS: 9999999ZZ

LONG TERM RPTD OVEREXP TO METHANOL VAP CONCS OF 3000

RTECS: 9999999ZZ

CUMULATIVE EFT TO OCCUR W/RSLT NAUS, VOMIT, HDCH,

RTECS: 9999999ZZ

GAIT, VERTIGO, & CLOUDED & DOUBLE VISION. PRLNG

RTECS: 9999999ZZ

EYE DMG IN SOME PERS. COMPONENTS OF THIS PROD ARE

RTECS: 9999999ZZ

ANIMAL STUDIES SUGGEST

RTECS: 9999999ZZ

IF IRRITAT, PAIN, SWELL/TEARING PERSISTS,

RTECS: 9999999ZZ

H*2O & INDUCE VOMIT. NEVER GIVE ANYTHING BY MOUTH TO

RTECS: 9999999ZZ

ROOM FOR ASSISTANCE & INSTRUCTIONS ON INDUCING VOMIT

RTECS: 9999999ZZ

COMBINATION OF VISUAL DISTURBANCE, METABOLIC

RTECS: 9999999ZZ

POISONING. THE PRINCIPAL TOX EFTS OF ETHYLENE GLYCOL

RTECS: 9999999ZZ

ETHANOL IS ANTIDOTAL, & ITS EARLY ADMIN MAY BLOCK

RTECS: 9999999ZZ

ETHYLENE GLYCOL. HEMODIALYSIS IS HIGHLY EFFECTIVE AT

RTECS: 9999999ZZ

METABOLITIES, AND MAY BE INDICATED DEPENDING UPON

RTECS: 9999999ZZ

FOUND IN THE WORK PLACE, MUST BE BASED ON

RTECS: 9999999ZZ

(NIOSH). A SUPPLIED AIR RESPIR W/FULL FACEPIECE

RTECS: 9999999ZZ

ORGANIC VAP CARTRIDGE RESPS ARE NOT REC FOR METHANOL

RTECS: 9999999ZZ

TO LIFE OR HEALTH CONDITIONS INCLUDING ALL

RTECS: 9999999ZZ

PRESSURE-DEMAND OR OTHER POSITIVE PRESSURE MODE.

RTECS: 9999999ZZ

LD50 LC50 Mixture:SEE INGREDIENTS
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:EMER OVERVIEW: FLAMM LIQ! EYE IRRIT.
INHAL MAY CAUSE HDCH, DIZZ, DROWS, NAUS, VISUAL IMPAIRMENT, NARCOS
& UNCONSCIOUSNESS. POISONOUS IF SWALLOWED. ACUTE:NO ACUTE TOX ETS
EXPECTED WHEN PROD IS USED AS DIRECTED. INHAL:INHAL OF HIGH CONC,
PARTICULARLY MISTS, MAY CAUSE IRRIT OF THE NOSE & THROAT W/HDCH,
(EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT.
Effects of Overexposure:HLTH HAZ:DIZZ, DROW, & DISTURB OF VISION.
SKIN:PRLNG CNTCT W/SKIN TO METHANOL MAY CAUSE REDDENING & DEFAT OF
THE SKIN. METHANOL MAY BE ABSORBED THRU THE SKIN POSSIBLY RSLTG IN
HARMFUL EFTS. EYE:MAY BE IRRITG & CAUSE PAIN, TEARING, REDDENING &
SWELL ACCOMPANIED BY THE STINGING SENSATION &/FEELING LIKE THAT OF
(SUPDAT)
Medical Cond Aggravated by Exposure:DUE TO ITS DEFATTING PROPERTIES,
METHANOL MAY AGGRAVATE AN EXISTING SKIN CONDITION.

First Aid:INHAL:IF SYMPS OF EXPOS DEVELOP, REMOVE TO FRESH AIR. IF
BRTHG BECOMES DFCLT, ADMINISTER OXYGEN IF AVAIL. ADMINISTER ARTF
RESP IF BRTHG STOPS. SEEK IMMED MED ATTN. SKIN:REMOVE CONTAMD
CLTHG. FLUSH EXP OSED SKIN W/COPIOUS AMTS OF H*2O & WASHW/SOAP. IF
IRRIT DEVELOPS & PERSISTS, SEEK MED ATTN. EYE:EXPOSED EYES SHOULD
BE REMOVED WHILE FLUSHING. FLUSH FOR A MIN OF 15 MIN/UNTIL IRRIT
SUBSIDES. (ING 13)

Flash Point Method:SCC
Flash Point:90.0F,32.2C
Lower Limits:SEE INGS
Upper Limits:SEE INGS
Extinguishing Media:USE WATER FOG, CARBON DIOXIDE, ALCOHOL FOAM OR DRY
CHEMICAL. COOL FIRE EXPOSED CONTAINERS WITH WATER.
Fire Fighting Procedures:USE NIOSH APPROVED SCBA & FULL PROTECTIVE
EQUIPMENT .
Unusual Fire/Explosion Hazard:FLAMM LIQ. METHANOL-WATER MIX WILL BURN
UNLESS VERY DILUTE. FLAME IS INVISIBLE IN DAYLIGHT. VAPS ARE
HVR/AIR & MAY FLOW ALONG SURF TO DISTANT IGNIT (SUPDAT)

Spill Release Procedures:ELIMINATE ALL IGNITION SOURCES. VENTILATE
AREA. WEAR APPROPRIATE PROTECTIVE CLOTHING AND EQUIPMENT. COLLECT
WITH ABSORBENT MATERIAL AND PLACE IN APPROPRIATE, LABELED CONTAINER
FOR DISPOSAL.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

Handling and Storage Precautions:STORE PROD BELOW 120F & AWAY FROM
DIRECT SUNLIGHT. STORE IN A COOL, WELL VENT AREA. DO NOT SWALLOW.
AVOID EYE & SKIN CONTACT. AVOID BRTHG VAPS/MISTS.
Other Precautions:USE ONLY WITH ADEQUATE VENTILATION. FLAMMABLE LIQUID!
KEEP CONTAINER AWAY FROM HEAT, SPARKS, OPEN FLAMES AND ALL OTHER
SOURCES OF IGNITION. DO NOT SMOKE DURING USE.

Respiratory Protection:THE FOLLOWING RESPS ARE REC ON INFO FOUND IN THE
PHYSICAL & CHEM PROPERTIES, TOXICOLOGICAL INFO & HLTH HAZS SECTION.
THEY ARE RANKED IN ORDER FROM MIN TO MAXIMUM RESP PROT. THE
SPECIFIC RESP MUST BE B ASED ON CONTAM LEVELS (ING 21)
Ventilation:USE GENERAL VENTILATION OR LOCAL EXHAUST AS REQUIRED TO
MAINTAIN EXPOSURES BELOW THE OCCUPATIONAL EXPOSURE LIMITS.
Protective Gloves:CHEMICAL RESISTANT GLOVES
Eye Protection:ANSI APPROVED CHEM WORKERS GOGGS .
Other Protective Equipment:EYE WASH FOUNTAIN & DELUGE SHOWER WHICH MEET
ANSI DESIGN CRITERIA .
Work Hygienic Practices:WASH EXPOSED SKIN THOROUGHLY WITH SOAP AND
WATER AFTER USE.
Supplemental Safety and Health
EXPLO HAZ:SOURCES & FLASH BACK. EFTS OF OVEREXP:FINE DUST IN THE EYES.
INGEST:MAY CAUSE NAUS, ABDOM PAIN, VOMIT, SHORTNESS OF BRTH,
FATIGUE & LEG CRAMPS. NERVOUS SYS EFTS INCL:HDCH, CONFUSN, DRUNKEN
B EHAVIOR, CNS DEPRESS, COMA & DEATH. VISUAL EFTS OF METHANOL INCL
BLURRED VISION, DOUBLE VISION, CHANGES IN COLOR (ING 5)

Boiling Pt:B.P. Text:158F,70C
Melt/Freeze Pt:M.P/F.P Text:-32F,-36C
Vapor Pres:36 @ 68F
Vapor Density:>1
Spec Gravity:7.9 LBS/GAL
pH:7.9
Evaporation Rate & Reference:<1 (BUTYL ACETATE=1)
Solubility in Water:100%
Appearance and Odor:CLEAR YELLOW LIQUID WITH SLIGHT ALCOHOL ODOR.
Percent Volatiles by Volume:>95

Stability Indicator/Materials to Avoid:YES
STRONG BASES, STRONG ACIDS, STRONG OXIDIZING AGENTS.
Stability Condition to Avoid:HEAT, SPARKS, FLAMES AND ALL OTHER SOURCES
OF IGNITION.
Hazardous Decomposition Products:CARBON MONOXIDE, CARBON DIOXIDE.

Waste Disposal Methods:DISPOSE OF PRODUCT AS HAZARDOUS WASTE
(IGNITABLE) IN ACCORDANCE WITH ALL LOCAL, STATE/PROVINCIAL AND
FEDERAL REGULATIONS.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.