Product ID:PYROIL CARB CLEANER (BONUS) 12/15.6 OZ
MSDS Date:07/14/1995
FSC:6850
NIIN:00N074547
MSDS Number: CDWVL

VALVOLINE CO

3499 DABNEY DR
LEXINGTON, KY 40512
US

Emergency Phone: 800-274-5263

Info Phone: 606-357-7847

Cage: IO754

VALVOLINE OIL CO

14000 LEXINGTON, KY 40512 US

Telephone: 606-357-7206 / 800-274-5263

Cage: 72527

XYLENE (SARA 313) (CERCLA)

CAS: 1330-20-7

RTECS: ZE2100000

Fraction By Weight: 39%

OSHA PEL 100 PPM

ACGIH TLV: 100 PPM/150STEL

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

METHYL ALCOHOL (METHANOL) (SARA 313) (CERCLA)

CAS: 67-56-1

RTECS: PC1400000

Fraction By Weight: 26%

OSHA PEL 200 PPM, S

ACGIH TLV: 200PPM/250STEL, S

EPA Report Quantity: 5000 LBS

DOT Report Quantity: 5000 LBS

ACETONE (SARA 313) (CERCLA)

CAS: 67-64-1

RTECS: AL3150000

Fraction By Weight: 20-30%

OSHA PEL 1000 PPM

ACGIH TLV: 750PPM/1000STEL

EPA Report Quantity: 5000 LBS

DOT Report Quantity: 5000 LBS

PROPANE

CAS: 74-98-6

RTECS: TX2275000

Fraction By Weight: 4.5-15%

OSHA PEL 1000 PPM

ACGIH TLV: ASPHYXIANT

ETHYL BENZENE (SARA 313)

CAS: 100-41-4

RTECS: DA0700000

Fraction By Weight: 6.9-7.7%

OSHA PEL 100 PPM

ACGIH TLV: 100 PPM/125STEL

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

TOLUENE (SARA 313) (CERCLA)

CAS: 108-88-3

RTECS: XS5250000

OSHA PEL 200 PPM

ACGIH TLV: 50 PPM, S

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

99.770%; 604.000 G/L (5.040

RTECS: 9999999VO

OSHA PEL N/K

ACGIH TLV: N/K

LIVER

RTECS: 9999999ZZ

BRAIN DMG. OVEREXP MAY CAUSE THE FOLLOWING EFTS IN

RTECS: 9999999ZZ

TO FETUS BASED ON LAB ANIMAL STUDIES. INTENTIONAL

RTECS: 9999999ZZ

W/LIVER, KIDNEY & BRAIN DMG IN HUMANS. RPTD EXPOS

RTECS: 9999999ZZ

LOSS BASED ON EVIDENCE IN LAB ANIMALS; HUMAN HLTH

RTECS: 9999999ZZ

APPEARS ON THE NAVY OCCUP CHEM REPRO HAZ LIST. SEEK

RTECS: 9999999ZZ

LATEST HAZ LIST INFORMATION & SAFE HANDLING &

RTECS: 9999999ZZ

COMPLETED. STOP SPILL AT SOURCE. PVNT FROM

RTECS: 9999999ZZ

PVNT FROM SPREADING. IF RUNOFF OCCURS, NOTIFY AUTH

RTECS: 9999999ZZ

CLEAN CONTRS FOR RECOVERY. ABSORB UNRECOVERABLE

RTECS: 9999999ZZ

CONTRS FOR DISP. PVNT RUN-OFF TO SEWERS,

RTECS: 9999999ZZ

PROPER AUTHORITIES AS REQUIRED, THAT A SPILL HAS

RTECS: 9999999ZZ

ACIDOSIS, VISUAL DISTURB & BLINDNESS. SINCE

RTECS: 9999999ZZ

ONSET MAY BE DELAYED FROM 6-30 HRS FOLLOWING

RTECS: 9999999ZZ

BEEN USED TO PVNT METHANOL METABOLISM. ETHANOL

RTECS: 9999999ZZ

METHANOL CONCENTRATIONS ABOVE 20 UG/DL. METHANOL IS

RTECS: 9999999ZZ

LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:ACUTE: EYE: IRRIT, STINGING, TEARING,
REDNESS, SWELL & BLURRED VISION. SKIN: MILD IRRIT. PRLNG/RPTD EXPOS
MAY DRY SKIN. REDNESS, BURNING, DRYING & CRACKING, & SKIN BURNS.
INGEST: SINGLE DOSE ORAL TOX IS LOW. INGEST SML AMTS DURING NORM
HNDLG IS NOT LIKELY TO CAUSE HARMFUL EFTS; INGEST LGE AMTS MAY BE
(EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT.
Effects of Overexposure:HLTH HAZ: HARMFUL. MATL CAN ENTER LUNGS DURING
SWALLOWING/VOMIT & CAUSE LUNG INFLAMM &/DMG. INHAL: EXPOS TO
VAP/MIST IS POSS. SYMPS OF EXPOS: GI IRRIT (NAUS, VOMIT, DIARR),
IRRIT (NOSE, THROAT, RESP T RACT), CNS DEPRESS (DIZZ, DROW, WEAK,
FATG, NAUS, HDCH, UNCON), & DEATH. TARGET ORGAN EFTS: OVEREXP MAY
CAUSE (ING 8)
Medical Cond Aggravated by Exposure:PREEXISTING SKIN DISORDERS, LUNG
DISORDERS (E.G., ASTHMA-LIKE CONDITIONS); LIVER ABNORMALITIES;
ANEMIA; SPLEEN, NERVOUS SYSTEM, EYE, KIDNEY, LUNG AND BRAIN DAMAGE.

First Aid:EYES: FLUSH W/POTABLE WATER FOR AT LEAST 15 MIN. SEE MD .
SKIN: FLUSH W/COPIOUS AMTS OF WATER. SEE MD . INHAL: REMOVE TO
FRESH AIR. SUPPORT BRTHG (GIVE OXYGEN/ARTF RESP) . INGEST: CA LL MD
IMMED . NOTE TO MD: CONTAINS METHANOL WHICH CAN CAUSE INTOXICATION
& CNS DEPRESS. METHANOL IS METABOLIZED TO FORMIC ACID &
FORMALDEHYDE. THESE METABOLITES CAN CAUSE METABOLIC (ING 20)

Lower Limits:1.0%
Upper Limits:36.5%
Extinguishing Media:REGULAR FOAM, CARBON DIOXIDE, DRY CHEMICAL.
Fire Fighting Procedures:WEAR NIOSH APPROVED SCBA & FULL PROTECTIVE
EQUIPMENT .
Unusual Fire/Explosion Hazard:MATL IS HIGHLY VOLAT & READILY GIVES OFF
VAPS WHICH MAY TRAVEL ALONG GROUND/BE MOVED BY VENT & IGNITED BY
PILOT LIGHTS, OTHER FLAMES, SPKS, HEATERS, (SUP DAT)

Spill Release Procedures:SML SPILL: ABSORB LIQ ON VERMICULITE, FLOOR
ABSORB/OTHER ABSORB MATL. LGE SPILL: ELIM ALL IGNIT SOURCES
(FLARES, FLAMES INCL PILOT LIGHTS, ELEC SPKS). PERS NOT WEARING
PROT EQUIP SHOULD BE EXCLUDED FR OM AREA OF SPILL UNTIL CLEAN-UP
HAS BEEN (ING 15)
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

Handling and Storage Precautions:CONTRS MAY BE HAZ WHEN EMPTIED. SINCE
EMPTIED CONTRS RETAIN PROD RESIDUES (VAP, LIQ, &/SOLID), ALL HAZ
PREC GIVEN IN MSDS MUST BE OBSERVED.
Other Precautions:ALL FIVE GALLON PAILS AND LARGER METAL CONTAINERS
INCLUDING TANK CARS AND TANK TRUCKS SHOULD BE GROUNDED AND/OR
BONDED WHEN MATERIAL IS TRANSFERRED.

Respiratory Protection:IF WORKPLACE EXPOS LIM OF PROD/ANY COMPONENT IS
EXCEEDED, A NIOSH APPRVD AIR SUPP RESP IS ADVISED IN ABSENCE OF
PROPER ENVIRON CTL. OSHA REGS ALSO PERMIT OTHER NIOSH RESPS (NEG
PRESS TYPE) UNDER SPECI FIED CNDTNS (CONSULT YOUR (SUP DAT)
Ventilation:PROVIDE SUFFICIENT MECHANICAL (GENERAL AND/OR LOCAL
EXHAUST) VENTILATION TO MAINTAIN EXPOSURE BELOW TLV'S.
Protective Gloves:NEOPRENE GLOVES.
Eye Protection:ANSI APPRVD CHEM WORKERS GOGGLES .
Other Protective Equipment:EMERGENCY EYEWASH AND DELUGE SHOWER MEETING
ANSI DESIGN CRITERIA .
Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health
EXPLO HAZ: SMKNG, ELEC MOTORS, STATIC DISCHARGE/OTHER IGNIT SOURCES AT
LOCATIONS DISTANT FROM MATL HNDLG POINT. NEVER USE WELDING/CUTTING
TORCH ON/NEAR DRUM (EVEN EMPTY) BECAUSE PROD (EVEN JUST RESIDU E)
CAN IGNITE EXPLO. RESP PROT: INDUS HYGIENIST).
ENGINEERING/ADMINISTRATIVE CTLS SHOULD BE IMPLEMENTED TO REDUCE
EXPOS.

Boiling Pt:B.P. Text:133F,56C
Vapor Pres:181.700
Vapor Density:>1 (AIR=1)
Spec Gravity:0.770
Appearance and Odor:LIQUID
Percent Volatiles by Volume:100

Stability Indicator/Materials to Avoid:YES
AVOID CONTACT WITH STRONG OXIDIZING AGENTS.
Stability Condition to Avoid:AVOID HEAT, OPEN FLAME, AND PROLONGED
STORAGE AT ELEVATED TEMPERATURES.
Hazardous Decomposition Products:MAY FORM CARBON DIOXIDE AND CARBON
MONOXIDE, VARIOUS HYDROCARBONS.

Waste Disposal Methods:DISPOSE OF IN ACCORDANCE WITH ALL APPLICABLE
LOCAL, STATE AND FEDERAL REGULATIONS.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.