Product ID:BUFFER SOLUTION (PH 6.00) UNDILUTED, SB106
MSDS Date:12/20/1991
FSC:6550
NIIN:00N038309
MSDS Number: CDZKG

FISHER SCIENTIFIC

1 REAGENT LN
FAIR LAWN, NJ 07410
US

Emergency Phone: 201-796-7100;800-424-9300(CHEMTREC)

Info Phone: 201-796-7100

Cage: 1B464

FISHER SCIENTIFIC CO. CHEMICAL MFG DIV

FAIRLAWN, NJ 07410-2802 US

Telephone: 201-796-7100

Cage: 1B464

CALIFORNIA SAFE DRINING WATER & TOXIC ENFORCEMENT

RTECS: 9999999ZZ

KNOWN SOURCES OF DRINKING WATER W/SUBSTANCES KNOWN

RTECS: 9999999ZZ

SLOW RXN BECOMES EXPLOSIVE AROUND 180C.

RTECS: 9999999ZZ

FIRE & EXPLO HAZ. PEROXYFORMIC

RTECS: 9999999ZZ

POLYMERIZATION RXN W/SUDDEN PRESS DEVELOPMENT.

RTECS: 9999999ZZ

CFR 29

RTECS: 9999999ZZ

PHOSPHATES ARE CAPABLE OF SERIOUSLY

RTECS: 9999999ZZ

SODIUM PHOSPHATE,

RTECS: 9999999ZZ

EVID OF CHEM REMAINS(@ LST 15-20 MIN). IN

RTECS: 9999999ZZ

BANDAGE SECURELY BUT NOT TOO TIGHTLY. GET MED ATTN

RTECS: 9999999ZZ

LIFTING UPPER & LOWER LIDS UNTIL NO EVID OF CHEM

RTECS: 9999999ZZ

SALINE UNTIL PH RETURNS TO NORM (30-60 MIN). COVER

RTECS: 9999999ZZ

SYMP & SUPPORTIVELY. GET MED ATTN IMMED. IF VOMIT

RTECS: 9999999ZZ

REPORTABLE QUANTITY ESTABLISHED FOR THAT

RTECS: 9999999ZZ

& STATE EMER RESPONSE COMMISSION (40 CFR 355.40).

RTECS: 9999999ZZ

SECTION 103, NRC MUST BE NOTIFIED IMMED AT

RTECS: 9999999ZZ

SODIUM PHOSPHATE, MONOBASIC; (POTASSIUM PHOSPHATE,

CAS: 7558-80-7

RTECS: WA1900000

Fraction By Weight: 8%

OSHA PEL N/K

ACGIH TLV: N/K

SODIUM HYDROXIDE (CERCLA)

CAS: 1310-73-2

RTECS: WB4900000

Fraction By Weight: 0.7%

OSHA PEL 2 MG/M3

ACGIH TLV: 2 MG/M3, C

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

(ORAL, RAT) 100

CAS: 50-00-0

RTECS: LP8925000

Fraction By Weight: 0.2%

OSHA PEL N/K

ACGIH TLV: 0.3 PPM, C

EPA Report Quantity: 100 LBS

DOT Report Quantity: 100 LBS

METHANOL; (METHYL ALCOHOL) (SARA 313) (CERCLA)

CAS: 67-56-1

RTECS: PC1400000

Fraction By Weight: 0.08%

OSHA PEL 200 PPM, S

ACGIH TLV: 200 PPM; 250 STEL, S

EPA Report Quantity: 5000 LBS

DOT Report Quantity: 5000 LBS

WATER

CAS: 7732-18-5

RTECS: ZC0110000

Fraction By Weight: 91.02%

OSHA PEL N/K

ACGIH TLV: N/K

ANILINE TREATED

RTECS: 9999999ZZ

WHICH BURNS W/EXPLO VIOLENCE. COPPER, COPPER ALLOYS,

RTECS: 9999999ZZ

FORMS HIGHLY TOX

RTECS: 9999999ZZ

LD50 LC50 Mixture:SEE INGREDIENTS
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:YES
Health Hazards Acute and Chronic:SODIUM PHOSPHATE, MONOBASIC: ACUTE:
INHAL: INHAL OF DUST MAY CAUSE IRRIT. SKIN: MAY CAUSE IRRIT. EYES:
MAY CAUSE TRANSIENT IRRIT. TESTED ON RABBIT EYES BY CONTINUOUS
EXPOS FOR 3 HRS AT 0.1 M SOLN AT P H 7.0-7.5 MADE UP TO 0.46
OSMOLAR W/SODIUM CHLORIDE OR SUCROSE, CAUSED NO DISTURBS OF CORNEA.
INGEST: (EFTS OF OVEREXP)
Explanation of Carcinogenicity:FORMALDEHYDE: IARC MONOGRAPHS, SUPP, VOL
7, PG 211, 1987:GROUP 2A. NTP 7TH ANNUAL RPT ON CARCONS, 1994:
ANTIC (ING 12)
Effects of Overexposure:HLTH HAZ: MAY RSLT IN ABDOMINAL PAIN, NAUS,
VOMIT, DIARR, CRAMPS, PAIN & BURNING IN MOUTH. DOSES OF 250 G/KG
GIVEN ORALLY TO GUINEA PIGS, RATS & RABBITS PRDCED DIARR.
GENERALLY, PHOSPHATES ARE SLOWLY & INCOMPLETELY ABSORBED,
THEREFORE SYSTEMIC RXNS ARE UNLIKELY WHEN THESE SALTS ARE GIVEN
ORALLY. SODIUM (ING 13)
Medical Cond Aggravated by Exposure:PERSONS WITH ASTHMA, CHRONIC SKIN
DISEASE OR PREEXISTING LUNG DISEASE ARE AT INCREASED RISK FROM
EXPOSURE.

First Aid:INHAL:REMOVE FROM EXPOS TO FRESH AIR IMMED. IF BRTHG HAS
STOPPED, GIVE ARTF RESP. MAINTAIN AIRWAY & BLOOD PRESS & ADMIN
OXYGEN IF AVAIL. KEEP AFFECTED PERSON WARM & AT REST. TREAT SYMP &
SUPPORTIVELY. ADMIN OF OXYGEN SHOULD BE PERFROMED BYQUALIFIED
PERS. GET MED ATTN IMMED. SKIN: REMOVE CONTAMD CLTHG & SHOES IMMED.
WASH AFFECTED AREA W/SOAP OR MILD DETERGENT & LG AMTS OF WATER
UNTIL NO (ING 15)

Extinguishing Media:DRY CHEMICAL, CARBON DIOXIDE, WATER SPRAY OR
REGULAR FOAM. FOR LARGER FIRES, USE WATER SPRAY, FOG OR REGULAR
FOAM.
Fire Fighting Procedures:USE NIOSH APPRVD SCBA & FULL PROT EQUIP . MOVE
CNTNR FROM AREA IF W/OUT RISK. DO NOT SCATTER SPILLED MATL
W/HIGH-PRESS STREAMS. DIKE FIRE-CONTROL (SUPDAT)
Unusual Fire/Explosion Hazard:NEGLIGIBLE FIRE HAZARD WHEN EXPOSED TO
HEAT OR FLAME.

Spill Release Procedures:STOP LEAK IF YOU CAN DO IT W/OUT RISK. FOR SM
SPILLS, TAKE UP W/SAND OR OTHER ABSORB MATL & PLACE INTO CLEAN, DRY
CNTNRS FOR LATER DISP. KEEP UNNEC PEOPLE AWAY. ISOLATE HAZ AREA &
DENY ENTRY. SARA 304 REQS THAT RELS EQUAL TO OR GREATER THAN (ING
20)
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

Handling and Storage Precautions:STORE AWAY FROM INCOMPATIBLE
SUBSTANCES.
Other Precautions:MAY BURN BUT DOES NOT IGNITE READILY. AVOID CONTACT
WITH STRONG OXIDIZERS. EXCESSIVE HEAT, SPARKS OR OPEN FLAME.

Respiratory Protection:THE SPECIFIC RESPIRATOR SELECTED MUST BE BASED
ON CONTAM LEVELS FOUND IN THE WORK PLACE, MUST NOT EXCEED THE
WORKING LIMITS OF THE RESPIRATOR & BE APPROVED BY NIOSH. FOR A LIST
OF SPECIFIC RESPIRATORS CONTACT NEHC .
Ventilation:PROVIDE LOCAL EXHAUST OR PROCESS ENCLOSURE VENT TO MEET
PUBLISHED EXPOS LIMITS. VENT EQUIP MUST BE EXPLOSION-PROOF.
Protective Gloves:IMPERVIOUS GLOVES .
Eye Protection:ANSI APPRVD CHEM WORKERS GOGGLES .
Other Protective Equipment:ANSI APPROVED EYE WASH & DELUGE SHOWER .
WEAR APPROP PROT (IMPERVIOUS) CLTHG & EQUIP TO PVNT ANY SKIN
CONTACT.
Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health
FIRE FIGHT PROC: WATER FOR LATER DISP. USE AGENTS SUITABLE FOR TYPE OF
SURROUNDING FIRE. AVOID BRTHG HAZ VAPS, KEEP UPWIND. MATL TO AVOID:
(STRONG), ANHYDRIDES, ISOCYANATES, OXIDES, UREA: FORMALDEHYDE
SOLNS REACT. AMMONIA, BISULFIDES, IODINE, IRON PREPARATIONS,
POTASSIUM PERMANGANATE, SILVER SALTS: INCOMPATIBLE.(ING 6)

Boiling Pt:B.P. Text:212F,100C
Melt/Freeze Pt:M.P/F.P Text:32.0F,0.0C
Solubility in Water:SOLUBLE
Appearance and Odor:LIQUID.

Stability Indicator/Materials to Avoid:YES
ING 1: BRASS, STEEL:MAY BE CORR IN PRESENCE OF MOISTURE. METALS:SOLNS
MAY BE CORR. ING 2: ACIDS(INORG), ALKALIES(SUPDAT)
Stability Condition to Avoid:STABLE UNDER NORMAL TEMPERATURES AND
PRESSURES.
Hazardous Decomposition Products:THERMAL DECOMPOSITION MAY RELEASE
TOXIC AND/OR HAZARDOUS GASES.

Waste Disposal Methods:OBSERVE ALL FEDERAL, STATE AND LOCAL REGULATIONS
WHEN STORING OR DISPOSING OF THIS SUBSTANCE. FOR ASSISTANCE CONTACT
THE DISTRICT DIRECTOR OF THE ENVIRONMENTAL PROTECTION AGENCY.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.