Product ID:ACID SPILL KIT, S101
MSDS Date:05/07/1991
FSC:6850
NIIN:00N038311
MSDS Number: CDZKH

FISHER SCIENTIFIC

1 REAGENT LN
FAIR LAWN, NJ 07410
US

Emergency Phone: 201-796-7100;800-424-9300(CHEMTREC)

Info Phone: 201-796-7100

Cage: 1B464

FISHER SCIENTIFIC CO. CHEMICAL MFG DIV

FAIRLAWN, NJ 07410-2802 US

Telephone: 201-796-7100

Cage: 1B464

MAY CAUSE

RTECS: 9999999ZZ

DERM & POSS SODA ULCERS ON HANDS/WRISTS. SENSITIVITY

RTECS: 9999999ZZ

INFLAM &

RTECS: 9999999ZZ

INTESTINAL OBSTRUCTION & FECAL CONCRETIONS.

RTECS: 9999999ZZ

WASH IMMED

RTECS: 9999999ZZ

UNTIL NO EVID OF CHEM REMAINS (@ LST 15-20 MIN).

RTECS: 9999999ZZ

MIN). COVER S/STERILE BANDAGES. GET MED ATTN.

RTECS: 9999999ZZ

OCCUR. AVOID GASTRIC LAVAGE/EMETICS. ESOPHAGOSCOPY

RTECS: 9999999ZZ

SUSPECTED, ESOPHAGOSCOPY SHOULD USUALLY BE PERFORMED

RTECS: 9999999ZZ

KEEP HEAD BELOW HIPS TO HELP PVNT ASPIR. GET MED

RTECS: 9999999ZZ

OF SPILL FOR LATER DISP. KEEP UNNEC PEOPLE

RTECS: 9999999ZZ

& FULL LENGTH FACESHIELD .

RTECS: 9999999ZZ

(ORAL, RAT) 7340 MG/KG

CAS: 1305-62-0

RTECS: EW2800000

Fraction By Weight: 51%

OSHA PEL 15 MG/M3 TDUST

ACGIH TLV: 5 MG/M3

(ORAL,

CAS: 497-19-8

RTECS: VZ4050000

Fraction By Weight: 32%

OSHA PEL N/K

ACGIH TLV: N/K

1); (CALCIUM CARBONATE)

CAS: 471-34-1

RTECS: FF9335000

Fraction By Weight: 16%

OSHA PEL N/K

ACGIH TLV: N/K

LITMUS; (LITMUS POWDER)

CAS: 1393-92-6

Fraction By Weight: 100%

OSHA PEL N/K

ACGIH TLV: N/K

ERYTHEMA, BLISTERS & SKIN NECROSIS. EYE

RTECS: 9999999ZZ

EPITHELIUM, CORNEAL OPACIFICATION & IRITIS. W/SEV

RTECS: 9999999ZZ

OPACITY, STAPHYLOMA, CATARACT, SYMBLEPHARON &

RTECS: 9999999ZZ

BLURRED VISION. CONC SOLNS MAY CAUSE NECROSIS. ING

RTECS: 9999999ZZ

MAY CAUSE IMMED PAIN, CIRCUMORAL BURNS, MUC MEMB

RTECS: 9999999ZZ

SPEAK. BURNING PAIN OF ESOPHAGUS/STOM, VOMIT, DIARR.

RTECS: 9999999ZZ

PERFORATION, ESOPHAGEAL & POSS GASTRIC/PYLORIC

RTECS: 9999999ZZ

DISTURBS. DEATH DUE TO CIRCULATORY COLLAPSE. LETHAL

RTECS: 9999999ZZ

MAY CAUSE INFLAM & ULCERATIVE CHGS IN

RTECS: 9999999ZZ

LD50 LC50 Mixture:SEE INGREDIENTS
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:ACUTE: INHAL: ING 1:MAY CAUSE IRRIT OF
RESP TRACT W/COUGH, CHOKING, PAIN & POSS BURNS OF MUC MEMBS. PULM
EDEMA MAY DEVELOP W/TIGHTNESS IN CHEST, DYSPNEA, FROTHY SPUTUM,
CYANOSIS, DIZZ; HYPOTENSION, WE AK & RAPID PULSE & MOIST RALES. MAY
BE FATAL. ING 2:DUST/VAPS MAY CAUSE MUC MEMB IRRIT. ING 3:MAY
CAUSE(EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT
Effects of Overexposure:HLTH HAZ:MECH IRRIT W/COUGH & SNEEZING;
UNPLEASANT DEPOSITS IN NASAL PASSAGES. ING 3:MAY BE IRRIT. SKIN:ING
1: DIRECT CNTCT MAY CAUSE SEV PAIN, BURNS & POSS BROWNISH STAINS,
CORRODED AREAS MAY BE SOFT , GELATINOUS & NECROTIC & TISS
DESTRUCTION DEEP. ING 2:CNTCT MAY CAUSE IRRIT & REDNESS. CONCS
SOLNS MAY CAUSE (ING 5)
Medical Cond Aggravated by Exposure:PERSONS WITH RENAL DYSFUNCTION,
GASTROINTESTINAL HEMORRHAGE, HYPOTHYROIDISM, HYPERCALCEMIA OR OTHER
METABOLIC DISTURBANCES ARE AT INCREASED RISK FROM EXPOSURE.

First Aid:INHAL:REMOVE TO FRESH AIR. IF BRTHG STOPS GIVE ARTF RESP.
MAINTAIN AIRWAY & BLOOD PRESS & ADMIN O*2 (BY QUALIFIED PERS) IF
AVAIL. KEEP WARM & AT REST. TREAT SYMP & SUPPORTIVELY. GET MED
ATTN. SKIN:REM OVE CONTAMD CLTHG & SHOES IMMED. WASH AREA W/SOAP &
LG AMTS OF WATER UNTIL NO EVID OF CHEM REMAINS (AT LST 15-20 MIN).
IN CASE OF CHEM BURNS, COVER AREA W/STERILE, DRY DRESSING. BANDAGE
(ING 18)

Flash Point:NOT COMBUSTIBLE
Extinguishing Media:DRY CHEMICAL, CARBON DIOXIDE, WATER SPRAY OR
REGULAR FOAM. FOR LARGER FIRES, USE WATER SPRAY, FOG OR REGULAR
FOAM.
Fire Fighting Procedures:NIOSH APPRVD SCBA & FULL PROT EQUIP . MOVE
CNTNR FROM AREA IF W/OUT RISK. APPLY COOLING WATER TO SIDES OF
CNTNRS EXPOS TO FLAMES UNTIL WELL AFTER (SUPDAT)
Unusual Fire/Explosion Hazard:NEGLIGIBLE FIRE HAZARD WHEN EXPOSED TO
HEAT OR FLAME.

Spill Release Procedures:DO NOT TOUCH SPILL MATL. STOP LEAK IF W/OUT
RISK. SM SPILL:TAKE UP W/ABSORB MATL & PLACE INTO CNTNRS FOR LATER
DISP. SM DRY SPILL: W/CLEAN SHOVEL PLACE MATL INTO CLEAN, DRY CNTNR
& COVER. MOVE CNTNRS FROM SPILL AREA. LG SPILLS:DIKE FAR AHEAD
(ING 24)
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

Handling and Storage Precautions:STORE AWAY FROM INCOMPAT SUBSTANCES.
Other Precautions:MAY BURN BUT DOES NOT IGNITE READILY. FLAMMABLE,
POISONOUS GASES MAY ACCUMULATED IN TANKS AND HOPPER CARS. MAY
IGNITE COMBUSTIBLES (WOOD, PAPER, OIL, ETC).

Respiratory Protection:SPECIFIC RESPIRATOR SELECTED MUST BE BASED ON
CONTAM LEVELS FOUND IN WORKPLACE, MUST BE BASED ON SPECIFIC
OPERATION, MUST NOT EXCEED WORKING LIMITS OF RESP & MUST BE NIOSH
APPROVED. FOR A LIST OF SPEC IFIC RESPIRATORS, CONTACT NEHC .
Ventilation:PROVIDE LOCAL EXHAUST OR GENERAL DILUTION VENTILATION
SYSTEM.
Protective Gloves:IMPERVIOUS GLOVES .
Eye Protection:ANSI APPRVD CHEM WORKERS GOGGS (ING 25)
Other Protective Equipment:ANSI APPROVED EYE WASH & DELUGE SHOWER .
WEAR APPROPRIATE PROTECTIVE (IMPERVIOUS) CLOTHING & EQUIPMENT.
Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health
FIRE FIGHT PROC: FIRE IS OUT. STAY AWAY FROM ENDS OF TANKS. EXTING
USING AGENT INDICATED; DO NOT USE WATER DIRECTLY ON MATL. IF LG
AMTS OF COMBUST MATLS INVOLVED, USE WATER SPRAY/FOG IN FLOODING
AMTS. AVOID BRTHG CORR DUSTS & FUMES FROM BURNING MATL, KEEP
UPWIND.

Solubility in Water:SOLUBLE
Appearance and Odor:WHITE POWDER WITH BLUE PARTICLES.

Stability Indicator/Materials to Avoid:YES
PHOSPHORUS, ACIDS, ALUMINUM, SULFURIC ACID, FLUORINE, MAGNESIUM. FOR A
LIST OF MATERIALS TO AVOID, CONTACT NEHC .
Stability Condition to Avoid:STABLE UNDER NORMAL TEMPERATURES AND
PRESSURES.
Hazardous Decomposition Products:THERMAL DECOMPOSITION PRODUCTS MAY
INCLUDE CORROSIVE CALCIUM OXIDE AND TOXIC OXIDES OF CARBON.

Waste Disposal Methods:DISPOSAL MUST BE IN ACCORDANCE WITH FEDERAL,
STATE AND LOCAL REGULATIONS .

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.