Product ID:DIESELINE, 31135
MSDS Date:04/09/1992
FSC:9140
NIIN:00N065444
MSDS Number: CDZNT

SHELL OIL CO

HOUSTON, TX 77210
US

Emergency Phone: 713-473-9461;800-424-9300(CHEMTREC)

Info Phone: 713-241-4819

Preparer: G.A. VANGELDER

Cage: SHELO

SHELL OIL COMPANY

4320 HOUSTON, TX 77210 US

Telephone: 800-231-6950

Cage: 54527

DIESEL FUELS; (SHELL DIESELINE)

CAS: 68334-30-5

RTECS: HZ1800000

Fraction By Weight: 100%

OSHA PEL N/K

ACGIH TLV: N/K

EVID BY GIDD, HDCH, DIZZ & NAUS; IN

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OSHA PEL N/K

ACGIH TLV: N/K

MAY RSLT

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AVOIDED AS EVEN SMALL QTYS MAY RESULT IN ASPIR

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(BLUISH SKIN); IN SEV CASES DEATH MAY OCCUR. OTHER

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RSLTS OF ANIMAL BIOASSAYS ON MID DISTIL FUELS SHOW

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RPTD DERMAL APPLICATN OF HIGH LEVELS OF MID DISTIL

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IRRIT TO CORR ACTION ON SKIN. VARYING DEGREES OF

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MOTTLING & MULTIFOCAL NECROSIS. MID DISTIL FUELS

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MARROW CYTOGENETICS ASSAY & MUTAGENIC IN MOUSE

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IN STUDIES W/LAB ANIMALS, NIOSH REGARDS WHOLE

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DO NOT

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PVNT ASPIR OF LIQ INTO LUNGS. GET MED ATTN. NOTE TO

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OCCURRED, EMESIS SHOULD BE INDUCED W/SUPERVISION.

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LOSS OF GAG REFLEX, CONVLS/UNCON OCCUR BEFORE

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ABSORB SUCH AS CLAY, SAND/OTHER SUITABLE MATL;

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DISP. FLUSH AREA W/WATER TO REMOVE TRACE RESIDUE;

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W/ABSORB MATL & PLACE IN NON-LEAKING CNTNRS FOR

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(ONLY) W/ADEQ VENT. CNTNRS, EVEN THOSE THAT

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DRILL, GRIND, WELD OR PERFORM SIMILAR OPERATIONS

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DRINKING, SMOKING OR USING TOILET FACILITIES.

RTECS: 9999999ZZ

LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:EYE:BASED ON ESSNTLY SIMILAR PROD
TESTS LIQ IS PRACTICALLY NONIRRIT. SKIN: BASED ON ESSNTLY SIMILAR
PROD TESTS LIQ IS PRESUMED TO BE MOD IRRIT TO SKIN. PRLNGD/RPTD LIQ
CNTCT CAN RSLT IN DEFAT & DRYING OF SKIN WHICH MAY RSLT IN SEV
IRRIT & DERM. MAY CAUSE SKIN SENSIT (ALLERGY); MAY BE EVID BY
RASHES (EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT
Effects of Overexposure:HLTH HAZ: ESP HIVES. RELS DURING HIGH PRESS
USAGE MAY RSLT IN INJECTION OF OIL INTO SKIN CAUSING LOCAL NECROSIS
EVID BY DELAYED ONSET OF PAIN & TISS DMG A FEW HRS FOLLOWING
INJECTION. INHAL: VAPS/MIST MAY CAUSE MILD IRRIT TO UPPER RESP
TRACT. HIGH CONCS MAY RSLT IN CNS DEPRESS. EARLY TO MOD CNS DEPRESS
MAY BE (ING 2)
Medical Cond Aggravated by Exposure:PREEXISTING SKIN & RESPIRATORY
DISORDERS MAY BE AGGRAVATED BY EXPOSURE TO PROD. PREEXISTING SKIN
OR LUNG ALLERGIES MAY INCREASE CHANCE OF DEVELOPING INCREASED
ALLERGY SYMPS FROM EXPOSURE TO PROD.

First Aid:EYES: FLUSH W/WATER. IF IRRIT OCCURS, GET MED ATTN. SKIN:
REMOVE CONTAMD CLTHG/SHOES & WIPE EXCESS FROM SKIN. FLUSH SKIN
W/WATER. FOLLOW BY WASHING W/SOAP & WATER. IF IRRIT OCCURS, GET MED
ATTN. DO NO T REUSE CLTHG UNTIL CLEANED. IF MATL ISINJECTED UNDER
SKIN, GET MED ATTN PROMPTLY TO PVNT SERIOUS DMG; DO NOT WAIT FOR
SYMPS TO DEVELOP. INHAL: REMOVE TO FRESH AIR & PROVIDE OXYGEN IF
BRTHG (ING 12)

Flash Point Method:PMCC
Flash Point:125F,52C
Extinguishing Media:USE WATER FOG, FOAM, DRY CHEM OR CO*2. DO NOT USE
DIRECT STREAM OF WATER. PROD WILL FLOAT & CAN REIGNITE ON WATER
SURF.
Fire Fighting Procedures:NIOSH APPRVD SCBA & FULL PROT EQUIP (HELMET
W/FSHLD, BUNKER COATS & RUB BOOTS). CAUTION. COMBUST. COOL FIRE
EXPOS CNTNRS W/WATER. IN CASE OF LG (SUDPAT)
Unusual Fire/Explosion Hazard:CNTNRS EXPOSED TO INTENSE HEAT FROM FIRES
SHOULD BE COOLED W/WATER TO PVNT VAP PRESS BUILDUP WHICH COULD RSLT
IN CNTNR RUPTURE. CNTNR AREAS EXPOS TO (SUPDAT)

Spill Release Procedures:CAUTION. COMBUST. LG SPILLS: ELIM POTNTL IGNIT
SOURCES. WEAR APPROP NIOSH APPRVD RESP & OTHER PROT CLTHG. SHUT OFF
SOURCE OF LEAK ONLY IF SAFE TO DO SO. DIKE & CNTN. REMOVE W/VACUUM
TRUCKS/PUMP TO STO RAGE/SALVAGE VESSELS. SOAK UP RESIDUE WITH(ING
16)
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

Handling and Storage Precautions:KEEP LIQ & VAP AWAY FROM HEAT, SPKS &
FLAME. SURFS THAT ARE SUFFICIENTLY HOT MAY IGNITE EVEN LIQ PROD IN
ABSENCE OF SPKS OR FLAME.
Other Precautions:EXTING PILOT LIGHTS, CIGARETTES & TURN OFF OTHER
IGNIT SOURCES PRIOR TO USE & UNTIL ALL VAPS ARE GONE. VAPS MAY
ACCUM & TRAVEL TO IGNIT SOURCES DISTANT FROM HNDLG SITE; FLASH-FIRE
CAN RESULT. KEEP CNT NRS CLSD WHEN NOT IN USE. USE (ING 19)

Respiratory Protection:USE A NIOSH APPROVED RESPIRATOR AS REQUIRED TO
PREVENT OVEREXPOSURE. IN ACCORD WITH 29 CFR 1910.134, USE EITHER A
FULL-FACE ATMOSPHERE-SUPPLYING RESPIRATOR OR AN AIR-PURIFYING
RESPIRATOR FOR ORGANIC V APORS.
Ventilation:USE EXPLOSION-PROOF VENTILATION AS REQUIRED TO CONTROL
VAPOR CONCENTRATIONS.
Protective Gloves:CHEMICAL RESISTANT GLOVES.
Eye Protection:ANSI APPRVD CHEM WORKERS GOGGLES .
Other Protective Equipment:ANSI APPROVED EYE WASH & DELUGE SHOWER .
WEAR OTHER CLOTHING AS REQUIRED TO MINIMIZE SKIN CONTACT.
Work Hygienic Practices:AVOID PROLONGED OR REPEATED CONTACT WITH SKIN.
Supplemental Safety and Health
FIRE FIGHT PROC: FIRES, ALSO COOL SURROUNDING EQUIP & STRUCTURES
W/WATER. EXPLO HAZ: DIRECT FLAME CNTCT SHOULD BE COOLED W/LG QTYS
OF WATER AS NEEDED TO PVNT WEAKENING OF CNTNR STRUCTURE. HAZ DECOMP
P RODS: GASES EVOLVE WHEN MATL UNDERGOES PYROLYSIS/COMBUST. CO &
OTHER UNIDENTIFIED ORG CMPDS MAY BE FORMED UPON COMBUST.

Boiling Pt:B.P. Text:450F,232C
Vapor Density:>1
Spec Gravity:0.6762 (H*2O=1)
Solubility in Water:NEGLIGIBLE
Appearance and Odor:YELLOW LIQUID; STRONG HYDROCARBON ODOR.

Stability Indicator/Materials to Avoid:YES
AVOID CONTACT WITH STRONG OXIDIZING AGENTS.
Stability Condition to Avoid:AVOID HEAT AND FLAME.
Hazardous Decomposition Products:THERMAL DECOMP PRODS ARE HIGHLY
DEPENDENT ON COMBUST CNDTNS. COMPLEX MIX OF AIRBORNE SOILID, LIQ,
PARTICULATES &(SUPDAT)

Waste Disposal Methods:UNDER EPA - RCRA (40 CFR 261.21), IF THIS
PRODUCT BECOMES A WASTE MATERIAL, IT WOULD BE IGNITABLE HAZARDOUS
WASTE. HAZARDOUS WASTE NUMBER D001. REFER TO LATEST EPA, FEDERAL,
STATE AND LOCAL REGULATION S REGARDING PROPER DISPOSAL.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.