Product ID:DINITROPHENOL
MSDS Date:06/01/1992
FSC:6810
NIIN:00N065634
MSDS Number: CDZNV

GENIUM PUBLISHING CORP

1145 CATALYN ST
SCHENECTADY, NY 12303-1836
US

Emergency Phone: 518-377-8854

Info Phone: 518-377-8854

Preparer: M. GANNON

Cage: 5Z768

GENIUM PUBLISHING CORPORATION

SCHENECTADY, NY 12303-1836 US

Telephone: 518-377-8854

Cage: 5Z768

PHENOL, DINITRO-; (DINITROPHENOL) (CERCLA)

CAS: 25550-58-7

RTECS: SL2625000

Fraction By Weight: 100%

OSHA PEL N/K

ACGIH TLV: N/K

EPA Report Quantity: 10 LBS

DOT Report Quantity: 10 LBS

NOZZS OR UNMANNED HOSE HOLDERS; IF THIS IS

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OF RUNOFF FROM FIRE CONTROL METHODS. DO NOT RELEASE

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VOMIT, BRIGHT YELLOW STOOLS & SYMPS ASSOC

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(RIGIDITY OF MUSCS AFTER DEATH) QUICKLY ENSUES.

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HYPERSENSITIVITY MAY RSLT FROM RPTD EXPOS.

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CLTHG. RINSE W/FLOODING AMTS OF WATER FOR

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BLISTERED SKIN, CONSULT MD. YELLOW DISCOLORATION

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REMOVE TO FRESH AIR & SUPPORT BRTHG AS NEEDED.

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CONVULSING. CNTCT POIS CTL CTR. UNLESS ADVISED

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OF WATER, THEN INDUCE VOMIT. AFTER VOMIT GIVE 2

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MONITOR FLUIDS & ELECTROLYTES, CONTROL

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AMINOPHENOL, IN URINE USING DERRIAN'S TEST. DUE TO

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LIFE), IT IS RECOMD THAT PERS HAVING TOX SYMPS NOT

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LET DINITROPHENOL DRY OUT AS IT BECOMES EXPLO)

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BOTTOM & LIFT W/MECH DREDGES. IF DISSOLVED, APPLY

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WITH SUCTION HOSES. FOR MORE INFO ON SPILL

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POINTS WHERE CNTNRS ARE FILLED OR CENTRIFUGES

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EXAMS OF EXPOSED WORKERS THAT EMPHASIZE LIVER &

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REGULARLY. EDUCATE WORKERS ABOUT DINITROPHENOL'S

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& FULL LENGTH FACESHIELD .

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BECAUSE IT ABSORBS DINITROPHENOL; DISCARD

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DRINKING, SMOKING, USING TOILET OR APPLYING

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BRIGHT YELLOW STAIN. SEPARATE CONTAMD WORK CLOTHES

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BEFORE WEARING. REMOVE THIS MATERIAL FROM YOUR

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LD50 LC50 Mixture:LD50: (ORAL, RAT) 30 MG/KG
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:ACUTE: INHAL CAN CAUSE HDCH, COUGH,
PROFUSE SWEATING, THIRST, INTENSE FATG, HIGH FEVER, RAPID PULSE,
WARM & FLUSHED SKIN, RAPID DFCLT BRTHG, ANXIETY & CONFUSION,
CONVULSIONS, LOSS OF CONSCIOUSNESS, RI SK OF PULM EDEMA (FLUID IN
LUNGS) & POSSIBLY DEATH DUE TO CIRCULATORY OR RESP COLLAPSE. SKIN
CONTACT (EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT
Effects of Overexposure:HLTH HAZ: PRODUCES RAPID YELLOW STAINING,
IRRIT, REDNESS, SWELLING, BLISTERS & DELAYED SYMPTOMS IDENTICAL TO
THOSE FROM INHAL DUE TO ABSORPTION THRU SKIN. EYE CONTACT PRODUCES
BURNING PAIN, WATERING & INFLAMMATION OF LIDS. IF INGEST OCCURS,
SYMPTOMS INCLUDE BURNING OF MOUTH & THROAT, SALIVATION, DIZZ,
NAUSEA & (ING 4)
Medical Cond Aggravated by Exposure:POSSIBLY THYROID, LIVER,
CARDIOVASCULAR AND KIDNEY DISEASES.

First Aid:IF FEVERISH, BATHE HEAD & HANDS IN TEPID WATER/WRAP LEGS IN
SOAKED TOWELS. CONSIDER HYPOTHERMIC BATH/BLANKET IF TEPID WATER
INSUFFICIENT. DO NOT GIVE ASPIRIN OR OTHER SALICYLATES. EYES:GENTLY
LIFT LID S & FLUSH IMMED FOR AT LST 15 MIN W/FLOODING AMTS OF WATER
UNTIL TRANSPORTED TO EMER MED FACILITY. DO NOT ALLOW TO RUB OR KEEP
EYES TIGHTLY CLSD. CONSULT MD IMMED. SKIN: QUICKLY REMOVE CONTAMD
(ING 7)

Flash Point:VARIES
Extinguishing Media:FLOOD FIRES WITH WATER. IF WATER IS UNAVAILABLE,
USE DRY CHEMICAL OR DIRT.
Fire Fighting Procedures:USE NIOSH APPRVD SCBA & FULL PROT EQUIP . DO
NOT MOVE CARGO/VEHICHLE IF CARGO HAS BEEN EXPOS TO HEAT. FOR
MASSIVE FIRE IN CARGO AREA USE MONITOR (ING 2)
Unusual Fire/Explosion Hazard:DINITROPHENOL IS HIGHLY EXPLOSIVE IF IT
BECOMES DRY AND IS EXPOSED TO HEAT, FLAME OR SHOCK.

Spill Release Procedures:IMMED NOTIFY SFTY PERS, ISOLATE AREA, DENY
ENTRY & STAY UPWIND. SHUT OFF IGNIT SOURCES. CLEANUP PERS SHOULD
PROTECT AGAINST INHAL & SKIN CONTACT. FOR SM SPILLS, FLUSH AREA
W/FLOODING AMTS OF WATER. FO R LG SPILLS, WET DOWN W/WATER (DO NOT
(ING 15)
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

Handling and Storage Precautions:PREVENT PHYSICAL DAMAGE TO CONTAINERS.
STORE IN COOL, WELL-VENTILATED AREA AWAY FROM HEAT AND IGNITION
SOURCES AND INCOMPATIBLES.
Other Precautions:TO REDUCE POTNTL HLTH HAZS, USE SUFFICIENT DILUTION
OR LOC EXHST VENT TO CTL AIRBORNE CONTAMINANTS & TO MAINTAIN CONCS
AT LOWEST PRACTICAL LEVEL. DURING MFG, MINIMIZE DUST BY INSTALLING
EXHST VENT (W/ APPROP DUST COLLECTION) AT (ING 18)

Respiratory Protection:SEEK PROFESSIONAL ADVICE PRIOR TO RESPIRATOR
SELECTION AND USE. FOLLOW OSHA RESPIRATOR REGULATIONS (29 CFR
1910.134) AND IF NECESSARY, WEAR A NIOSH APPROVED RESPIRATOR.
CONTACT NEHC FOR MORE INFO ON S PECIFIC RESPIRATORS .
Ventilation:PROVIDE GENERAL AND LOCAL EXHAUST VENTILATION. LOCAL
EXHAUST IF PREFERRED.
Protective Gloves:CHEMCIALLY PROTECTIVE GLOVES.
Eye Protection:ANSI APPRVD CHEM WORKERS GOGGS (ING 21)
Other Protective Equipment:ANSI APPRVD EYE WASH & DELUGE SHOWER .
BOOTS, APRONS & GAUNTLETS TO PVNT SKIN CNTCT. DO NOT WEAR LEATHER
(ING 22)
Work Hygienic Practices:NEVER EAT, DRINK OR SMOKE IN WORK AREAS.
PRACTICE GOOD PERSONAL HYGIENE AFTER USING MATL, ESP BEFORE EATING,
(ING 23)
Supplemental Safety and Health
BP: SUBLIMES WHEN CAREFULLY HEATED. MP: 291.2F(144C) (2,3-ISOMER);
233.6F(112C) (2,4-ISOMER); 145.4F(63C) (2,6-ISOMER). VAP DENS
(AIR=1.2 KG/M3 OR 0.075 LBS/F3): 1.243-1.283 KG/M3 OR 0.078-0.080
LBS/F 3. SOL IN H*2O: SLIGHTLY SOLUBLE IN COLD, FREELY IN HOT.

Boiling Pt:B.P. Text:SUPDAT
Melt/Freeze Pt:M.P/F.P Text:SUPDAT
Vapor Pres:10-15 @68F
Vapor Density:SUPDAT
Spec Gravity:1.68 @ 68F(20C)
Solubility in Water:SUPDAT
Appearance and Odor:YELLOW CRYSTALS OR IN SOLN; COLORLESS LIQ BELOW PH
4 & YELLOW LIQ ABOVE PH 4.

Stability Indicator/Materials to Avoid:YES
VOLATILE WITH STEAM & INCOMPATIBLE WITH STRONG OXIDIZERS. 2,4-ISOMER
FORMS EXPLOSIVE SALTS WITH ALKALIES & AMMONIA.
Stability Condition to Avoid:EXPOSURE TO HEAT, FLAME, INCOMPATIBLES OR
SHOCK AND ALLOWING DINITROPHENYL TO BECOME DRY.
Hazardous Decomposition Products:THERMAL OXIDATIVE DECOMPOSITION OF
DINITROPHENOL CAN PRODUCE CARBON DIOXIDE AND TOXIC NITROGEN OXIDES.

Waste Disposal Methods:CONTACT YOUR SUPPLIER OR LICENSED CONTRACTOR FOR
DETAILED RECOMMENDATIONS. FOLLOW APPLICABLE FEDERAL, STATE AND
LOCAL REGULATIONS.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.