Product ID:LEAD-ACID BATTERY
MSDS Date:02/01/1996
FSC:6140
NIIN:00-228-3994
MSDS Number: CFFDC

EXIDE CORP

645 PENN STREET
READING (FORMALLY IN HORSHAM), PA 19612-4205
US

Emergency Phone: 610-378-0500/800-424-9300(CHEMTREC)

Info Phone: 610-378-0550/ FAX -0616

Cage: 20038

PIQUA BATTERY INC

822 PIQUA, OH 45356-2339 US

Telephone: 610-378-0500/0798

Cage: 6W836

INORG LEAD/ELECTROLYTE PRIMARY COMPO OF EVERY BATT MAFG BY

INORGANIC COMPOUNDS INCLUDES INGREDS 2-6.

Fraction By Weight: NP

LEAD (SARA 313) (CERCLA)

CAS: 7439-92-1

RTECS: OF7525000

Fraction By Weight: 53%

OSHA PEL SEE 1910.1025

ACGIH TLV: 0.05MG/M3, A3; 9596

EPA Report Quantity: 1 LB

DOT Report Quantity: 1 LB

ANTIMONY (SARA 313) (CERCLA)

CAS: 7440-36-0

RTECS: CC4025000

Fraction By Weight: 0.2%

OSHA PEL 0.5 MG/M3

ACGIH TLV: 0.5 MG (SB)/M3; 9596

EPA Report Quantity: 5000 LBS

DOT Report Quantity: 5000 LBS

ARSENIC (SARA 313) (CERCLA)

CAS: 7440-38-2

RTECS: CG0525000

Fraction By Weight: 0.003%

OSHA PEL SEE 1910.1018

ACGIH TLV: 0.01 MG/M3, A1; 9596

EPA Report Quantity: 1 LB

DOT Report Quantity: 1 LB

CALCIUM, METAL

CAS: 7440-70-2

RTECS: EV8040000

Fraction By Weight: 0.02%

TIN

CAS: 7440-31-5

RTECS: XP7320000

Fraction By Weight: 0.06%

OSHA PEL 2 MG/M3

ACGIH TLV: 2 MG/M3; 9596

SULFURIC ACID (SARA 302/313) (CERCLA), ELECTROLYTE

CAS: 7664-93-9

RTECS: WS5600000

Fraction By Weight: 30-40%

OSHA PEL 1 MG/M3

ACGIH TLV: 1 MG/M3/3 STEL; 9596

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

CASE MATERIAL INCLUDES INGREDS 9,10.

Fraction By Weight: NP

POLYPROPYLENE,PRINCIPAL CASE MATERIAL OF AUTOMOTIVE AND

CAS: 9003-07-0

RTECS: TR5000000

Fraction By Weight: 5-6%

HARD RUBBER

Fraction By Weight: NP

LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:YES
Health Hazards Acute and Chronic:INHAL:BREATH ACID VAP/MIST CAUSE SEVER
RESP IRRIT.PB DUST/FUME INHAL MAY CAUSE UPPER RESP TRACT/LUNGS
IRRIT.INGEST:ACID MAY CAUSE SEVER MOUTH/THROAT/ESOPHA/STOMA
IRRIT.PB:MAY CAUSE ABD PAIN,NAU,VOMIT, DIARR,SEVERE CRAMP.MAY LEAD
RAPIDLY TO SYST TOXICITY.SKIN:ACID SEVER IRRIT,BURNS,ULCERAT.PB:NOT
ABSORBED.EYE:ACID(SUPPL)
Explanation of Carcinogenicity:PER MSDS:IARC CAT I-STRONG INORG ACID
MIST W/H2SO4(DOESNT APPLY TO LIQ FORM/SOLN IN
BATT);NTP/IARC/OSHA-ARSENIC PROL EXP
Effects of Overexposure:HEALTH:SEVER IRRIT,BURNS,CORNEA
DMG,BLIND.PB:CAUSE IRRIT.OVEREXPO:ACID SEVER SKIN IRRIT,CORNEA
DMG,UPPER RESP IRRIT,TOOTH ENAMEL EROSION,INFLAMM
NOSE/THROAT/BRONC.PB:TOXI SYMPT-HEAD,FTG,ABD PAIN,APPET ITE
LOS,MUSCU ACHES,WEAK,SLEEP DISTURB,IRRITABI,ANEMIA,NEUROPATHY,KID
DMG,REPRODUCTIVE CHANGES IN MALE/FEMALES.
Medical Cond Aggravated by Exposure:H2SO4 MIST OVEREXPO MAY CAUSE LUNG
DMG,AGGRAVATE PULM CONDITIONS.H2SO4 CONTACT W/SKIN MAY AGGRAVATE
SKIN DISEASES-ECZEMA,CONTACT DERM.LEAD/CMPDS CAN AGGRAVATE SOME
FORMS OF KIDN/LIV/NEUROLOGIC DISEASE

First Aid:INHAL:ACID:REMOVE TO FRESH AIR IMMED.DIFFIC BREATH GIVE
OXY.PB:REMOVE FROM EXPO,GARGLE,WASH NOSE/LIPS;CONSULT
DR.INGEST:ACID:GIVE LG QUANT OF H2O.DONT INDUCE VOMIT.CONSULT
DR.PB:CONSULT DR IMMED.SKIN: ACID:FLUSH W/LG AMTS OF H2O FOR @LEAST
15MINS.REMOVE CONTAM CLOTH COMPLETELY INCLUDE SHOES.PB:WASH IMMED
W/SOAP/H2O.EYE:ACID/PB:FLUSH IMMED W/LG AMTS OF H2O FOR @LEAST
15MINS.CONSULT DR.

Flash Point:NA
Lower Limits:4.1 HYDROGEN
Upper Limits:74.2
Extinguishing Media:CO2, FOAM, DRY CHEMICAL.
Fire Fighting Procedures:USE +PRESSURE SCBA.BEWARE OF ACID SPLATTER
DURING H2O APPLICATION,WEAR ACID-RESIST CLOTH/GLOVE/FACE/EYE
PROT.BATT ON CHARGE SHUT OFF POWER TO CHARGING EQPMT(SU)
Unusual Fire/Explosion Hazard:OPERATION BATT GENER/RELEASE FLAMM
H2;ASSUME CONTAIN H2 WHICH IF IGN BY BURN CIGARETTE,NAKE
FLAME,SPARK MAY CAUSE BATT EXPLO W/DISPERSION OF CASING FRAG
(SUPPL)

Spill Release Procedures:STOP MATL FLOW.CONTAIN/ABSORB SM SPILLS
W/DRYSAND,EARTH,VERMI.DONT USE COMBUST MATLS.IF POSSIBLE CAREFULLY
NEUTRA SPILL ACID W/SODA ASH,SODIUM BICARBONATE,LIME,ETC.WEAR
ACID-RESIST CLOTH,BOOTS,GLOVES, FCSHIELD.DONT ALLOW DISCHARGE OF
UNNEUTRA TO SEWER
Neutralizing Agent:ELECTROLYTE(ACID):SODA ASH, SODIUM BICARBONATE,
LIME, ETC.

Handling and Storage Precautions:STORE IN COOL DRY WELL VENTI AREA
W/IMPERV SURFACE/ADQU CONTAIN IN EVENT OF SPILL.STORE UNDER
ROOF-PROTECT AGAINST ADVERSE WEATHER CONDITIONS.
Other Precautions:SEPARATE FRO INCOMP MATLS.STORE/HNDL ONLY IN AREAS
W/ADEQUA H2O SUPPLY/SPILL CNTRL.AVOID DMG TO CNTNR.KEEP AWAY FROM
FIRE/SPARKS/HEAT.IN AREAS WHERE H2SO4 IS HNDL IN CONCEN >1% EMERG
EYEWASH STATIONS/ SHOWERS SHOULD BE PROVIDED W/UNLIMIT H2O

Respiratory Protection:NONE REQUIRED UNDER NORMAL CONDITONS.WHEN
CONCENTRATIONS OF SULFURIC ACID MSIT ARE KNOWN TO EXCEED PEL USE
NIOSHNIOSH APPROVED RESPIRATORY PROTECTION.
Ventilation:STORE/HNDL IN WELL-VENTILATED AREA.IF MECHANICAL
VENTILATION IS USED COMPONENTS MUST BE ACID-RESISTANT.
Protective Gloves:RUBB,PLAST ACID-RESIST W/ELBOW LENG GAUN
Eye Protection:CHEMICAL GOGGLES OR FACE SHIELD.
Other Protective Equipment:WEAR PROT CLOTH WHEN FILL/HNDLF
BATT.ACID-RESIST APRON.UNDER SEVERE EXPO/EMERG CONDITIONS WEAR
ACID-RESIST CLOTH/BOOTS.
Work Hygienic Practices:HNDL BATT CAUT TO AVOID SPILLS.MAKE CERTAIN
VENT CAPS ARE ON SECURELY.AOVID CONTACT W/INTERN COMPO.
Supplemental Safety and Health
FIREFIGHT:NOTE-SERIES CONNECT BATT STILL POSE ELECTR SHOCK EVEN WHEN
OFF. FIRE/EXPLO:CORR LIQ ELECTROLYTE.FOLLOW MFG INSTRUCT FOR
INSTALL/SERV.KEEP AWAY ALL GAS IGN SOURCES,DONT ALLOW METALLIC ART
SIM ULTAN CONTACT -/+ TERM BATT. INCOMP:FLAM H2.PB:STRONG
ACIDS,BASES,HALIDES,HALOGENATES,KNO3,PERM,PEROXIDE,HASC H2,RED AGE

HCC:C1
Boiling Pt:B.P. Text:203F,95C
Melt/Freeze Pt:M.P/F.P Text:NA
Decomp Temp:Decomp Text:NP
Vapor Pres:17-11
Vapor Density:>1
Spec Gravity:1.230-1.350
pH:NP
Viscosity:NP
Evaporation Rate & Reference:<1, BUTYL ACETATE=1
Solubility in Water:100%, COMPLETE
Appearance and Odor:MFG ARTICLE,NO APPARENT ODOR.CLEAR LIQ,SHARP
PENETRATING PUNGENT ODOR.
Percent Volatiles by Volume:NA
Corrosion Rate:NP

Stability Indicator/Materials to Avoid:YES
H2SO4:W/COMBUST/ORG MATL-FIRE/EXPLO.RX VIOLENT W/STRONG RED
AGENTS,METALS,SO3,STRONG OXIDZIER,H2O.METAL PROD SO2,(SUPPL)
Stability Condition to Avoid:PROLONGED OVERCHARGE @HIGH CURRENT;SOURCES
OF IGNITION.
Hazardous Decomposition Products:H2SO4:SO3,CO,H2SO4 MIST,SO2,H2.PB:HI
TEMPS PROD TOXIC METAL FUME/VAP/DUST;STRONG ACID/BASE/NASC H2
CONTACT-ARSINE GAS.

Waste Disposal Methods:SPENT BATT:SENT TO 2ND PB SMELTER-RECYCL.PLACE
NEUTRA SLURRY INTO SEAL CNTNR,DISPO AS HAZ WASTE AS APPLICABLE.LG
H2O DILUT SPILL AFT NEUTRA,TEST SHOULD BE MANAGED IAW APPROV
LOC/STATE/FED REQMTS.CONSU LT STATE ENVIRO AGENCY &/OR FED
EPA.D002,TQ=1000LB

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of Defense. The United States of America in no manner whatsoever,
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disclaims all liability for its use. Any person utilizing this
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assume responsibility for the suitability of this information to their
particular situation.