Product ID:EPM60007, METHOD 601 PURGEABLE (SUPDAT)
MSDS Date:11/16/1993
FSC:6550
NIIN:00N078573
MSDS Number: CFHVZ

EM SCIENCE

480 DEMOCRAT RD
GIBBSTOWN, NJ 08027
US

Emergency Phone: 800-424-9300 (CHEMTREC)

Info Phone: 609-354-9200

Cage: DO242

EM SCIENCE

70 GIBBSTOWN, NJ 08927 US

Telephone: 800-424-9300 (CHEMTREC)

Cage: DO242

CARBON TETRACHLORIDE (SARA 313) (CERCLA)

CAS: 56-23-5

RTECS: FG4900000

Fraction By Weight: 0.02%

OSHA PEL 10 PPM Z-2

ACGIH TLV: S, 5PPM/10 STEL, A3

EPA Report Quantity: 10 LBS

DOT Report Quantity: 10 LBS

CHLOROBENZENE (SARA 313) (CERCLA)

CAS: 108-90-7

RTECS: CZ0175000

Fraction By Weight: 0.02%

OSHA PEL 75 PPM

ACGIH TLV: 10 PPM

EPA Report Quantity: 100 LBS

DOT Report Quantity: 100 LBS

BENZENE, O-DICHLORO-; (1,2-DICHLOROBENZENE) (SARA 313)

CAS: 95-50-1

RTECS: CZ4500000

Fraction By Weight: 0.02%

OSHA PEL C 50 PPM

ACGIH TLV: 25 PPM/50 STEL

EPA Report Quantity: 100 LBS

DOT Report Quantity: 100 LBS

BENZENE, M-DICHLORO-; (1,3-DICHLOROBENZENE) (SARA 313)

CAS: 541-73-1

RTECS: CZ4499000

Fraction By Weight: 0.02%

OSHA PEL N/K

ACGIH TLV: N/K

EPA Report Quantity: 100 LBS

DOT Report Quantity: 100 LBS

BENZENE, P-DICHLORO-; (1,4-DICHLOROBENZENE) (SARA 313)

CAS: 106-46-7

RTECS: CZ4550000

Fraction By Weight: 0.02%

OSHA PEL 75 PPM

ACGIH TLV: 10 PPM, A3

EPA Report Quantity: 100 LBS

DOT Report Quantity: 100 LBS

ETHANE, 1,1-DICHLORO-; (1,1-DICHLOROETHANE) (SARA 313)

CAS: 75-34-3

RTECS: KI0175000

Fraction By Weight: 0.02%

OSHA PEL 100 PPM

ACGIH TLV: 100 PPM

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

ETHANE, 1,2-DICHLORO-; (1,2-DICHLOROETHYLENE) (SARA 313)

CAS: 107-06-2

RTECS: KI0525000

Fraction By Weight: 0.02%

OSHA PEL 50 PPM; Z-2

ACGIH TLV: 10 PPM

EPA Report Quantity: 100 LBS

DOT Report Quantity: 100 LBS

ETHYLENE, 1,1-DICHLORO-; (1,1-DICHLOROETHYLENE) (CERCLA)

CAS: 75-35-4

RTECS: KV9275000

Fraction By Weight: 0.024%

OSHA PEL 1 PPM

ACGIH TLV: 5 PPM/20 STEL

EPA Report Quantity: 100 LBS

DOT Report Quantity: 100 LBS

ETHYLENE, 1,2-DICHLORO-, (E)-; (TRANS-1,2-DICHLOROETHYLENE)

CAS: 156-60-5

RTECS: KV9400000

Fraction By Weight: 0.02%

OSHA PEL N/K

ACGIH TLV: N/K

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

PROPENE, 1,2-DICHLORO-; (CIS-1,3-DICHLOROPROPENE) (SARA

CAS: 78-87-5

RTECS: TX9625000

Fraction By Weight: 0.02%

OSHA PEL 75 PPM

ACGIH TLV: 75 PPM/110 STEL

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

PROPENE, 1,3-DICHLORO-, (Z)-; (TRANS-1-3-DICHLOROPROPENE)

CAS: 10061-01-5

RTECS: UC8325000

Fraction By Weight: 0.02%

OSHA PEL N/K

ACGIH TLV: N/K

PROPENE, 1,3-DICHLORO-, (E)-; (TRANS-1,3-DICHLOROPROPENE)

CAS: 10061-02-6

RTECS: UC8320000

Fraction By Weight: 0.02%

OSHA PEL N/K

ACGIH TLV: N/K

METHANE, DICHLORO-; (METHYLENE CHLORIDE) (SARA 313)

CAS: 75-09-2

RTECS: PA8050000

Fraction By Weight: 0.02%

OSHA PEL 500 PPM; Z-2

ACGIH TLV: 50 PPM, A2

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

ETHANE, 1,1,2,2-TETRACHLORO-; (1,1,2,2-TETRACHLOROETHANE)

CAS: 79-34-5

RTECS: KI8575000

Fraction By Weight: 0.02%

OSHA PEL S, 5 PPM

ACGIH TLV: S, 1 PPM

EPA Report Quantity: 100 LBS

DOT Report Quantity: 100 LBS

ETHYLENE, TETRACHLORO-; (TETRACHLOROETHYLENE) (SARA 313)

CAS: 127-18-4

RTECS: KX3850000

Fraction By Weight: 0.02%

OSHA PEL 100 PPM, Z-2

ACGIH TLV: 25 PPM/100 STEL, A3

EPA Report Quantity: 100 LBS

DOT Report Quantity: 100 LBS

ETHANE, 1,1,1-TRICHLORO-; (1,1,1-TRICHLOROETHANE) (SARA

CAS: 71-55-6

RTECS: KJ2975000

Fraction By Weight: 0.02%

OSHA PEL 350 PPM

ACGIH TLV: 350 PPM/450 STEL

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

ETHANE, 1,1,2-TRICHLORO-; (1,1,2-TRICHLOROETHANE) (SARA

CAS: 79-00-5

RTECS: KJ3150000

Fraction By Weight: 0.02%

OSHA PEL S, 10 PPM

ACGIH TLV: S, 10 PPM

EPA Report Quantity: 100 LBS

DOT Report Quantity: 100 LBS

ETHYLENE, TRICHLORO-; (TRICHLOROETHYLENE) (SARA 313)

CAS: 79-01-6

RTECS: KX4550000

Fraction By Weight: 0.02%

OSHA PEL 100 PPM; Z-2

ACGIH TLV: 50 PPM/100 STEL, A5

EPA Report Quantity: 100 LBS

DOT Report Quantity: 100 LBS

METHYL ALCOHOL (METHANOL) (SARA 313) (CERCLA)

CAS: 67-56-1

RTECS: PC1400000

Fraction By Weight: 99.64%

OSHA PEL S, 200 PPM

ACGIH TLV: S, 200 PPM/250 STEL

EPA Report Quantity: 5000 LBS

DOT Report Quantity: 5000 LBS

HAVE BEEN RPTD FROM PRLNGD EXPOS TO METHYL ALCOHOL

RTECS: 9999999ZZ

AND CONTAINERIZE FOR PROPER DISPOSAL.

RTECS: 9999999ZZ

SPECIFIED CNDTNS. ENGINEERING &/OR ADMINISTRATION

RTECS: 9999999ZZ

& FULL LENGTH FACESHIELD .

RTECS: 9999999ZZ

LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:CHLOROCARBON MATLS HAVE PRDCED SENSIT
OF MYOCARDIUM TO EPINEPHRINE IN LAB ANIMALS & COULD HAVE A SIMILAR
EFT IN HUMANS. ADRENOMIMETICS (E.G. EPINEPHRINE) MAY BE
CONTRAINDICATED EXCEPT FOR LIFE-SUSTAIN ING USES IN HUMANS ACUTELY
OR CHRONICALLY EXPOS TO CHLOROCARBONS . ACUTE:TOX BY INGEST &
INHAL. (ETS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT.
Effects of Overexposure:HLTH HAZ:CAN BE TOX BY SKIN ABSORP. AFTER
INGEST/INHAL, INITIAL SYMPS MAY BE ONLY THAT OF MILD INTOXICATION,
BUT MAY BECOME SEV AFTER 12-18 HRS. AFFECTS CNS, ESPECIALLY OPTIC
NERVE. MARKED IMPAIRMENT OF VISION & ENLARGEMENT OF LIVER HAS BEEN
RPTD W/CHRONIC EXPOS. CHRONIC EXPOS MAY ALSO CAUSE DMG TO KIDNEYS
(SUPDAT)
Medical Cond Aggravated by Exposure:SKIN CONDITIONS, EYE PROBLEMS,
IMPAIRED LIVER OR KIDNEY FUNCTION.

First Aid:GET MED ASSISTANCE FOR ALL CASES OF OVEREXP. SKIN:IMMED FLUSH
THORO W/LG AMTS OF WATER. EYES:IMMED FLUSH THORO W/WATER FOR @ LST
15 MINS. INHAL:REMOVE TO FRESH AIR; GIVE ARTF RESP IF BRTHG HAS
STOPPED . INGEST:IF CONSCIOUS, DRINK WATER & INDUCE VOMIT IMMED AS
DIRECTED BY MED PERS. NEVER GIVE ANYTHING BY MOUTH TO UNCON PERSON.
REMOVE CONTAMD CLTHG & WASH BEFORE REUSE.

Flash Point Method:TCC
Flash Point:52.0F,11.1C
Lower Limits:6.7%
Upper Limits:36.5%
Extinguishing Media:USE WATER SPRAY, FOAM, DRY CHEMICAL, OR CO*2.
Fire Fighting Procedures:WEAR NIOSH APPROVED PRESSURE DEMAND SCBA &
FULL PROTECTIVE EQUIPMENT .
Unusual Fire/Explosion Hazard:THERM DECOMP PROD MAY INCLUDE HCL &
PHOSGENE . DANGEROUS FIRE & EXPLO HAZ. CLSD CNTNRS MAY EXPLODE UPON
HEATING. VAP CAN TRAVEL DIST TO IGNIT (SUPDAT)

Spill Release Procedures:EVAC AREA OF ALL UNNEC PERS. WEAR SUITABLE
PROT EQUIP LISTED UNDER EXPOSURE/PERSONAL PROT. ELIMINATE ANY IGNIT
SOURCES UNTIL AREA IS DETERM TO BE FREE OF EXPLO/FIRE HAZS. CONTAIN
RELEASE & ELIM ITS SO URCE, IF CAN BE DONE W/OUT RISK. TAKE UP (ING
21)
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

Handling and Storage Precautions:KEEP CNTNR CLSD. STORE IN COOL AREA
AWAY FROM IGNIT SOURCES & OXIDIZERS. DO NOT BREATH VAP/MIST. DO NOT
GET IN EYES, ON SKIN, OR ON CLOTHING.
Other Precautions:ELECTRICALLY GROUND ALL EQUIPMENT WHEN HANDLING THIS
PRODUCT. NO SMOKING IN AREA OF USE. DO NOT USE IN GEN VICINITY OF
ARC WELDING, OPEN FLAMES OR HOT SURFACES. HEAT &/OR UV RADIA MAY
CAUSE FORMATION OF HCL &/OR PHOSGENE .

Respiratory Protection:IF WORKPLACE WXPOS LIMIT(S) OF PROD/ANY
COMPONENT IS EXCEEDED (SEE TLV/PEL), NIOSH APPRVD AIR SUPPLIED RESP
IS ADVISED IN ABSENCE OF PROPER ENVIR CONTROL. OSHA REGS ALSO
PERMIT OTHER NIOSH APPRVD RESP S (NEG PRESS TYPE) UNDER (ING 22)
Ventilation:MATERIAL SHOULD BE HANDLED OR TRANSFERRED IN AN APPRVD FUME
HOOD/WITH ADEQUATE VENTILATION.
Protective Gloves:BUTYL RUBB, VITON OR EQUIVALENT GLOVES.
Eye Protection:ANSI APPRVD CHEM WORKERS GOGGS (ING 23)
Other Protective Equipment:ANSI APPRVD EYE WASH & DELUGE SHOWER .
Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING. DO NOT TAKE
INTERNALLY.
Supplemental Safety and Health
MFR TRADE NAME/PART NO:HALOCARBONS-LIQ. EXPLO HAZ:SOURCE & FLASH BACK.
EFTS OF OVEREXP:& CNS. CAUSES DIZZ, NAUS, MUSCLE WEAK, NARCOS, RESP
FAILURE. INGEST CAN PRDCE BLNDNESS (AS LITTLE AS 30ML/DEATH ( AS
LITTLE AS 100ML). PRLNGD/RPTD SKIN CONT MAY CAUSE IRRIT. FETAL
DEVELOPMENT ABNORMAL & EFTS ON EMBRYO/FETUS (ING 20)

Boiling Pt:B.P. Text:149F,65C
Melt/Freeze Pt:M.P/F.P Text:-144F,-98C
Vapor Pres:97 @ 20C
Vapor Density:1.1
Spec Gravity:0.791 (H*2O=1)
Evaporation Rate & Reference:5.9 (BUAC =1)
Solubility in Water:SOLUBLE
Appearance and Odor:CLEAR LIQUID.
Percent Volatiles by Volume:99.9+

Stability Indicator/Materials to Avoid:YES
ACIDS, OXIDIZERS, OTHER:REACTIVE METALS.
Stability Condition to Avoid:HEAT; CONTACT WITH IGNITION SOURCES.
Hazardous Decomposition Products:HCL & PHOSGENE . CO*X, FORMALDEHYDE.

Waste Disposal Methods:COMPLY WITH FEDERAL, STATE, AND LOCAL
REGULATIONS.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.