Product ID:50-363 BLACK STENCIL
MSDS Date:12/28/1989
FSC:7510
NIIN:00-469-7910
MSDS Number: CFMZK

NILES CHEMICAL PAINT COMPANY

225 FORT STREET
NILES, MI 49120

Emergency Phone: (616) 236-5856

Info Phone: (616) 683-3377

Preparer: MICHAEL LICHATOWICH

Cage: 02388

NILES CHEMICAL PAINT

307 NILES, MI 49120 US

Telephone: 616-683-3377/219-236-5856

Cage: 02388

PROPANE/ISOBUTANE (VP = 4400 @ 20C)

CAS: 68476-86-8

Fraction By Weight: 30.0%

OSHA PEL 1000 PPM

ACETONE (SARA III) (VP = 180 @ 20C)

CAS: 67-64-1

RTECS: AL3150000

Fraction By Weight: 26.0%

OSHA PEL 1000 PPM

ACGIH TLV: 750 PPM/STEL 100

EPA Report Quantity: 5000 LBS

DOT Report Quantity: 5000 LBS

TOLUENE (SARA III) (VP = 22 @ 20C)

CAS: 108-88-3

RTECS: XS5250000

Fraction By Weight: 10.0%

OSHA PEL 200 PPM

ACGIH TLV: 100 PPM/STEL 150

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

XYLENE (SARA III) (VP = 7.0 @ 20C)

CAS: 1330-20-7

RTECS: ZE2100000

Fraction By Weight: 9.0%

OSHA PEL 100 PPM

ACGIH TLV: 100 PPM/STEL 150

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

RESIN

Fraction By Weight: 6.05%

MINERAL SPIRITS (VP = 2 @ 20C)

CAS: 8052-41-3

RTECS: WJ8925000

Fraction By Weight: 2.0%

OSHA PEL 500 PPM

ACGIH TLV: 100 PPM

METHYL ISOBUTYL KETONE (SARA III) (VP = 15 @ 20C)

CAS: 108-10-1

RTECS: SA9275000

Fraction By Weight: 2.0%

OSHA PEL 100 PPM

ACGIH TLV: 50 PPM/STEL 75

EPA Report Quantity: 5000 LBS

DOT Report Quantity: 5000 LBS

COBALT COMPOUNDS (SARA III)

CAS: 7440-48-4

RTECS: GF8750000

Fraction By Weight: <1.0%

OSHA PEL 0.1 MG/M3

ACGIH TLV: 2 MG/M3

PROPRIETARY INGREDIENTS

Fraction By Weight: BALANCE

Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:EYE: IRRITATION. SKIN: REDNESS,
IRRITATION, DEFATTING & DERMATITIS. INHAL: IRRITATION, CNS
DEPRESSION, DIZZINESS, NAUSEA, HEADACHE, VERTIGO, UNCONSCIOUSNESS &
ASPHYXIATION.*
Explanation of Carcinogenicity:NONE
Effects of Overexposure:* CHRONIC: EYE IRRITATION, BRAIN/NS DAMAGE,
DISORIENTATION, FROSTBITE, NARCOSIS, COMA, INCOHERENCE, CORNEAL
VACUOLIZATION, ANOREXIA, EUPHORIA, NERVOUSNESS, INSOMNIA,
PARESTHESIA, PHOTOPHOBIA. MAY AFFE CT RESPIRATORY SYSTEM, SKIN,
CNS, EYES,GI TRACT, BLOOD, LIVER & KIDNEYS.

First Aid:INHAL: REMOVE TO FRESH AIR. PROVIDE OXYGEN IF BREATHING IS
DIFFICULT. IF BREATHING HAS STOPPED, PERFORM ARTIFICIAL
RESPIRATION. SKIN: WASH W/SOAP & WATER. REMOVE CONTAM CLOTHES, WASH
BEFORE REUSE. EYE S: FLUSH W/LARGE AMOUNTS OF WATER FOR AT LEAST 15
MINS. LIFT LIDS. OBTAIN MEDICAL ATTENTION IN ALL CASES.

Flash Point Method:CC
Flash Point:<-104F,<-76C
Autoignition Temp:Autoignition Temp Text:806F
Lower Limits:0.8
Upper Limits:12.0
Extinguishing Media:DRY CHEMICAL, FOAM, CO2.
Fire Fighting Procedures:WEAR SELF-CONTAINED BREATHING APPARATUS W/FULL
FACEPIECE OPERATED IN POSITIVE PRESSURE MODE & FULL PROTECTIVE
CLOTHING.
Unusual Fire/Explosion Hazard:CANS RUPTURE FROM INTERNAL PRESSURE AT
190F. VAPORS >AIR. MAY TRAVEL ALONG GROUND TO IGNITION SOURCE.

Spill Release Procedures:ELIMINATE IGNITION SOURCES. AVOID VAPOR
BREATING/SKIN CONTACT. ABSORB. SHOVEL RECLAIMED LIQUID & ABSORBENT
INTO RECOVERY OR SALVAGE DRUMS FOR DISPOSAL.

Handling and Storage Precautions:DONT STORE >120F. STORE LARGE AMOUNTS
IN AREAS DESIGNED FOR NFPA CLASS 1A FLAMMABLE LIQUIDS. DONT SPRAY
IN EYES. DONT STICK SHARP OBJECTS INTO OPENING
Other Precautions:ON TOP OF CAN. DONT PUNCTRUE/INCINERATE CAN. DONT LET
FINGER PROTRUDE OVER FRONT OF SPRAY BUTTON. INTENTIONAL MISUSE BY
DELIBERATELY CONCENTRATING & INHALING CONTENTS MAY BE HARMFUL OR
FATAL. DONT WEA R CONTACTS WHEN WORKING W/THIS MATERIAL.

Respiratory Protection:USE NIOSH/MSHA RESPIRATORY PROTECTION. EVACUATE
AREA IF NECESSARY.
Ventilation:SUFFICIENT.
Protective Gloves:NONE REQUIRED
Eye Protection:NONE REQUIRED
Other Protective Equipment:NONE REQUIRED
Work Hygienic Practices:WASH HANDS AFTER USE & BEFORE EATING, SMOKING,
OR USING RESTROOM.
Supplemental Safety and Health
NK

Boiling Pt:B.P. Text:<0.0F
Decomp Temp:Decomp Text:NOT EST.
Vapor Density:>AIR
Viscosity:55 +- 5 Z#1
Evaporation Rate & Reference:SLOWER THAN ETHER
Solubility in Water:NA
Appearance and Odor:VAPOR, ODOR OF SOLVENTS
Percent Volatiles by Volume:90.76

Stability Indicator/Materials to Avoid:YES
NK
Hazardous Decomposition Products:HYDROGEN CHLORIDE, CO & PHOSGENE

Waste Disposal Methods:IN ACCORDANCE W/LOCAL, STATE, & FEDERAL
REGULATIONS. EPA #D001 (IGNITABLE).

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.