Product ID:JP-8
MSDS Date:12/03/1996
FSC:9130
NIIN:01-429-4563
MSDS Number: CFRBN

DIAMOND SHAMROCK REFINING CO L.P.

9830 COLONADE BLVD
SAN ANTONIO, TX 78269-6000
US

Emergency Phone: 210-979-8346

Info Phone: 210-530-8680

Cage: 3P045

DIAMOND SHAMROCK REFINING AND MARKETING CO

696000 SAN ANTONIO, TX 78269-6000 US

Telephone: 210-641-8601

Cage: 3P045

100

CAS: 8008-20-6

RTECS: OA5500000

Fraction By Weight: >97%

OSHA PEL N/K

ACGIH TLV: N/K

NAPHTHALENE (SARA 313) (CERCLA)

CAS: 91-20-3

RTECS: QJ0525000

Fraction By Weight: <1%

OSHA PEL 10 PPM

ACGIH TLV: 10 PPM;15 STEL

EPA Report Quantity: 100 LBS

DOT Report Quantity: 100 LBS

WHICH MAY RSLT IN NAUS & VOMIT; CNS DEPRESS

RTECS: 9999999ZZ

EXPER HAS SHOWN NO MAJOR

RTECS: 9999999ZZ

NIOSH RECS THAT WHOLE DIESEL EXHST BE REGARDED AS

RTECS: 9999999ZZ

FUMES MAY BE GENERATED. PROD IS SIMILAR TO DIESEL

RTECS: 9999999ZZ

INSTITUE HAS SHOWN THAT SIMILAR NAPHTHA PRODS

RTECS: 9999999ZZ

SKIN CANCERS IN LAB MICE. ONLY WEAK TO MOD RESPONSE

RTECS: 9999999ZZ

IS POTNTL IRRIT TO EYES, SKIN & LUNGS & MAY CAUSE

RTECS: 9999999ZZ

REPORTS OF OPTICAL NEURITIS, CATARACTS & CORNEAL

RTECS: 9999999ZZ

TO ING 2. SEV HEMOLYTIC ANEMIA, PROD OF HEINZ

RTECS: 9999999ZZ

CARBON

RTECS: 9999999ZZ

JET ENGINE EXHST & OTHER FORMS OF HYDROCARBON

RTECS: 9999999ZZ

HDCH, NAUS, VOMIT, INCR CARDIAC OUTPUT & CONFUSN.

RTECS: 9999999ZZ

HEART/BRAIN DMG &/OR DEATH. EXPOS TO HIGH CONCS OF

RTECS: 9999999ZZ

AVAILABLE OXYGEN. COMBUST OF THIS & OTHER SIMILAR

RTECS: 9999999ZZ

NEVER

RTECS: 9999999ZZ

NOT INDUCE VOMIT. IF VOMIT OCCURS SPONT, KEEP AIRWAY

RTECS: 9999999ZZ

INDUCE VOMIT, USE GASTRIC LAVAGE ONLY. ASPIR OF LIQ

RTECS: 9999999ZZ

IS NOT ADVISED. TREAT SYMPTOMATICALLY.

RTECS: 9999999ZZ

WASTE IF FLASH POINT IS <140F REQUIRING

RTECS: 9999999ZZ

AGENCIES SHOULD BE CONTACTED TO ASSURE PROPER ACTION

RTECS: 9999999ZZ

KEROSENE, BOTH ACTIVE & PASSIVE MONITORS

RTECS: 9999999ZZ

AVG MOLECULAR WT OF 170 HAS BEEN SUGGESTED AS AVG

RTECS: 9999999ZZ

DIRECT READING COLORIMETRIC TUBES ARE AVAILABLE TO

RTECS: 9999999ZZ

LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:ACUTE:CNS DEPRESS W/EXTREME OVEREXP;
EFTS MAY INCL ANESTH, COMA, RESP ARREST, IRREG HEART RATE, COUGH &
RAPIDLY DEVEL PULM EDEMA AT HIGH CONCS. OXYG DEPRIVATION IS POSS IF
WORKING IN CONFINED SPACES. INHAL:IRRIT OF UPPER RESP TRACT W/CNS
DEPRESS, DIZZ, HDCH, INCOORD, ANESTH, COMA, RESP ARREST, COUGH &
(EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT
Effects of Overexposure:HLTH HAZ:RAPIDLY DEVEL PULM EDEMA AT HIGH
CONCS. SKIN CONT:DEFAT MAY OCCUR W/CONTINUED & PRLNG CONT. IRRIT &
BURNING SENSATION MAY OCCUR ON EXPOS TO LIQ/MISTS. SKIN
ABSORPTION:NOT SIGNIFICANT. EYE CON T:SEV BURNING SENSATION
W/TEMPORARY IRRIT & SWELL OF LIDS. INGEST:IRRIT OF MUC MEMBS OF
THROAT, ESOPHAGUS & STOM (ING 3)
Medical Cond Aggravated by Exposure:MED CNDTNS WHICH HAVE SAME SYMPS &
EFTS AS THOSE OUTLINED UNDER HLTH HAZ INFO SECTION CAN BE
AGGRAVATED BY EXPOS TO THIS PROD. PERS W/CONGENITAL DEFICIENCY OF
ERYTHROCYTE GLUCOSE-6-PHOSPHATE (SUPDAT)

First Aid:EYES:IMMED FLUSH W/LG AMT OF WATER FOR AT LST 15 MINS HOLDING
LIDS APART TO ENSURE FLUSHING OF ENTIRE SURF. SEEK MED ATTN.
SKIN:WASH CONTAM AREAS W/PLENTY OF SOAP & WATER. SOOTHING OINTMENT
MAY BE APP LIED TO IRRIT AFTER THORO CLEANSING. REMOVE CONTAM CLTHG
& FOOTWEAR. SEEK MED ATTN. INHAL:GET PERS OUT OF CONTAM AREA TO
FRESH AIR. IF BRTHG HAS STOPPED RESUSCITATE & ADMIN OXYG IF READILY
(ING 17)

Flash Point Method:PMCC
Flash Point:>144F,>62C
Lower Limits:0.6%
Upper Limits:5%
Extinguishing Media:DRY CHEMICAL, FOAM OR CARBON DIOXIDE. WATER SPRAY
MAY BE INEFFECTIVE ON BURNING PRODUCT.
Fire Fighting Procedures:USE NIOSH APPROVED SCBA & FULL PROTECTIVE
EQUIPMENT .
Unusual Fire/Explosion Hazard:CLOTHING, RAGS OR SIMILAR ORGANIC MATL
CONTAMINATED W/PROD & STORED IN CLSD SPACE MAY UNDERGO SPONT
COMBUST. TRANSFER PROD TO & FROM COMMONLY GROUNDED CNTNRS.

Spill Release Procedures:IF MATL IS SPILLED/RELS TO ATM, STEPS SHOULD
BE TAKEN TO CONTAIN LIQ & PVNT DISCHARGES TO STREAMS/SEWER SYS; &
CONTROL/STOP LOSS OF VOLAT MATLS TO ATM. SPILLS/RELS SHOULD BE
REPORTED, IF REQD, TO APPR OP LOC, STATE & FED REGULATORY AGENCIES.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

Handling and Storage Precautions:PROT AGAINST PHYSICAL DMG. SEPARATE
FROM OXIDIZING MATLS. STORE IN COOL, WELL-VENTED AREAS OF
NON-COMBUST CONSTRUCTION AWAY FROM POSS IGNIT SOURCES.
Other Precautions:OUTSIDE/DETACHED STOR IS PREF. CONTAM CLTHG SHOULD BE
STORED IN WELL VENTED AREAS & PRECS TAKEN FOR POSS SPONT COMBUST.
NO APPLIC BIOLOGICAL MONITORING EXPOS PROC, BREATH ANALYSIS FOR
HYDROCARBONS HAS BEEN SUGGESTED. MONITOR FOR (ING 23)

Respiratory Protection:RESP PROT IS NOT REQD UNLESS PRODUCT IS HEATED
ABOVE IT'S FLASHPOINT/SPRAYED; USE NIOSH APPROVED RESPIRATORY PROT
WHERE SPRAY, MISTS, VAPORS MAY BE GENERATED; FOLLOWING MFR'S RECS.
NIOSH APPRVD SUPPLI ED AIR RESP PROT IS REQD FOR IDLH AREAS.
Ventilation:WORK IN WELL VENTED AREAS; USE GOOD ENGINEERING TO PROCESS,
TRANSFER & STORE; SPECIAL VENT IS NOT REQD UNLESS (SUPDAT)
Protective Gloves:IMPERMEABLE GLOVES.
Eye Protection:ANSI APPRVD CHEM WORKERS GOGGS &(SUPDAT)
Other Protective Equipment:EYE WASH FOUNTAIN & DELUGE SHOWER WHICH MEET
ANSI DESIGN CRITERIA .
Work Hygienic Practices:CLTHG CONTAM W/THIS PROD SHOULD BE REMOVED,
WASHED IN SOAP & WATER & DRIED BEFORE REUSE. SHOES WHICH HAVE BEEN
(SUPDAT)
Supplemental Safety and Health
MED CNDTNS:DEHYDROGENASE ACTIVITY ARE HYPERSUSCEPTIBLE TO HEMOLYTIC
EFTS OF NAPHTHALENE. VENT:PROD IS HEATED ABOVE IT'S
FLASHPOINT/SPRAYED; GOOD ENGINEERING CONTROLS ARE REQD IN HIGH VOL
USES. EYE PRO T:FULL LGTH FSHLD . HYGIENE PRACT:CONTAM W/THIS PROD
& CAN NOT BE DECONTAM SHOULD BE DISCARDED.

Boiling Pt:B.P. Text:>360F,>182C
Spec Gravity:0.822 (H*2O=1)
Solubility in Water:TRACE
Appearance and Odor:COLORLESS LIQUID W/AROMATIC ODOR; ODOR THRESHOLD 1
PPM & IS NOT INDEX OF EXPOS.
Percent Volatiles by Volume:100

Stability Indicator/Materials to Avoid:YES
AVOID CONTACT W/STRONG OXIDIZERS SUCH AS CHLORINE, CONCENTRATED OXYGEN
& SODIUM HYPOCHLORITE OR OTHER HYPOCHLORITES.
Stability Condition to Avoid:AVOID SOURCES OF IGNITION SUCH AS FLAMES,
HOT SURFACES, ELECTRICAL OR FUNCTIONAL SPARKS, ETC.
Hazardous Decomposition Products:THERMAL DECOMPOSITION PRODUCTS MAY
INCLUDE CARBON MONOXIDE & CARBON DIOXIDE.

Waste Disposal Methods:CLEAN-UP ACTION SHOULD BE CAREFULLY PLANNED &
EXECUTED. SHIPMENT, STOR &/OR DISP OF WASTE MATLS ARE REGULATED &
ACTION TO HANDLE/DISP OF SPILLED/RELS MATLS MUST MEET ALL APPLIC
LOC, STATE & FED RULES & REGS. WASTE PRODS WILL BE CONSIDERED
HAZ(ING 21)

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.