Product ID:ROUNDUP PRO HERBICIDE, 425200
MSDS Date:11/30/1995
FSC:6840
NIIN:00N081614
MSDS Number: CFSSG

VAN WATERS & ROGERS INC

6100 CARILLON POINT
KIRKLAND, WA 98033
US

Emergency Phone: 800-424-9300 (CHEMTREC)

Info Phone: 206-889-3712

Cage: DO735

VOPAK USA INC

KIRKLAND, WA 98033-7357 US

Telephone: 425-889-3400/425-889-3617

Cage: 0STM5

GLYCINE, N-(PHOSPHONOMETHYL)-, COMPD WITH 2-PROPANAMINE

CAS: 38641-94-0

RTECS: MC1080000

Fraction By Weight: <41%

OSHA PEL N/K

ACGIH TLV: N/K

1);

CAS: 38641-94-0

RTECS: MC1080000

Fraction By Weight: <41%

OSHA PEL N/K

ACGIH TLV: N/K

INERT INGREDIENTS (INCLUDING SURFACTANTS)

Fraction By Weight: 59%

OSHA PEL N/K

ACGIH TLV: N/K

PHOSPHATE ESTER NEUTRALIZED POLYETHOXYLATED TALLOWAMINE

Fraction By Weight: 14.5%

OSHA PEL N/K

ACGIH TLV: N/K

EXPOS (3 WK) TO GLYPHOSATE, SLIGHT SKIN IRRIT WAS

RTECS: 9999999ZZ

EYE CHANGES WERE OBSERVED AT HIGH-DOSE LEVEL IN ONE

RTECS: 9999999ZZ

FED CONTINUOUSLY TO RATS AT VERY HIGH DOSE, LEVEL

RTECS: 9999999ZZ

LINED CONTRS. DO NOT MIX, STORE/APPLY IN

RTECS: 9999999ZZ

OR SPRAY TANKS. REACTS W/SUCH CONTRS & TANKS TO

RTECS: 9999999ZZ

THIS GAS MIX COULD FLASH/EXPLODE, CAUSING SERIOUS

RTECS: 9999999ZZ

TORCH, LIGHTED CIGARETTE OR OTHER IGNITION SOURCES.

RTECS: 9999999ZZ

FLOOR/OTHER IMPERVIOUS SURF SHOULD BE

RTECS: 9999999ZZ

OTHER ABSORB CLAYS. COLLECT CONTAM ABSORB, PLACE IN

RTECS: 9999999ZZ

UNDER DISP. THORO SCRUB FLOOR/OTHER IMPERVIOUS SURF

RTECS: 9999999ZZ

THAT SOAK INTO GROUND SHOULD BE DUG UP, PLACED IN

RTECS: 9999999ZZ

UNDER DISP. CONT APPROP STATE AGENCY WHEN

RTECS: 9999999ZZ

BE SEPARATED FROM NON-LEAKING & EITHER CONTR/ITS

RTECS: 9999999ZZ

DISP OF I/A/W INSTRUCTIONS PROVIDED IN DISP. ANY

RTECS: 9999999ZZ

APPROVAL NUMBER TC-14C. FULL FACEPIECE REPLACES

RTECS: 9999999ZZ

SPECIFIED BY MFRS. RESP PROT PROGRAMS MUST COMPLY

RTECS: 9999999ZZ

RESPS ARE NOT REQUIRED FOR USE OF

RTECS: 9999999ZZ

HANDLERS MUST WEAR LONG-SLEEVED SHIRT,

RTECS: 9999999ZZ

FOR CLEANING/MAINTAINING PPE. IF NO SUCH

RTECS: 9999999ZZ

KEEP AND WASH PPE SEPARATELY FROM OTHER LAUNDRY.

RTECS: 9999999ZZ

IF PESTICIDE GETS INSIDE. THEN WASH

RTECS: 9999999ZZ

LD50 LC50 Mixture:LD50 (ORAL RAT): >5,000 MG/KG.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:ACUTE (BASED ON TOX STUDIES): EYE: MAY
CAUSE PAIN, REDNESS & TEARING. SKIN: SLIGHTLY TOX & SLIGHTLY IRRIT.
INGEST: SLIGHTLY TOX. NO SIGNIFICANT ADVERSE HLTH EFTS ARE EXPECTED
TO DEVELOP IF ONLY SML AM TS (< MOUTHFUL) ARE SWALLOWED. INGEST OF
SIMILAR FORMULATIONS HAS BEEN REPORTED TO PRDCE GI DISCOMFORT (EFTS
OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT.
Effects of Overexposure:HLTH HAZ: W/IRRIT OF MOUTH, NAUS, VOMIT &
DIARR. ORAL INGEST OF LGE QTYS OF ONE SIMILAR PROD HAS BEEN
REPORTED TO RSLT IN HYPOTENSION & LUNG EDEMA. INHAL: SLIGHTLY TOX.
TOX INFO: EYE IRRIT: RABBIT; MO D IRRIT; ALL ANIMALS FREE OF IRRIT
BY DAY 7, FIBRA CATEGORY IV. ING 1: IN REPEAT DOSING STUDIES (6
MONTH), (SUP DAT)
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.

First Aid:EYES: FLUSH W/PLENTY OF WATER FOR AT LEAST 15 MINUTES. GET
MED ATTN IF IRRIT PERSISTS. INHAL: REMOVE TO FRESH AIR. IF NOT
BREATHING, GIVE ARTIFICIAL RESPIRATION, PREFERABLY MOUTH-TO-MOUTH.
GET MED ATT N. SKIN: FLUSH W/COPIOUS AMOUNTS OF WATER. SEE MD .
INGEST: CALL MD IMMED . FOR ADDITIONAL HUMAN EMERGENCY FIRST
AID/TREATMENT GUIDANCE, CALL COLLECT, ANYTIME, DAY/NIGHT (314)
694-4000.

Flash Point Method:PMCC
Flash Point:>200F,>93C
Extinguishing Media:WATER SPRAY, FOAM, DRY CHEMICAL, CARBON DIOXIDE, OR
ANY CLASS B EXTINGUISHING AGENT.
Fire Fighting Procedures:WEAR NIOSH APPROVED SCBA & FULL PROTECTIVE
EQUIPMENT . EQUIPMENT SHOULD BE THOROUGHLY CLEANED AFTER USE.
Unusual Fire/Explosion Hazard:NONE.

Spill Release Procedures:OBSERVE ALL PROT & SFTY PREC WHEN CLEANING UP
SPILLS. SML SPILL: FOR SPILL <1 GAL ON FLOOR/OTHER IMPREVIOUS SURF,
SOAK UP W/TOWELS/OTHER ABSORB MATL & DISCARD IN TRASH. CLEAN SPILL
AREA W/SOAP & WATER & RINSE ARE THORO. LGE LIQ SPILL: ON THE (ING
12)
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

Handling and Storage Precautions:AVOID CONTACT WITH EYES OR CLOTHING.
AVOID BREATHING VAPOR OR SPRAY MIST.
Other Precautions:DO NOT APPLY DIRECTLY TO WATER, TO AREAS WHERE SURF
WATER IS PRESENT/TO INTERTIDAL AREAS BELOW MEAN HIGH WATER MARK. DO
NOT CONTAM WATER WHEN DISP OF EQUIP WASHWATERS. DO NOT CONTAM
WATER, FOODSTUFFS, FEED/SEED BY STOR/DISP.

Respiratory Protection:IN EVENT OF ABNORM EXPOS CNDTNS, USE NIOSH
APPRVD EQUIP. IN WORK SITUATIONS WHERE AIR PURIFYING ELEMENTS FOR
PROT AGAINST ORG VAP & DUST/MIST APPRVD FOR PESTICIDES IS REC. USE
CARTRIDGES W/NIOSH APPRV D NUMBER TC-23C/CANISTER W/NIOSH(ING 19)
Ventilation:NO SPECIAL PRECAUTIONS ARE RECOMMENDED.
Protective Gloves:IMPERVIOUS GLOVES .
Eye Protection:ANSI APPRVD CHEM WORKERS GOGGLES .
Other Protective Equipment:ANSI APPRVD EMER EYEWASH & DELUGE SHOWER .
WEAR APPROP PROT CLTHG TO PVNT SKIN CONT. APPLICATORS & OTHER (ING
22)
Work Hygienic Practices:WASH HANDS BEFORE EATING, DRINKING, CHEWING
GUM, USING TOBACCO/USING THE TOILET. REMOVE CLOTHING IMMEDIATELY
(ING 25)
Supplemental Safety and Health
PH: 4.99 (1% SOLN). EFTS OF OVEREXP: DOGS FED MON 0139 EXHIBITED SLIGHT
BODY WT CHANGES. FOLLOWING RPTD SKIN EXPOS (3-WK) TO MON 0139, SKIN
IRRIT AS PRIMARY EFT IN RABBITS. FOLLOWING RPTD EXPOS (90 DA YS) TO
GLYPHOSATE IN THEIR FEED, DECRD WT GAINS WERE NOTED AT HIGHEST TEST
LEVEL IN MICE. FOLLOWING RPTD SKIN (ING 5)

Spec Gravity:1.17 (H*2O=1)
pH:SUPDAT
Appearance and Odor:CLEAR, VISCOUS AMBER-COLORED SOLN;PRACTICALLY
ODORLESS TO SLIGHT AMINE-LIKE ODO

Stability Indicator/Materials to Avoid:YES
SPRAY SOLNS SHOULD BE MIXED, STORED/APPLIED USING ONLY STAINLESS STEEL,
ALUMINUM, FIBERGLASS, PLASTIC/PLASTIC- (ING 8)
Stability Condition to Avoid:NONE.

Waste Disposal Methods:WASTES THAT CANNOT BE USED/CHEM REPROCESSED
SHOULD BE DISP OF IN LANDFILL APPRVD FOR PESTICIDE DISP OR I/A/W
APPLIC FED, STATE/LOC PROC. EMPTIED CONTR RETAINS VAP & PROD
RESIDUE. OBSERVE ALL LABEL PRE C UNTIL CONTR IS CLEANED,
RECONDITIONED/DESTROYED.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.