Product ID:CARBOL-FUCHSIN SOLUTION, HT 80-1-16
MSDS Date:11/01/1995
FSC:6505
NIIN:00N082778
MSDS Number: CGDPJ

SIGMA CHEMICAL CO

ST LOUIS, MO 63178
US

Emergency Phone: 800-325-3010; 314-771-5750

Info Phone: 800-325-3010; 314-771-5750

Cage: 21076

SIGMA CHEMICAL COMPANY

14508 ST LOUIS, MO 63178 US

Telephone: 314-771-5765

Cage: 21076

BENZENAMINE,4-((4-AMINOPHENYL)(4-IMINO-2,5-

CAS: 569-61-9

RTECS: CX9850100

Fraction By Weight: 0.85%

OSHA PEL N/K

ACGIH TLV: N/K

PHENOL (SARA 302/313) (CERCLA)

CAS: 108-95-2

RTECS: SJ3327000

Fraction By Weight: 2.5%

OSHA PEL 5 PPM, S

ACGIH TLV: 5 PPM, S

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

GLYCEROL

CAS: 56-81-5

RTECS: MA8050000

Fraction By Weight: 5.3%

OSHA PEL 15 MG/M3 (MIST)

ACGIH TLV: 10 MG/M3 (MIST)

METHYL SULFOXIDE; (DIMETHYL SULFOXIDE)

CAS: 67-68-5

RTECS: PV6210000

Fraction By Weight: 5.3%

OSHA PEL N/K

ACGIH TLV: N/K

ETHYL ALCOHOL (ETHANOL)

CAS: 64-17-5

RTECS: KQ6300000

Fraction By Weight: 5.3%

OSHA PEL 1000 PPM

ACGIH TLV: 1000 PPM

LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:NO
Health Hazards Acute and Chronic:ACUTE: MAY BE HARMFUL BY INHALATION,
INGESTION, OR SKIN ABSORPTION. CAUSES IRRITATION. VAPOR OR MIST IS
IRRITATING TO EYES, MUCOUS MEMBRANES AND UPPER RESPIRATORY TRACT.
THE TOXICOLOGICAL PROPERTIES H AVE NOT BEEN THOROUGHLY
INVESTIGATED. TARGET ORGANS: EYES, KIDNEYS.
Explanation of Carcinogenicity:BASIC FUCHSIN: IARC MONO, VOL 57, PG
125:GROUP 2B. NTP 7TH ANNUAL RPT ON CARCINS, 1994:ANTIC TO BE
CARCIN. ANIMAL:LIVER.
Effects of Overexposure:SEE HEALTH HAZARDS.
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.

First Aid:INGESTION: WASH OUT MOUTH WITH WATER PROVIDED PERSON IS
CONSCIOUS. CALL MD. SKIN: FLUSH WITH COPIOUS AMOUNTS OF WATER FOR
AT LEAST 15 MINUTES. REMOVE CONTAMINATED CLOTHING & SHOES. CALL MD.
INHALATION : REMOVE TO FRESH AIR. IF BREATHING BECOMES DIFFICULT,
CALL MD. EYES: FLUSH WITH COPIOUS AMOUNTS OF WATER FOR AT LEAST 15
MINUTES. ASSURE ADEQUATE FLUSHING BY SEPARATING EYELIDS WITH
FINGERS. CALL MD.

Extinguishing Media:WATER SPRAY, CARBON DIOXIDE, DRY CHEMICAL POWDER OR
APPROPRIATE FOAM.
Fire Fighting Procedures:WEAR NIOSH APPROVED SCBA AND FULL PROTECTIVE
EQUIPMENT .
Unusual Fire/Explosion Hazard:EMITS TOXIC FUMES UNDER FIRE CONDITIONS.

Spill Release Procedures:WEAR NIOSH APPROVED RESPIRATOR, CHEMICAL
SAFETY GOGGLES, RUBBER BOOTS AND HEAVY RUBBER GLOVES. ABSORB ON
SAND OR VERMICULITE AND PLACE IN CLOSED CONTAINERS FOR DISPOSAL.
VENTILATE AREA AND WASH SPILL SITE AFTER MATERIAL PICKUP IS
COMPLETE.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

Handling and Storage Precautions:DO NOT BREATHE DUST. KEEP CONTAINER
TIGHTLY CLOSED IN A COOL, WELL-VENTILATED PLACE.
Other Precautions:NONE SPECIFIED BY MANUFACTURER.

Respiratory Protection:WEAR APPROPRIATE NIOSH APPROVED RESPIRATOR.
Ventilation:MECHANICAL EXHAUST REQUIRED.
Protective Gloves:CHEMICAL-RESISTANT GLOVES.
Eye Protection:ANSI APPRVD CHEM WORKERS GOGGLES .
Other Protective Equipment:EMERGENCY EYEWASH AND DELUGE SHOWER MEETING
ANSI DESIGN CRITERIA . PROTECTIVE CLOTHING.
Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health
NONE SPECIFIED BY MANUFACTURER.

Appearance and Odor:LIQUID

Stability Indicator/Materials to Avoid:YES
NONE SPECIFIED BY MANUFACTURER.
Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER.
Hazardous Decomposition Products:TOXIC FUMES OF CARBON MONOXIDE AND
CARBON DIOXIDE.

Waste Disposal Methods:DISSOLVE OR MIX THE MATERIAL WITH A COMBUSTIBLE
SOLVENT AND BURN IN A CHEMICAL INCINERATOR EQUIPPED WITH AN
AFTERBURNER AND SCRUBBER. OBSERVE ALL FEDERAL, STATE AND LOCAL
ENVIRONMENTAL REGULATIONS.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.