CGMYK - LEAD-ACID BATTERY,COM-30 H,A 0003

Product Identification

Product ID:LEAD-ACID BATTERY,COM-30 H,A 0003
MSDS Date:02/01/1996
FSC:6140
NIIN:01-297-2076
MSDS Number: CGMYK

Responsible Party
EXIDE CORP.-GENERAL BATTERY CORP
645 PENN STREET
READING, PA 19601
US

Emergency Phone: 215-378-0527/800-424-9300(CHEMTREC)

Info Phone: 215-378-0527/610-378-0500

Cage: 08163

Contractor
SOUTHEASTERN EQUIPMENT CO INC
UNKNOW READING, PA 19601 US

Telephone: 215-378-0527/800-424-9300(CHEMTREC)

Cage: 9H953

Ingredients

LEAD (SARA 313) (CERCLA)/LEAD,LEAD OXIDE,LEAD SULFATE

CAS: 7439-92-1

RTECS: OF7525000

Fraction By Weight: 53%

OSHA PEL SEE 1910.1025

ACGIH TLV: 0.05MG/M3, A3; 9596

EPA Report Quantity: 1 LB

DOT Report Quantity: 1 LB


ANTIMONY (SARA 313) (CERCLA)

CAS: 7440-36-0

RTECS: CC4025000

Fraction By Weight: 0.2%

OSHA PEL 0.5 MG/M3

ACGIH TLV: 0.5 MG (SB)/M3; 9596

EPA Report Quantity: 5000 LBS

DOT Report Quantity: 5000 LBS


ARSENIC (SARA 313) (CERCLA)

CAS: 7440-38-2

RTECS: CG0525000

Fraction By Weight: 0.003%

OSHA PEL SEE 1910.1018

ACGIH TLV: 0.01 MG/M3, A1; 9596

EPA Report Quantity: 1 LB

DOT Report Quantity: 1 LB


CALCIUM, METAL

CAS: 7440-70-2

RTECS: EV8040000

Fraction By Weight: 0.02%


TIN

CAS: 7440-31-5

RTECS: XP7320000

Fraction By Weight: 0.06%

OSHA PEL 2 MG/M3

ACGIH TLV: 2 MG/M3; 9596


SULFURIC ACID (SARA 302/313) (CERCLA)/ELECTROLYTE

CAS: 7664-93-9

RTECS: WS5600000

Fraction By Weight: 30 - 40%

OSHA PEL 1 MG/M3

ACGIH TLV: 1 MG/M3/3 STEL; 9596

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS


5-6 %)

CAS: 9003-07-0

RTECS: TR5000000

Fraction By Weight: SEE ING


HARD RUBBER

Fraction By Weight: SEE # 7%


SILICONE DIOXIDE (GEL CELL BATTERIES)/SILICA, CRYSTALLINE -

CAS: 60676-86-0

RTECS: VV7328000

Fraction By Weight: 3 - 5%

OSHA PEL SEE TABLE Z-3

ACGIH TLV: 0.1 MG/M3 RDUST;9596

Hazards

LD50 LC50 Mixture:LD50 (ORAL, RAT) IS NOT RELEVANT.
Routes of Entry: Inhalation:NO Skin:NO Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:TARGET ORGANS:EYE, SKIN, CNS, LUNG, GI
TRACT. ACUTE- LEAD MAY CAUSE GI UPSET, DIARRHEA, CRAMPING &
FATIGUE. SULFURIC ACID MAY CAUSE EYE, SKIN & RESPIRATORY TRACT
IRRITATION, BURNS, CORNEAL & LUNG DAMA GE. CHRONIC- LEAD MAY CAUSE
ANEMIA, KIDNEY & NERVOUS SYSTEM DAMAGE. ACID CAN CAUSE BRONCHITIS,
EROSION OF TOOTH ENAMEL.
Explanation of Carcinogenicity:NONE
Effects of Overexposure:GI UPSET, LOSS OF APPETITE, DIARRHEA,
CONSTIPATION, CRAMPING, LACK OF SLEEP, FATIGUE, SEVERE IRRITATION,
BURNS, CORNEAL AND LUNG DAMAGE, BLINDNESS, ULCERATION, WRIST DROP,
REPRODUCTIVE CHANGES
Medical Cond Aggravated by Exposure:LEAD AND ITS COMPOUNDS CAN
AGGRAVATE CHRONIC FORMS OF KIDNEY, LIVER AND NEUROLOGIC DISEASES.
CONTACT OF SULFURIC ACID WITH SKIN MAY AGGRAVATE DISEASES SUCH AS
ECZEMA. ACID MIST AGGRAVATES LUNG DISEASE

First Aid

First Aid:OBTAIN MEDICAL ATTENTION IMMEDIATELY IN ALL CASES OF
EXPOSURE. EYES/SKIN:IMMEDIATELY FLUSH WITH WATER FOR 15 MINUTES.
KEEP EYELIDS OPEN. INHALATION:REMOVE TO FRESH AIR IMMEDIATELY. IF
BREATHING IS DIF FICULT, PROVIDE OXYGEN. INGESTION:DO NOT INDUCE
VOMITING. IF CONSCIOUS, DRINK LARGE AMOUNT OF WATER OR MILK.

Fire Fighting

Flash Point:NON-FLAMMABLE
Lower Limits:4.1%HYDROGEN
Upper Limits:74.2HYDROGEN
Extinguishing Media:USE CARBON DIOXIDE, SAND, HALON/DRY CHEMICAL. WATER
APPLIED TO ELECTROLYTE GENERATES HEAT AND CAUSES IT TO SPATTER.
Fire Fighting Procedures:WEAR ACID-RESISTANT CLOTHING AND
NIOSH-APPROVED SELF-CONTAINED BREATHING APPARATUS WITH FULL
FACEPIECE OPERATED IN THE POSITIVE PRESSURE MODE.
Unusual Fire/Explosion Hazard:BATTERY CELLS MAY RUPTURE WHEN EXPOSED TO
EXCESSIVE HEAT. THIS COULD RESULT IN RELEASE OF CORROSIVE
MATERIALS. HYDROGEN GAS, IF PRESENT, IS EXPLOSIVE/FLAMMABLE.

Accidental Release

Spill Release Procedures:WEAR PROTECTIVE EQUIPMENTS. VENTILATE AREA.
REMOVE IGNITION SOURCES (H2 MAY BE PRESENT). CONTAIN BY DIKING AND
COVER SPILL WITH SODA ASH OR QUICKLIME. MIX WELL. CHECK THAT
MIXTURE IS NEUTRAL. COLLECT AND PLACE IN A DRUM. DO NOT FLUSH TO
SEWER.
Neutralizing Agent:SODA ASH (SODIUM CARBONATE), QUICKLIME (CALCIUM
OXIDE)

Handling

Handling and Storage Precautions:STORE NEAR EYEWASH FOUNTAIN AND SAFETY
SHOWER. STORAGE AREA SHOULD BE EQUIPPED WITH A DRAIN WHICH CAPTURES
SPILLS OF ACID FOR PROPER DISPOSAL.
Other Precautions:KEEP TERMINALS COVERED. AVOID SHORTING BATTERIES. DO
NOT CRACK/OVERCHARGE BATTERIES. KEEP LIGHTED CIGARETTES, SPARKS,
AND FLAMES AWAY FROM BATTERIES. KEEP OUT OF REACH OF CHILDREN.
AVOID METALLIC ARTI CLES TO CONTACT TERMINALS OF A BETTERY.

Exposure Controls

Respiratory Protection:NOT REQUIRED UNDER NORMAL USE. USE
NIOSH-APPROVED ACID-MIST FILTER RESPIRATOR IF 1 MG/M3 TWA IS
EXCEEDED (ACID).
Ventilation:ADEQUATE GENERAL VENTILATION
Protective Gloves:RUBBER
Eye Protection:SPLASH-PROOF CHEMICAL GOGGLES
Other Protective Equipment:RUBBER APRON AND BOOTS. EYES WASH STATION
AND SAFETY SHOWER. USE ACID-PROOF CLOTHING FOR MAJOR SPILLS.
Work Hygienic Practices:REMOVE METALLIC JEWELRY-SHOCK POTENTIAL. WASH
THOROUGHLY AFTER HANDLING AND BEFORE EATING AND DRINKING.
Supplemental Safety and Health

Chemical Properties

HCC:C1
NRC/State Lic Num:NOT RELEVANT
Spec Gravity:1.23-1.35(ACID)
Viscosity:NOT RELEVANT
Evaporation Rate & Reference:NOT RELEVANT
Solubility in Water:NOT RELEVENT
Appearance and Odor:BATTERY CONTAINING SULFURIC ACID AND LEAD.

Stability

Stability Indicator/Materials to Avoid:YES
COMBUSTIBLES, ORGANIC MATERIALS, METALS, REDUCING AGENTS, SULFUR
TRIOXIDE, WATER, BASES
Stability Condition to Avoid:HIGH HEAT, OPEN FLAMES, OVERCHARGING,
SMOKING, SPARKS
Hazardous Decomposition Products:LEAD OXIDE, HYDROGEN, SULFUR DIOXIDE,
SULFUR TRIOXIDE, METAL FUMES, SULFURIC ACID MIST

Disposal

Waste Disposal Methods:DISPOSE AS HAZARDOUS WASTE. OBSERVE ALL FEDERAL,
STATE AND LOCAL ENVIRONMENTAL REGULATIONS FOR ACID OR LEAD SCRAP.
SEND BATTERIES TO LEAD SMELTER FOR RECLAMATION FOLLOWING APPLICABLE
FEDERAL, STATE AN D LOCAL REGULATIONS.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.