Product ID:04357, FORMULASHELL PREMIUM GASOLINE WITH (SUPDAT)
MSDS Date:01/25/1996
FSC:9130
NIIN:00N084599
MSDS Number: CGTMS

SHELL OIL CO

HOUSTON, TX 77210
US

Emergency Phone: 713-473-9461;800-424-9300(CHEMTREC)

Info Phone: 713-241-4819

Cage: SHELO

SHELL OIL COMPANY

4320 HOUSTON, TX 77210 US

Telephone: 800-231-6950

Cage: 54527

ALKANES, CYCLOALKANES, ALKANES & AROMATIC HYDROCARBONS

Fraction By Weight: BALANCE

OSHA PEL N/K

ACGIH TLV: N/K

XYLENE (SARA 313) (CERCLA)

CAS: 1330-20-7

RTECS: ZE2100000

Fraction By Weight: 0-25%

OSHA PEL 100 PPM

ACGIH TLV: 100 PPM; 150 STEL

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

TOLUENE (SARA 313) (CERCLA)

CAS: 108-88-3

RTECS: XS5250000

Fraction By Weight: 0-25%

OSHA PEL 200 PPM

ACGIH TLV: 50 PPM, S

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

BENZENE (SARA 313) (CERCLA)

CAS: 71-43-2

RTECS: CY1400000

Fraction By Weight: 0-4%

OSHA PEL N/K

ACGIH TLV: 10 PPM

EPA Report Quantity: 10 LBS

DOT Report Quantity: 10 LBS

HEXANE; (N-HEXANE) (CERCLA)

CAS: 110-54-3

RTECS: MN9275000

Fraction By Weight: 0-3%

OSHA PEL 500 PPM

ACGIH TLV: 50 PPM

EPA Report Quantity: 1 LB

DOT Report Quantity: 1 LB

ETHYL ALCOHOL

CAS: 64-17-5

RTECS: KQ6300000

Fraction By Weight:

OSHA PEL 1000 PPM

ACGIH TLV: 1000 PPM

BENZENE, 1,2,4-TRIMETHYL-; (PSEUDOCUMENE

CAS: 95-63-6

RTECS: DC3325000

Fraction By Weight: 0-5%

OSHA PEL 25 PPM

ACGIH TLV: 25 PPM

CYCLOHEXANE (SARA 313) (CERCLA)

CAS: 110-82-7

RTECS: GU6300000

Fraction By Weight: 0-1%

OSHA PEL 300 PPM

ACGIH TLV: 300 PPM

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

BENZENE, ETHYL-; (ETHYLBENZENE) (SARA 313)

CAS: 100-41-4

RTECS: DA0700000

Fraction By Weight: 0-3%

OSHA PEL 100 PPM

ACGIH TLV: 100 PPM; 125 STEL

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

NAPHTHALENE (SARA 313) (CERCLA)

CAS: 91-20-3

RTECS: QJ0525000

Fraction By Weight: 0-1%

OSHA PEL 10 PPM

ACGIH TLV: 10 PPM; 15 STEL

EPA Report Quantity: 100 LBS

DOT Report Quantity: 100 LBS

BE EVID BY COUGH, LABORED BRTHG & CYANOSIS (BLUISH

RTECS: 9999999ZZ

EVID BY CHGS IN URINE OUTPUT & APPEAR OR EDEMA

RTECS: 9999999ZZ

APPETITE LOSS, JAUN (YELLOWISH SKIN) & PAIN IN UPPER

RTECS: 9999999ZZ

LIST OF OCCUP CHEM REPRO HAZS. CONSULT APPROP HLTH

RTECS: 9999999ZZ

& EXPOS INFO . IARC HAS DETERM GASOLINE IS POSS

RTECS: 9999999ZZ

UNLEADED MOTOR GASOLINE HAS PRDCED KIDNEY & LIVER

RTECS: 9999999ZZ

OTHER MASSIVE EXPOS TO ETHANOL MAY RSLT IN MULTIPLE

RTECS: 9999999ZZ

PREGNANCY CAUSING BIRTH DEFECTS IN SOME INFANTS.

RTECS: 9999999ZZ

SHOWN TO CAUSE CANCER IN LAB ANIMALS. CONTACT NEHC

RTECS: 9999999ZZ

HEAD BELOW HIPS TO PVNT ASPIR OF LIQ INTO LUNGS.

RTECS: 9999999ZZ

W/VACUUM TRUCK/PUMP TO STOR/SALVAGE VESSELS.

RTECS: 9999999ZZ

DISP. FLUSH AREA W/WATER; DISP OF FLUSH SOLN AS

RTECS: 9999999ZZ

SWALLOW IS HARMFUL/FATAL. DO NOT SIPHON GAS BY

RTECS: 9999999ZZ

MAY CAUSE FIRE IF GAS PUMPED INTO UNGROUNDED GAS

RTECS: 9999999ZZ

GROUND. DO NOT FILL IN VEHICLE/TRUCK BED. KEEP NOZZ

RTECS: 9999999ZZ

LD50 LC50 Mixture:LD50: (ORAL, RAT) >5 G/KG
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:YES
Health Hazards Acute and Chronic:EYES:IRRIT. SKIN:PRLNGD & RPTD LIQ
CNTCT CAN CAUSE DEFAT & DRY SKIN RSLTG IN IRRIT & DERM. INHAL:MAY
CAUSE IRRIT TO NOSE, THROAT & RESP TRACT & MAY PRDCE LIVER & KIDNEY
DMG. HIGH VAP CONCS MAY PRDCE C NS DEPRESS. PRLNGD & RPTD BENZENE
EXPOSMAY CAUSE SERIOUS INJURY TO BLOOD FORMING ORGANS & IS LINKED
TO(EFTS OF OVEREXP)
Explanation of Carcinogenicity:BENZENE: IARC MONO, SUPP, VOL 7, PG 120,
1987:GROUP 1. NTP 7TH ANNUAL RPT ON CARCINS, 1994:KNOWN TO BE
CARCIN. (SUPDAT)
Effects of Overexposure:HLTH HAZ: LATER DEVELOPMENT OF ACUTE
MYELOGENOUS LEUKEMIA. INGEST:MAY BE HARMFUL/FATAL IF SWALLOWED.
POSS VOMIT; AVOID ASPIR (BRTHG) OF VOMITUS INTO LUNGS AS EVEN SM
QTYS MAY RSLT IN ASPIR PNEUMIT. LI Q IS READILY ABSORBED & MAY
PRDCE CNS DEPRESS. PRLNGD & RPTD EXPOS MAY PRDCE LIVER DMG. EARLY
TO MOD CNS DEPRESS(SUPDAT)
Medical Cond Aggravated by Exposure:PREEXISTING EYE, SKIN & RESPIRATORY
DISORDERS MAY BE AGGRAVATED BY EXPOSURE TO THIS PRODUCT. IMPAIRED
LIVER & KIDNEY FUNCTIONS FROM PREEXISTING DISORDERS MAY BE
AGGRAVATED BY EXPOSURE TO THIS PRODUCT.

First Aid:EYES:FLUSH W/WATER FOR @ LEAST 15 MIN WHILE HOLDING LIDS
OPEN. GET MED ATTN. SKIN:FLUSH W/WATER WHILE REMOVING CONTAM CLTHG
& SHOES. FOLLOW BY WASHING W/SOAP & WATER. DO NOT REUSE CLTHG/SHOES
UNTIL CL EANED. IF IRRIT PERSISTS GET MED ATTN. INHAL:REMOVE TO
FRESH AIR & PROVIDE OXYG IF BRTHG DFCLT. GIVE ARTF RESP IF NOT
BRTHG. GET MED ATTN. INGEST:DO NOT INDUCE VOMIT; IF IT OCCURS SPONT
KEEP (ING 20)

Flash Point Method:TCC
Flash Point:-40F,-40C
Lower Limits:1.3%
Upper Limits:7.6%
Extinguishing Media:USE WATER FOG, FOAM, DRY CHEM OR CO*2. DO NOT USE
DIRECT STREAM OF WATER. PROD WILL FLOAT & REIGNITE ON SURF OF
WATER.
Fire Fighting Procedures:USE NIOSH APPRVD SCBA & FULL PROT EQUIP .
DANGER. EXTREMELY FLAMMABLE. CLEAR FIRE AREA OF UNPROT PERS &
ISOLATE. COOL FIRE EXPOSED CNTNRS W/WATER.
Unusual Fire/Explosion Hazard:VAPS ARE HVR/AIR, ACCUM IN LOW AREAS &
TRAVEL ALONG GROUND AWAY FROM HNDLG SITE. DO NOT WELD, HEAT/DRILL
ON/NEAR CNTNR. HOWEVER, IF EMER SITUATIONS REQ (SUPDAT)

Spill Release Procedures:EXTREMELY FLAM. ELIM IGNIT SOURCES. GROUND
HNDLG EQUIP. LG SPILLS:ISOLATE AREA & DENY ENTRY. WEAR APPROP NIOSH
APPRVD RESP & CLTHG. SHUT OFF LEAK ONLY IF SAFE TO DO SO. DIKE &
CNTN. WATER FOG USEFUL T O SUPPRESS VAP CLOUD; CNTN RUN-OFF.
REMOVE(ING 21)
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

Handling and Storage Precautions:EXTREMELY FLAM. AVOID HEAT/SPKS/OPEN
FLAMES/STRONG OXIDIZING AGENTS. USE EXPLO-PROOF VENT TO PVNT VAP
ACCUM. GROUND HNDLG EQUIP TO PVNT SPKG. (ING 23)
Other Precautions:FOR USE AS MOTOR FUEL ONLY. DO NOT USE AS CLEAN
SOLV/FOR OTHER NON-MOTOR FUEL USES. UNDER NORM WORKING CNDTNS AT
SERVICE STATIONS, RESP NOT WARRANTED. IF MAJOR SPILL OCCURS, GET
UPWIND & NOTIFY LOC EM ER PERS. EXPLO & FIRE IS IMMED DANGER.

Respiratory Protection:AVOID BRTHG VAP. UNDER CNDTNS OF POTNTL HIGH
EXPOS, NIOSH APPRVD RESP IS RECOM. PER 29 CFR 1910.134 OR 29 CFR
1910.1028 USE EITHER ATM-SUPPLYING RESP OR AIR-PURIFYING RESP FOR
ORG VAPS. FOR SERVICE ST ATION PERS, SEE SPEC PRECS SECTION.
Ventilation:USE EXPLOSION-PROOF VENTILATION AS REQUIRED TO CONTROL
VAPOR CONCENTRATIONS.
Protective Gloves:NITRILE RUBBER, PVA OR VITON/NEOPRENE.
Eye Protection:ANSI APPRVD CHEM WORKERS GOGGLES .
Other Protective Equipment:ANSI APPRVD EYE WASH & DELUGE SHOWER.
INDICATIONS THAT BEST CLTHG PROT IS BY NITRILE RUB/PVA OR
VITON/NEOPRENE.
Work Hygienic Practices:WASH W/SOAP & WATER BEFORE EATING, DRINKING,
SMKNG OR USING TOILET FACILITIES. LAUNDER CLTHG BEFORE REUSE.
Supplemental Safety and Health
MFR'S TRADE NAME/PART NO: ETHANOL (CONVENTIONAL AND RFG). SPEC GRAV:
0.72-0.76 (H*2O=1). EXPLO HAZ: DRILLING, ONLY TRAINED EMER PERS
SHOULD DRILL. EXPLAN OF CARCIN: OSHA REGULATED: CFR 29 1910.1028. E
FTS OF OVEREXP: MAY BE EVID BY GIDD, HDCH, DIZZ & NAUS; IN EXTREME
CASES, UNCON & DEATH POSS. ASPIR PNEUMIT MAY (ING 11)

Boiling Pt:B.P. Text:>100F,>38C
Vapor Pres:7-14.5 PSI
Vapor Density:3.5
Spec Gravity:SUPDAT
Solubility in Water:NEGLIGIBLE
Appearance and Odor:RED COLOR, CLEAR AND BRIGHT LIQUID; HYDROCARBON
ODOR.
Percent Volatiles by Volume:100

Stability Indicator/Materials to Avoid:YES
AVOID STRONG OXIDIZING AGENTS.
Stability Condition to Avoid:AVOID HEAT, SPARKS AND OPEN FLAMES.
PREVENT VAPOR ACCUMULATION.
Hazardous Decomposition Products:CARBON MONOXIDE AND OTHER UNIDENTIFIED
ORGANIC COMPOUNDS CAN BE FORMED UPON COMBUSTION.

Waste Disposal Methods:DISPOSAL MUST BE IN ACCORDANCE WITH FEDERAL,
STATE AND LOCAL REGULATIONS .

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.