Product ID:ETHYL ALCOHOL 190 PROOF NON-DENATURED, W241903
MSDS Date:07/31/1996
FSC:6810
NIIN:00N085053
MSDS Number: CGZWT

SIGMA CHEMICAL CO

ST LOUIS, MO 63178
US

Emergency Phone: 314-771-5765

Info Phone: 314-771-5765

Cage: 21076

SIGMA CHEMICAL COMPANY

14508 ST LOUIS, MO 63178 US

Telephone: 314-771-5765

Cage: 21076

7060 MG/KG

CAS: 64-17-5

RTECS: KQ6300000

OSHA PEL 1000 PPM

ACGIH TLV: 1000 PPM

DEATH, OTHER EFTS TO EMBRYO/FETUS); SPECIFIC DEVEL

RTECS: 9999999ZZ

& RESP SYS); EFTS ON NEWBORN (GROWTH STATISTICS);

RTECS: 9999999ZZ

LD50 LC50 Mixture:SEE INGREDIENT 1.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:ACUTE: MAY BE HARMFUL BY INHAL,
INGEST/SKIN ABSORPTION. VAP/MIST IS IRRITATING TO EYES, MUC MEMBS &
UPPER RESP TRACT. CAUSES SKIN IRRIT. CAN CAUSE CNS DEPRESS. CAN
CAUSE NAUS, HDCH & VOMIT. NARCOTIC E FT. DMG TO HEART. TARGET
ORGANS: NERVES, LIVER. TARGET ORGAN DATA: BEHAVIORAL (SLEEP, CHANGE
IN MOTOR (EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT.
Effects of Overexposure:HLTH HAZ: ACTIVITY, ATAXIA, ANTIPSYCHOTIC,
HDCH, CHANGE IN PSYCHOPHYSIOLOGICAL TESTS); LUNGS, THORAX/RESP
(CHRONIC PULM EDEMA/CONGESTION, DYSPNAE, OTHER CHANGES); GI
(ALTERATION IN GASTRIC SECRETION, HYPERMOTILITY, DIARR,
NAUS/VOMIT, OTHERCHANGES); LIVER (FATTY LIVER DEGENERATION,
TUMORS); BLOOD (OTHER (SUP DAT)
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.

First Aid:INHAL: REMOVE TO FRESH AIR. IF BREATHING BECOMES DIFFICULT,
CALL MD. EYES: FLUSH W/COPIOUS AMOUNTS OF WATER FOR AT LEAST 15
MINUTES. ASSURE ADEQ FLUSHING BY SEPARATING EYELIDS W/FINGERS. CALL
MD. INGE ST: WASH OUT MOUTH W/WATER IF CONSCIOUS. CALL MD IMMED.
SKIN: FLUSH W/COPIOUS AMOUNTS OF WATER FOR AT LEAST 15 MIN. REMOVE
CONTAM CLOTHING & SHOES. CALL MD. WASH CONTAMINATED CLOTHING BEFORE
REUSE.

Flash Point:62.0F,16.7C
Lower Limits:YES
Upper Limits:YES
Extinguishing Media:CARBON DIOXIDE, DRY CHEMICAL POWDER OR APPROPRIATE
FOAM.
Fire Fighting Procedures:WEAR NIOSH APPROVED SCBA AND FULL PROTECTIVE
EQUIPMENT . USE WATER SPRAY TO COOL FIRE-EXPOSED CONTAINERS.
FLAMMABLE LIQUID.
Unusual Fire/Explosion Hazard:VAPOR MAY TRAVEL CONSIDERABLE DISTANCE TO
SOURCE OF IGNITION AND FLASH BACK.

Spill Release Procedures:EVACUATE AREA. SHUT OFF IGNIT SOURCES. WEAR
NIOSH APPRVD SCBA, RUB BOOTS & HEAVY RUB GLOVES. COVER W/DRY-LIME,
SAND/SODA ASH. PLACE IN COVERED CONTRS USING NON-SPKG TOOLS &
TRANSPORT OUTDOORS. VENT AR EA & WASH SPILL SITE AFTER MATL PICKUP
COMPLETED.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

Handling and Storage Precautions:DO NOT BREATHE VAPOR. DO NOT GET IN
EYES, ON SKIN, ON CLOTHING. AVOID PROLONGED OR REPEATED EXPOSURE.
IRRITANT. KEEP TIGHTLY CLOSED.
Other Precautions:KEEP AWAY FROM HEAT, SPARKS, AND OPEN FLAME. STORE IN
A COOL DRY PLACE.

Respiratory Protection:WEAR APPROPRIATE NIOSH APPROVED RESPIRATOR.
Ventilation:USE ONLY IN A CHEMICAL FUME HOOD.
Protective Gloves:CHEMICAL-RESISTANT GLOVES.
Eye Protection:ANSI APPRVD CHEM WORKERS GOGGLES .
Other Protective Equipment:EMERGENCY EYEWASH AND DELUGE SHOWER MEETING
ANSI DESIGN CRITERIA . WEAR PROTECTIVE CLOTHING.
Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING.
Supplemental Safety and Health
EFTS OF OVEREXP: CHANGES, LYMPHOMA INCL HODGKIN'S DISEASE); PATERNAL
EFTS (TESTES, EPIDIDYMIS, SPERM DUCT); EFTS ON FERTILITY (FEMALE &
MALE FERTILITY INDEX, POST-IMPLANTATION MORTALITY, OTHER MEASURE S
OF FERTILITY); EFTS ON EMBRYO/FETUS (EXTRA EMBRYONIC STRUCTURES,
CYTOLOGICAL CHANGES, FETOTOXICITY, (FETAL (ING 2)

Boiling Pt:B.P. Text:172F,78C
Spec Gravity:0.816
Appearance and Odor:COLORLESS LIQUID

Stability Indicator/Materials to Avoid:YES
OXIDIZING AGENTS, PEROXIDES, ACIDS, ACID CHLORIDES, ACID ANHYDRIDES,
ALKALI METALS, AMMONIA.
Stability Condition to Avoid:PROTECT FROM MOISTURE.
Hazardous Decomposition Products:TOXIC FUMES OF CARBON MONOXIDE AND
CARBON DIOXIDE.

Waste Disposal Methods:BURN IN A CHEMICAL INCINERATOR EQUIPPED WITH AN
AFTERBURNER AND SCRUBBER BUT EXERT EXTRA CARE IN IGNITING AS THIS
MATERIAL IS HIGHLY FLAMMABLE. OBSERVE ALL FEDERAL, STATE AND LOCAL
ENVIRONMENTAL REGUL ATIONS.

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