Product ID:PHENYLHYDRAZINE
MSDS Date:03/05/1987
FSC:6505
NIIN:00N085098
MSDS Number: CGZYT

MALLINCKRODT CHEMICAL INC

PARIS, KY 40362
US

Emergency Phone: 314-539-1600

Info Phone: 314-539-1600

Cage: 23104

MALLINCKRODT SPECIALTY CHEMICALS CO

PHILLIPSBURG, NJ 08865 US

Telephone: 908-859-2151

Cage: 62910

HYDRAZINE, PHENYL-; (PHENYLHYDRAZINE)

CAS: 100-63-0

RTECS: MV8925000

OSHA PEL 5 PPM, S

ACGIH TLV: 0.1 PPM, S

NOT BREATHE VAP. AVOID CONT W/EYES, SKIN & CLTHG.

RTECS: 9999999ZZ

SPARKS & FLAME.

RTECS: 9999999ZZ

BECAUSE IT CAN CONTROL EMISSIONS OF CONTAM AT ITS

RTECS: 9999999ZZ

PLEASE REFER TO ACGIH DOCUMENT, "INDUSTRIAL VENT, A

RTECS: 9999999ZZ

LD50 LC50 Mixture:LD50:(ORAL,RAT) 188 MG/KG.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:ACUTE:INHAL:POISON. CORROSIVE TO RESP
TRACT. MAY PRDCE SORE THROAT, COUGHING, LABORED BRTHG, DIZZ, BLUISH
SKIN, FAINTNESS. INGEST:TOXIC. MAY BE FATAL IF SWALLOWED. CORROSIVE
TO TISSUES. MAY CAUSE VOMI TING, DIZZ, FAINTNESS & JAUNDICE. SKIN
CONT:CORROSIVE. CONTACT DERM & SENSIT MAY OCCUR. OTHER SYMPS (EFTS
OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT
Effects of Overexposure:HLTH HAZ:INCL REDNESS, PAIN, BURNS; ABSORPTION
CAN PRDCE TOX EFTS NOTED FOR INHAL EYE CONT:CORROSIVE. VAPS LIQ
ARE DESTRUCTIVE TO TISSUE. CHRONIC:CHRONIC & ACUTE EXPOS MAY PRDCE
BLOOD EFTS, LIVER & K IDNEY DMG. MUTAGEN REFERENCES CITED; ANIMAL
REPRO EFT CITED; TUMORIGENIC EFTS CITED.
Medical Cond Aggravated by Exposure:PERSONS W/PRE-EXISTING SKIN
DISORDERS OR EYE PROBLEMS OR IMPAIRED LIVER, KIDNEY OR RESPIRATORY
FUNCTION MAY BE MORE SUSCEPTIBLE TO THE EFFECTS OF THE SUBSTANCE.

First Aid:UPON POIS BY PHENYLHYDRAZINE, SPECIFIC FIRST AID & TREATMENT
ARE ESSNTL. GET IMMED MED ATTN FOR ANY EXPOS. INHAL:REMOVE TO FRESH
AIR. IF NOT BRTHG, GIVE ARTF RESP. IF BRTHG IS DFCLT, GIVE OXYG.
CALL M D. INGEST:CALL MD IMMED. SKIN:IMMED FLUSH W/PLENTY OF WATER
FOR AT LST 15 MINS WHILE REMOVING CONTAM CLTHG & SHOES. WASH CLTHG
BEFORE REUSE. CALL MD IMMED. EYE:WASH W/PLENTY OF WATER FOR AT
(SUPDAT)

Flash Point:190F,88C
Extinguishing Media:DRY CHEMICAL, FOAM OR CARBON DIOXIDE. WATER MAY BE
INEFFECTIVE.
Fire Fighting Procedures:USE NIOSH APPROVED SCBA & FULL PROTECTIVE
EQUIPMENT .
Unusual Fire/Explosion Hazard:COMBUSTIBLE LIQUID. ABOVE FLASH POINT,
EXPLOSIVE VAPOR-AIR MIXTURES MAY BE FORMED.

Spill Release Procedures:VENT AREA OF LEAK/SPILL. REMOVE ALL SOURCES OF
IGNIT. CLEAN-UP PERS REQ PROT CLTHG & NIOSH APPRVD RESP PROT FROM
VAPS. CNTN & RECOVER LIQ WHEN POSS. COLLECT AS HAZ WASTE & ATOMIZE
IN SUITABLE RCRA APP RVD COMBUST CHAMBER/ABSORB W/VERMICULITE,
(SUPDAT)
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

Handling and Storage Precautions:PROT AGAINST PHYSICAL DMG.
OUTSIDE/DETACHED STOR IS PREF. INSIDE STOR SHOULD BE IN STD FLAMM
LIQS STOR ROOM/CABINET. SEPARATE FROM OXIDIZING MATLS.
Other Precautions:STOR & USE AREAS SHOULD BE NO SMOKING AREAS. DO NOT
STORE ON WOODEN FLOORS. DANGER! MAY BE FATAL IF SWALLOWED,
INHALED/ABSORBED THRU SKIN. CORR. CAUSES BURNS. COMBUST. VAP & LIQ
ARE EXTREMELY TOX & CO RR. CHRONIC EXPOS MAY AFFECT (SUPP DATA)

Respiratory Protection:IF TLV IS EXCEEDED, WEAR A NIOSH APPROVED
SUPPLIED AIR, FULL-FACEPIECE RESPIRATOR, AIRLINED HOOD OR SELF
CONTAINED BREATHING APPARATUS.
Ventilation:SYS OF LOC &/OR GEN EXHST IS REC TO KEEP EMPLOYEE EXPOS
BELOW AIRBORNE EXPOS LIMS. LOC EXHST VENT IS GENRLY PREF (ING 4)
Protective Gloves:IMPERVIOUS GLOVES.
Eye Protection:ANSI APPROVED CHEM WORKERS GOGGS(SUPDAT)
Other Protective Equipment:ANSI APPRVD EYE WASH FOUNTAIN & DELUGE
SHOWER . WEAR IMPERVIOUS PROT CLTHG, INCL BOOTS, LAB COAT, APRON/
(SUPDAT)
Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING. CONTACT LENSES
SHOULD NOT BE WORN WHEN WORKING W/THIS MATERIAL.
Supplemental Safety and Health
FIRST AID PROC:LST 15 MINS, LIFTING LOWER & UPPER LIDS OCCAS. GET MED
ATTN IMMED. SPILL PROC:DRY SAND, EARTH/SIMILAR MATL FOR DISP AS HAZ
WASTE IN RCRA APPRVD FACILITY. DO NOT FLUSH TO SEWER! EYE PROT :&
FULL LGTH FSHLD . OTHER PROT EQUIP:COVERALLS TO PVNT SKIN CONT.
OTHER PREC:BLOOD, LIVER & KIDNEYS. DO (ING 2)

Boiling Pt:B.P. Text:470F,243C
Melt/Freeze Pt:M.P/F.P Text:66.0F,18.9C
Decomp Temp:Decomp Text:470F,243C
Vapor Pres:1 @ 71.8C
Vapor Density:3.7
Spec Gravity:1.099
Solubility in Water:SLIGHTLY SOLUBLE
Appearance and Odor:YELLOW CRYSTALS OR OIL; FAINT AROMATIC ODOR.

Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZERS.
Stability Condition to Avoid:STABLE UNDER ORDINARY CONDITIONS OF USE &
STORAGE.
Hazardous Decomposition Products:MAY FORM CARBON OXIDES & NITROGEN
OXIDES WHEN HEATED TO DECOMPOSITION.

Waste Disposal Methods:ENSURE COMPLIANCE W/LOCAL, STATE & FEDERAL
REGULATIONS.

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of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.