Product ID:ECCOBOND 285 BLACK
MSDS Date:03/11/1997
FSC:8040
NIIN:01-325-1694
MSDS Number: CHHDJ

EMERSON & CUMING INC

55 HAYDEN AVE
LEXINGTON, MA 02173
US

Emergency Phone: 800-424-9300 (CHEMTREC)

Info Phone: 617-828-3300

Preparer: DAVID HAAS

Cage: DO244

EMERSON & CUMING INC DIV/W R GRACE CO

AUOBURN, MA 01888 US

Telephone: (617) 935-4850 OR (617) 938-8630

Cage: DO244

ALUMINUM OXIDE

CAS: 1344-28-1

RTECS: BD1200000

Fraction By Weight: 70-80%

OSHA PEL 10 MG/M3 (MFR)

ACGIH TLV: 10 MG/M3 (MFR)

EPOXY RESIN

Fraction By Weight: 20-30%

OSHA PEL N/K

ACGIH TLV: N/K

N-BUTYL GLYCIDYL ETHER

CAS: 2426-08-6

RTECS: TX4200000

Fraction By Weight: <2%

OSHA PEL 25 PPM (MFR)

ACGIH TLV: 25 PPM (MFR)

AMORPHOUS SILICA; (AMORPHOUS FUMED SILICA)

Fraction By Weight: <2%

OSHA PEL 6 MG/M3 (MFR)

ACGIH TLV: 10 MG/M3 (MFR)

CARBON BLACK

CAS: 1333-86-4

RTECS: FF5800000

Fraction By Weight: <0.3%

OSHA PEL 3.5 MG/M3

ACGIH TLV: 3.5 MG/M3; 9495

MODIFERS/ADDITIVES

RTECS: 9999999ZZ

Fraction By Weight: <2%

OSHA PEL N/K

ACGIH TLV: N/K

DILUTE BY GIVING

RTECS: 9999999ZZ

ALERT. NEVER GIVE ANYTHING BY MOUTH TO A DROWSY,

RTECS: 9999999ZZ

W/VERMICULITE/OTHER SIMILAR MATL. WASH AREA

RTECS: 9999999ZZ

& WATER RINSES IN APPROP CNTNRS. DISPOSE OF

RTECS: 9999999ZZ

ACCESS TO IMMEDIATE SPILL AREA. SHUT OFF SOURCE OF

RTECS: 9999999ZZ

ACTIVATE AVAIL EXHST VENT SYS IN AREA. DIKE AREA TO

RTECS: 9999999ZZ

WATERWAYS. COLLECT SPILLED MATL FOR

RTECS: 9999999ZZ

AREA W/SOAPY WATER. PREVENT RUNOFF FROM ENTERING

RTECS: 9999999ZZ

APPROPRIATE WASTE CONTAINERS. DISPOSE OF IN

RTECS: 9999999ZZ

ROUTINE INHAL. THIS IS NEC ESP DURING ELEVATED TEMP

RTECS: 9999999ZZ

AIRBORNE LEVELS OF SECTION 2 INGREDIENTS BELOW

RTECS: 9999999ZZ

RESPIRATOR APPROVED BY NIOSH IF EXPOSURES EXCEED

RTECS: 9999999ZZ

AIR-PURIFYING, ETC.) WILL DEPEND UPON THE

RTECS: 9999999ZZ

SHOULD BE USED TO PREVENT SKIN CONTACT

RTECS: 9999999ZZ

SHOULD BE WASHED BEFORE REUSE.

RTECS: 9999999ZZ

THE OGFRA EPOXY RESIN IN THIS PROD HAS

RTECS: 9999999ZZ

HAS FAILED TO SHOW MUTAGENICITY IN OTHERS.

RTECS: 9999999ZZ

CELLS. TWO-YEARS BIOASSAYS ON MICE EXPOSED BY THE

RTECS: 9999999ZZ

LIMITED EVIDENCE OF WEAK CARCINOGENICITY. FOR MORE

RTECS: 9999999ZZ

LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:YES OSHA:NO
Health Hazards Acute and Chronic:EYE: CNTNS MATLS IRRIT TO EYES. SYMPS
MAY INCL BLURRED VISION, BURNING SENSATION & TEARING. SKIN: CNTNS
MATLS WHICH CAUSE MOD SKIN IRRIT. PRLNG/RPTD EXPOS TO LIQ MAY EXERT
A DEFAT/DRYING ACTION ON SKI N, POSSIBLY RSLTG IN DERM. THIS PROD
MAY CAUSE SKIN SENSIT/ALLERGIC SKIN RXNS WHICH MAY BE SEV IN (EFTS
OF OVEREXP)
Explanation of Carcinogenicity:CARBON BLACK: IARC MONOGRAPHS, VOL 65,
PG 24-27, 1995: GROUP 2B.
Effects of Overexposure:HLTH HAZ:CERTAIN INDIVIDUALS; SYMPS INCL RASH,
ITCHING, HIVES, SWELL OF EXTREMITIES. INHAL: HEATING CAN GENERATE
VAPS THAT MAY CAUSE RESP IRRIT, NAUS & HDCHS. INHAL HAZ AT ROOM
TEMP IS UNLIKELY; DUE T O LOW VOLATILITY OF THIS PROD. INGEST:
HARMFUL IF SWALLOWED. CHRONIC: ALTHOUGH THE SIGNIFICANCE IS
UNKNOWN, (ING 22)
Medical Cond Aggravated by Exposure:EXPOSURE MAY AGGRAVATE PREEXISTING
SKIN AND/OR EYE DISORDERS.

First Aid:EYE: FLUSH THOROUGHLY W/WATER FOR AT LEAST 15 MIN WHILE
HOLDING EYELIDS OPEN. GET MED ATTN. SKIN: REMOVE ANY CONTAMD CLTHG
& FLUSH AFFECTED AREA OF SKIN THOROUGHLY W/PLENTY OF H*2O. FOLLOW
BY WASHING W/SOAP & H*2O. GET MED ATTN IF IRRIT PERSISTS. DO NOT
REUSE CONTAMD CLTHG UNTIL PROPERLY CLEANED. INHAL: REMOVE VICTIM TO
FRESH AIR. PROVIDE OXYGEN IF BRTHG IS DFCLT. GIVE ARTF RESP IF
(SUPDAT)

Flash Point:>200F,>93C
Extinguishing Media:USE CARBON DIOXIDE, DRY CHEMICAL, FOAM, WATER FOG.
Fire Fighting Procedures:USE NIOSH APPRVD SCBA & FULL PROT EQUIP . COOL
EXPOSED CNTNRS W/WATER TO PVNT PRESS BUILDUP. IF LRG QTIES OF MATL
ARE INVOLVED, EVACUATE AREA & (SUPDAT)
Unusual Fire/Explosion Hazard:DECOMPOSITION AND COMBUSTION PRODUCTS MAY
BE TOXIC. CLOSED CONTAINERS MAY VIOLENTLY RUPTURE UNDER FIRE
CONDITIONS.

Spill Release Procedures:SPILL RESPONSE OPERATIONS MUST BE CONDUCTED
I/A/W/PREVISIONS OF OSHA 29 CFR 1910.120. REVIEW ENTIRE MSDS BEFORE
PROCEEDING W/SPILL RESPONSE. SMALL SPILLS: ACTIVATE AVAIL EXHST
VENT EQUIP IN IMMED SPIL L AREA. WIPE UP/ABSORB SPILLED MATL (ING
9)
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

Handling and Storage Precautions:STORE IN A COOL, DRY LOCATION WITH
ADEQUATE VENTILATION. KEEP CONTAINER TIGHTLY CLOSED WHEN NOT IN
USE. KEEP AWAY FROM OPEN FLAMES AND HEAT SOURCES.
Other Precautions:CONSULT THE PRODUCT TECHNICAL BULLETIN FOR DETAILED
STORAGE INFORMATION.

Respiratory Protection:THE TYPE OF PROTECTION SELECTED APPROBED BY
NIOSH (SCBA, AIR-PURIFYING, ETC.) WILL DEPEND UPON THE CONDITIONS
OF USE. OBSERVE OSHA REGULATION FOR RESPIRATORY PROTECTION (29 CFR
1910.134).
Ventilation:PROVIDE EFTIVE MECH EXHST VENT TO DRAW VAPS, MISTS/FUMES
GENERATED DURING PROCESSING AWAY FROM WORKER & PVNT (ING 16)
Protective Gloves:IMPERVIOUS GLOVES .
Eye Protection:ANSI APPROVED CHEM WORKERS GOGGS .
Other Protective Equipment:ANSI APPRVD EMER EYE WASH & DELUGE SHOWER .
A PROPER CHEM-RESISTANT APRON & ADDITIONAL IMPERVIOUS CLTHG (ING
20)
Work Hygienic Practices:WASH HANDS AND FACE THOROUGHLY AFTER HANDLING
THIS PRODUCT AND BEFORE EATING, DRINKING OR SMOKING.
Supplemental Safety and Health
FIRE FIGHT PROC: FIGHT FIRE FROM A SAFE DISTANCE. CNDTNS (STAB):
AGENTS/EXPOS TO INCOMPATIBLE SUBSTANCES. MATL TO AVOID: MAY CAUSE
HAZ POLYMERIZATION. HAZ DECOMP PROC: NATURE & QTY OF DECOMP
BY-PRODS WILL VARY WIDELY DEPENDING ON CNDTNS OFCOMBUSTIONS. FIRST
AID PROC: BRTHG IS DFCLT. GIVE ARTF RESP IF NOT (ING 7)

Vapor Pres:<0.1 @ 25C
Spec Gravity:2.35 (H*2O = 1)
Solubility in Water:INSOLUBLE
Appearance and Odor:BLACK LIQUID
Percent Volatiles by Volume:<2

Stability Indicator/Materials to Avoid:YES
INCOMPATIBLE W/STRONG OXIDIZERS, ACIDS, BASES; UNCONTROLLED MIXING
W/AMINES, ANHYDRIDES, MERCAPTONS, IMIDAZOLES (SUPDAT)
Stability Condition to Avoid:AVOID STORAGE IN OPEN CNTNRS, EXPOS TO
OPEN FLAME/UNCONTROLLED EXPOS TO HEAT, UNCONTROLLED MIXING
W/CURING, (SUPDAT)
Hazardous Decomposition Products:CARBON MONOXIDE, CARBON DIOXIDE,
ALDEHYDES, ACIDS & OTHER ORG SUBSTANCES MAY BE FORMED DURING
COMBUSTION. CHEM (SUPDAT)

Waste Disposal Methods:DISPOSE OF IN ACCORDANCE WITH CURRENT FEDERAL,
STATE, AND LOCAL REGULATIONS.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.