Product ID:CAT#:250473 3-7-90 FIXER & REPLENISHER (10GAL SIZE),WORK SOL
MSDS Date:06/01/1997
FSC:6525
NIIN:01-096-0617
MSDS Number: CHKYK

PICKER INTERNATIONAL

4 ESTERBROOK LANE
CHERRY HILL, NJ 08003
US

Emergency Phone: 609-424-3620;800-424-9300(CHEMTREC)

Info Phone: 609-424-3620

Cage: 47220

PICKER INTL INC

ROSLYN HEIGHTS, NY 11577-2031 US

Telephone: 609-424-3620;800-424-9300(CHEMTREC)

Cage: MO904

WATER

CAS: 7732-18-5

RTECS: ZC0110000

Fraction By Weight: 80-90%

AMMONIUM THIOSULFATE

CAS: 7783-18-8

RTECS: XN6465000

Fraction By Weight: 10-15%

SODIUM BISULFITE (SASA III) (CERCLA)

CAS: 7631-90-5

RTECS: VZ2000000

Fraction By Weight: 1-5%

OSHA PEL 5 MG/M3

ACGIH TLV: 5 MG/M3; 9596

EPA Report Quantity: 5000 LBS

DOT Report Quantity: 5000 LBS

SODIUM ACETATE

CAS: 127-09-3

RTECS: AJ4300010

Fraction By Weight: 1-5%

ALUMINUM SULFATE

CAS: 10043-01-3

RTECS: BD1700000

Fraction By Weight: 1-5%

OSHA PEL 2 MG/M3

ACGIH TLV: 2 MG/M3; 9596

EPA Report Quantity: 5000 LBS

DOT Report Quantity: 5000 LBS

LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:CONTAINS SODIUM BISULFITE.CONTAINS
AMMONIUM SALTS WHICH PRODUCE AMMONIA IN PRESENCE OF BASES/HIGH
HEAT,WILL PRODUCE TOXIC CMPDS IF MIX W/SODIUM
HYPOCHLORITE(BLEACH).HARMFUL IF SWALLOWED,CAUSES SKIN/EY E
IRRIT,MAY CAUSE ALLERGIC SKIN RX.DONTMIX W/HOUSEHOLD
BLEACH.EYE/SKIN:IRRIT.MAY CAUSE ALLERGIC RX.ORAL:(SUPPLEMENTAL)
Explanation of Carcinogenicity:PER MSDS:NONE OF COMPONENTS ARE LISTED
BY IARC/NTP/OSHA AS CARCINOGEN.
Effects of Overexposure:EYE/SKIN IRRIT,GI TRACT IRRIT, HARMFUL IF
SWALLOWED, CAUSES ALLERGIC SKIN REACTION.
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.
TARGET ORGANS:RESP SYS,EYES,SKIN.

First Aid:INHAL:MOVE TO FRESH AIR,OBTAIN MED ATTN IF REQUIRED.EYE:HOLD
EYELIDS APART & IMMED FLUSH W/PLENTY OF WATER FOR 15MINS.GET MED
ATTN.SKIN:IMMED FLUSH W/PLENTY OF WATER WHILE REMOVING CONTAM
CLOTH/SHOES. SKIN IRRIT/ALERGIC SKIN RX DVLPS GET MED
ATTN.INGEST:DRINK 1-2 GLASSES OF WATER,GET MED ATTN.

Flash Point:NONE
Autoignition Temp:Autoignition Temp Text:NP
Lower Limits:NP
Upper Limits:NP
Extinguishing Media:WATER SPRAY, DRY CHEMICAL, CARBON DIOXIDE (CO2) OR
ALCOHOL FOAM.
Fire Fighting Procedures:WEAR SELF-CONTAINED BREATHING APPARATUS &
PROTECTIVE CLOTHING TO PREVENT CONTACT W/SKIN AND EYES.
Unusual Fire/Explosion Hazard:NONE

Spill Release Procedures:FLUSH TO SEWER W/LG AMT OF WTER
(PH4.0-4.5).OTHERWISE ABSORB SPILL W/VERMICULITE OR OTHER SUITABLE
ABSORBENT & PLACE IN IMPERVIOUS CNTNR FOR DISPO IN APPROVED &
PERMITTED LANDFILL.CLEAN AREA THOROUGHL Y TO REMOVE RESIDUAL
CONTAMINATION.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

Handling and Storage Precautions:AVOID CONTACT W/EYE/SKIN/CLOTH.STORE
BETWEEEN 10-25C(50-80F).PROTECT SHIPMENTS FROM FREEZING(KEEP ABOVE
4C(40F)).
Other Precautions:NONE SPECIFIED BY MANUFACTURER.

Respiratory Protection:RESPIRATORS:SHOULD NOT BE REQUIRED.
Ventilation:GOOD GEN VENTI(10RM VOL/HR)SHOULD BE SUFFIC TO CNTRL
AIRBORNE LEVELS BEL RECOMMENDED EXPO LIMITS WHEN PROD USED AS INTEN
Protective Gloves:IMPERVIOUS GLOVES(NITRILE RUBBER)
Eye Protection:CHEM SPLASH GOGGLES OR FACE SHIELD
Other Protective Equipment:NONE SPECIFIED BY MANUFACTURER.
Work Hygienic Practices:LAUNDER CONTAM CLOTHES/SHOES PRIOR TO REUSE.
Supplemental Safety and Health
KEY1=HCC:N1. HEALTH:MAY CAUSE IRRIT OF GI TRACT.INHAL:VAPOR IRRIT.
2-PART KIT, SEE PNIND:G(PART B),F(PART A).

HCC:C3
Melt/Freeze Pt:M.P/F.P Text:NP
Decomp Temp:Decomp Text:NP
Spec Gravity:1.1
pH:4-4.5
Viscosity:NP
Solubility in Water:COMPLETE
Appearance and Odor:PALE YELLOW LIQUID W/CHARACTERISTIC FIXER SMELL
Percent Volatiles by Volume:NP
Corrosion Rate:NP

Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZING AGENTS, ACIDS, BASES, & SODIUM HYPOCHLORITE(BLEACH).
Stability Condition to Avoid:ALL SOLUTIONS STABLE UNDER NORMAL AMBIENT
& ANTICIPATED STORAGE & HNDLG CONDITIONS OF TEMPERATURE & PRESSURE.
Hazardous Decomposition Products:EXCESSIVE HEAT MAY PROD HAZ DECOMPO
PRODS.AMMONIA & OXIDES OF SULFUR.

Waste Disposal Methods:SOLN HAS PH THAT MAY CAUSE ADVERSE ENVIRO
EFFECTGS.ONCE NEUTRALIZED & DILUTED THESE EFFECGTS WILL BE LESSENED
SUBSTANTIALLY.DISCHARGE/TREAT/DISPO MAY BE SUBJ TO CERTAIN GOVT
REGS.SARA CHEMS:NONE.

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This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.