Product ID:E-Z DENATURED SOLVENT ALCOHOL
MSDS Date:01/01/1997
FSC:8010
NIIN:00N088333
MSDS Number: CHLXV

E E ZIMMERMAN CO

PITTSBURGH, PA 15238
US

Emergency Phone: 412-963-0949

Info Phone: 412-963-0949

Cage: ZMMER

E E ZIMMERMAN CO

111254 PITTSBURGH, PA 15238 US

Telephone: 412-963-0949

Cage: ZMMER

METHYL ALCOHOL (METHANOL) (SARA 313) (CERCLA)

CAS: 67-56-1

RTECS: PC1400000

Fraction By Weight: 57%

OSHA PEL S, 200 PPM

ACGIH TLV: S, 200 PPM/250 STEL

EPA Report Quantity: 5000 LBS

DOT Report Quantity: 5000 LBS

ETHYL ALCOHOL (ETHANOL)

CAS: 64-17-5

RTECS: KQ6300000

Fraction By Weight: 38-42%

OSHA PEL 1000 PPM

ACGIH TLV: 1000 PPM

WATER

CAS: 7732-18-5

RTECS: ZC0110000

Fraction By Weight: 1-4.5%

OSHA PEL N/K

ACGIH TLV: N/K

(NAUS, VOMIT, DIARR), IRRIT(NOSE, THROAT,

RTECS: 9999999ZZ

FATG, NAUS, HDCH, UNCON), LEG CRAMPS, INVOLUNTARY

RTECS: 9999999ZZ

BLURRED VISION, SHORTNESS OF BREATH, IMPAIRED COORD,

RTECS: 9999999ZZ

BLUISH DISCOLORATION OF SKIN & NAILS), ANESTH,

RTECS: 9999999ZZ

PROD CNTNS ETHANOL. ALCOHOLIC

RTECS: 9999999ZZ

DMG, & PANCREATITIS IN HUMANS. RELEVANCE OF THESE

RTECS: 9999999ZZ

UNCERTAIN. EXPOS TO LETHAL CONCS OF METHANOL HAS

RTECS: 9999999ZZ

PANCREAS, HEART, LUNGS & BRAIN. ALTHOUGH THIS

RTECS: 9999999ZZ

FROM PERM NEUROLOGICAL DMG. OVEREXP TO MATL (OR ITS

RTECS: 9999999ZZ

EFTS IN LAB ANIMALS, & MAY AGGRAVATE PRE-EXISTING

RTECS: 9999999ZZ

PANCREATIC DMG, LIVER DMG, CNS DMG, BRAIN DMG.

RTECS: 9999999ZZ

CAUSE OF FOLLOWING EFTS IN HUMANS, & MAY AGGRAVATE

RTECS: 9999999ZZ

WHILE

RTECS: 9999999ZZ

IN EXPERIMENTAL ANIMALS, RELEVANCE OF THESE FINDING

RTECS: 9999999ZZ

METABOLISM & TOX OF METHANOL BETWEEN HUMANS &

RTECS: 9999999ZZ

IF INDIVIDUAL IS CONSCIOUS & ALERT, INDUCE

RTECS: 9999999ZZ

FINGERS @ BACK OF THROAT. IF POSS, DO NOT LEAVE

RTECS: 9999999ZZ

SEEK IMMED MED ATTN; KEEP PERSON WARM & QUIET. IF

RTECS: 9999999ZZ

PROD CNTNS METHANOL

RTECS: 9999999ZZ

IS METABOLIZED TO FORMIC ACID AND FORMALDEHYDE. FOR

RTECS: 9999999ZZ

COMPLETED. STOP SPILL @ SOURCE. PVNT FROM

RTECS: 9999999ZZ

PVNT FROM SPREADING. IF RUNOFF OCCURS, NOTIFY AUTH

RTECS: 9999999ZZ

LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:ACUTE: EYE: CAUSES IRRIT. SYMPS MAY
INCL STINGING, TEARING, REDNESS & SWELL. SKIN: MAY CAUSE MILD
IRRIT. PRLNGD/RPTD EXPOS MAY DRY SKIN. SYMPS MAY INCL REDNESS,
BURNING, DRYING & CRACKING, & SKIN BURN S. SKIN ABSORP IS POSS, &
MAY CONTRIBUTE TO SYMPS OF TOX FROM OTHER ROUTES OF EXPOS. INGEST:
SINGLE (EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT.
Effects of Overexposure:HLTH HAZ: DOSE ORAL TOX IS MOD. INGEST MAY BE
HARMFUL. INHAL: EXPOS TO VAP/MIST IS POSS. SHORT-TERM INHAL TOX IS
LOW. BRTHG SM AMTS DURING NORM HNDLG IS NOT LIKELY TO CAUSE HARMFUL
EFTS. BRTHG LG AMTS MAY BE HARMFUL. SYMPS ARE MORE TYPICALLY SEEN
@ AIR CONCS EXCEEDING REC EXPOS LIMITS. SYMPS OF EXPOS: GI IRRIT
(ING 4)
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.

First Aid:EYES: IMMED MOVE AWAY FROM EXPOS & INTO FRESH AIR. FLUSH
GENTLY W/WATER FOR @ LST 15 MINS WHILE HOLDING EYELIDS APART. SEEK
IMMED MED MED ATTN. SKIN: REMOVE CONTAMD CLTHG. WASH EXPOS AREA
W/SOAP & WAT ER. IF SYMPS PERSIST, SEEK MED ATTN. LAUNDER CLTHG
BEFORE REUSE. INGEST: SEEK MED ATTN. IF INDIVIDUAL IS DROWSY/UNCON,
DO NOT GIVE ANYTHING BY MOUTH; PLACE INDIVIDUAL ON LEFT SIDE W/HEAD
DOWN.(ING 19)

Flash Point Method:TCC
Flash Point:>20F,>-7C
Lower Limits:1.4%
Extinguishing Media:ALCOHOL FOAM, CARBON DIOXIDE, DRY CHEMICAL.
Fire Fighting Procedures:USE NIOSH APPROVED SCBA & FULL PROTECTIVE
EQUIPMENT .
Unusual Fire/Explosion Hazard:VAPS ARE HVR/AIR & MAY TRAVEL ALONG
GROUND/MAY BE MOVED BY VENT & IGNITED BY PILOT LIGHTS, OTHER
FLAMES, SPKS, HEATERS, SMKNG, ELEC MOTORS, STATIC (SUPDAT)

Spill Release Procedures:SM SPILL: ABSORB LIQ ON VERMICULITE, FLOOR
ABSORB/OTHER ABSORB MATL. LG SPILL: ELIM ALL IGNIT SOURCES(FLARES,
FLAMES INCL PILOT LIGHT, ELEC SPKS). PERSONS NOT WEARING PROT EQUIP
SHOULD BE EXCLUDED FRO M AREA OF SPILL UNTIL CLEANUP HAS BEEN (ING
24)
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

Handling and Storage Precautions:ALL 5 GAL PAILS & LGR METAL CNTNRS
INCL TANK CARS & TANK TRUCKS SHOULD BE GROUNDED &/OR BONDED WHEN
MATERIAL IS TRANSFERRED.
Other Precautions:CNTNRS OF MATL MAY BE HAZ WHEN EMPTIED. SINCE EMPTIED
CNTNRS RETAIN PROD RESIDUES(VAP, LIQ, &/OR SOLID), ALL HAZ PREC
GIVEN IN DATA SHEET MUST BE OBSERVED. FOR MORE SPECIFIC INFORMATION
CONTACT NEHC ( ).

Respiratory Protection:IF WORKPLACE EXPOS LIM(S) OF PROD/ANY COMPONENT
IS EXCEEDED(SEE EXPOS GUIDELINES), NIOSH APPRVD AIR SUPPLIED RESP
IS ADVISED IN ABSENCE OF PROPER ENVIRONMENT CONTROL. FOR MORE
SPECIFIC INFORMATION CON T NEHC .
Ventilation:PROVIDE SUFFICIENT MECH(GEN AND/OR LOC EXHAUST) VENT TO
MAINTAIN EXPOS BELOW TLV(S).
Protective Gloves:RESISTANT GLOVES.
Eye Protection:ANSI APPRVD CHEM WORKERS GOGGLES .
Other Protective Equipment:ANSI APPRVD EYE WASH & DELUGE SHOWER . TO
PVNT RPTD/PRLNGD SKIN CONT, WEAR IMPERVIOUS CLOTHING AND BOOTS.
Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health
VP: 97.680 @ 68F. EXPLO HAZ: DISCHARGE/OTHER IGNIT SOURCES @ LOCATIONS
DIST FROM MATL HNDLG POINT. NEVER USE WELDING/CUTTING TORCH ON/NEAR
DRUM (EVEN EMPTY) BECAUSE PROD (EVEN JUST RESIDUE) CAN IGNITE
EXPLOSIVELY. HAZ PRODS OF COMBUST: MAYFORM: CARBON DIOXIDE & CARBON
MONOXIDE, VARIOUS HYDROCARBONS.

Boiling Pt:B.P. Text:147F,64C
Vapor Pres:SUPDAT
Vapor Density:1.000
Spec Gravity:0.301 @ 77F
Evaporation Rate & Reference:SLOWER THAN ETHYL ETHER
Solubility in Water:NOT KNOWN
Appearance and Odor:LIQUID. NO ODOR.

Stability Indicator/Materials to Avoid:YES
AVOID CONTACT WITH: STRONG OXIDIZING AGENTS.
Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER.
Hazardous Decomposition Products:MAY FORM: CARBON DIOXIDE AND CARBON
MONOXIDE.

Waste Disposal Methods:DISPOSE OF IN ACCORDANCE WITH ALL APPLICABLE
LOCAL, STATE AND FEDERAL REGULATIONS.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.