CHMCK - PERCHLOROETHYLENE

  • MSDS: CHMCK
  • Manufacturer: VULCAN CHEMICALS
  • Product Name: PERCHLOROETHYLENE
  • National Stock Number: 6810-00-819-1128
Product Identification

Product ID:PERCHLOROETHYLENE
MSDS Date:12/01/1993
FSC:6810
NIIN:00-819-1128
MSDS Number: CHMCK

Responsible Party
VULCAN CHEMICALS
BIRMINGHAM, AL 35253-0390
US

Emergency Phone: 316-524-5751

Info Phone: 800-843-4898

Cage: EO675

Contractor
VULCAN MATERIALS CO
530390 BIRMINGHAM, AL 35253 US

Telephone: 316-524-5751

Cage: 1B637

Ingredients

TETRACHLOROETHYLENE (SARA III)

CAS: 127-18-4

RTECS: KX3850000

Fraction By Weight: 100%

OSHA PEL 100 PPM

ACGIH TLV: 25PPM/100,A3 STEL;94

EPA Report Quantity: 100 LBS

DOT Report Quantity: 100 LBS

Hazards

Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:NO
Health Hazards Acute and Chronic:ACUTE-INHALE:IRRITATION, FLUSHED
FACE/NECK, HEADACHE, SLURRED SPEECH, DROWSINESS, DIZZINESS,
LIGHTHEADED, NUMB AROUND MOUTH, NARCOSIS, VERTIGO, NAUSEA,
CONFUSION, UNCONSCIOUS, & DEATH. EYE:PAIN/IRRITA TION, TEMPORARY
DAMAGE. INGEST:GI IRRITATION, NAUSEA, VOMITING, STOMACH CRAMPS,
DIARRHEA. ASPIRATION: CHEMICAL PNEUMONIA
Explanation of Carcinogenicity:SUFFICIENT EVIDENCE OF CARCINOGENICITY
OF PERCHLOROETHYLENE IN ANIMALS, INADEQUATE EVIDENCE (HUMANS). PROP
65 (CALIF) .
Effects of Overexposure:CHRONIC-SKIN: PROLONGED/REPEATED CONTACT CAN
CAUSE IRRITATION, DEFATTING OF SKIN & DERMATITIS. PROLONGED SINGLE
EXPOSURE CAN RESULT IN PROGRESSIVELY SEVERE BURNING SENSATION &
REDNESS. ABSORPTION THRO UGH INTACT SKIN POSSIBLE IF CONTACT WITH
LIQUID IS PROLONGED. ANIMAL STUDIES: LIVER & KIDNEY TOXIC EFFECTS.
Medical Cond Aggravated by Exposure:ACUTE AND CHRONIC LIVER DISEASE,
RHYTHMS DISORDERS OF THE HEART AND NEURITIS.

First Aid

First Aid:INHAL:REMOVE TO FRESH AIR. IF BREATHING STOPPED, GIVE CPR.
CALL DR. SKIN:REMOVE SOILED CLOTHES & SHOES. WASH EXPOSED AREA
W/SOAP & WATER 15 MIN. EYES:FLUSH EYES IMMEDIATELY WITHER FOR 15
MIN. IF IRRIT ATION PERSISTS, CALL DR. INGEST:DONT INDUCE VOMITING.
CONTACT DOCTOR/EMERGENCY MEDICAL FACILITY IMMEDIATELY. NOTE:DONT
GIVE ADRENALIN TO PERSONS EXPOSED TO PERCHLOROETHYLENE.

Fire Fighting

Flash Point Method:TCC
Flash Point:NONE
Lower Limits:NONE
Upper Limits:NONE
Fire Fighting Procedures:FIREFIGHTERS SHOULD WEAR SELF CONTAINED
POSITIVE-PRESSURE BREATHING APPARATUS AND AVOID SKIN CONTACT.

Accidental Release

Spill Release Procedures:EVACUATE THE AREA, VENTILATE & AVOID BREATHING
VAPORS. DIKE AREA TO CONTAIN SPILL. TURN OFF HEATING/AIR
CONDITIONING SYSTEMS, PREVENT VAPORS FROM CONTAMINATING ENTIRE
BUILDING. CLEAN UP AREA BY MOPPIN G OR WITH ABSORBENT MATERIAL &
TRANSFERTO CONTAIN

Handling

Handling and Storage Precautions:FOLLOW CONTROL MEASURES WHEN HANDLING
PRODUCT. STORE IN LABELED, SEALED CNTNRS IN COOL, DRY, VENTED AREA.
DONT USE ALUMINUM EQUIP FOR TRANSFER/STORAGE
Other Precautions:PREVENT WATER/MOIST AIR ENTERING STORAGE TANKS/
CONTAINERS. DONT CUT/WELD ON EMPTY/FULL DRUMS. VAPOR HEAVIER THAN
AIR, COLLECT IN LOW AREAS. DONT ENTER CONFINED SPACES W/O FOLLOWING
ENTRY PROCEDURES ( ASTM D-4276).DONT REMOVE/DEFACE LABEL.

Exposure Controls

Respiratory Protection:ABOVE 25 PPM WEAR NIOSH/MSHA ORGANIC VAPOR TYPE
HALF MASK RESPIRATOR. NIOSH/MSHA SCBA OR AIR LINE RESPIRATOR WITH
FULL FACE PIECE REQUIRED FOR CONCENTRATIONS ABOVE 250 PPM AND FOR
SPILLS OR EMERGENCIE S. FOLLOW RESPIRATOR USE STANDARDS/REGS.
Ventilation:DONT USE IN CLOSED OR CONFINED SPACE. OPEN DOORS AND/OR
WINDOWS. USE VENT TO MAINTAIN EXPOSURE LEVELS BELOW 25 PPM.
Protective Gloves:VITON, POLYVINYL ALCOHOL OR EQUAL
Eye Protection:SAFETY GLASSES, CHEM GOGGLES, FACESHIELD
Other Protective Equipment:WEAR SOLVENT RESISTANT BOOTS, APRON,
HEADGEAR, FACESHIELD WHERE SPLASHING POSSIBILE. EYEWASH STATION &
SAFETY SHOWER.
Work Hygienic Practices:AVOID SKIN CONTACT, BREATHING VAPOR. DONT EAT,
DRINK,SMOKE IN WRK AREA. WASH HANDS BEFORE EATING,DRINKING,USING
RESTRM.
Supplemental Safety and Health
WASH CONTAMINATED CLOTHING & SHOES BEFORE REUSE. TO DETERMINE EXPOSURE
LEVELS, PERFORM MONITORING REGULARLY. NOTE: SELECT/USE/MAINTAIN
PROTECT EQUIP ACCORDING TO STANDARDS/REGS. FOR INFO, CONTACT CLOT
HING/EQUIP MFR OR VULCAN CHEMICAL TECH DEPT.

Chemical Properties

HCC:T4
Boiling Pt:B.P. Text:250F,121C
Vapor Pres:13 @ 20C
Vapor Density:5.8
Spec Gravity:1.62 @ 25C
Evaporation Rate & Reference:9.1 (ETHER=1)
Solubility in Water:0.015 GM/100 GM @25C
Appearance and Odor:COLORLESS, CLEAR LIQUID; MILDLY SWEET ODOR
Percent Volatiles by Volume:100

Stability

Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZERS, BARIUM, LITHIUM
Stability Condition to Avoid:AVOID CONTACT WITH OPEN FLAME, ELECTRIC
ARC, OR OTHER HOT SURFACES WHICH CAN CAUSE THERMAL DECOMPOSITION.
Hazardous Decomposition Products:HYDROGEN CHLORIDE, PHOSGENE, CHLORINE
Conditions to Avoid Polymerization:AVOID CONTACT WITH OPEN FLAME,
ELECTRIC ARC, OR OTHER HOT SURFACES WHICH CAN CAUSE THERMAL
DECOMPOSITION.

Disposal

Waste Disposal Methods:RECOVERED LIQUID MAY BE SENT TO LICENSED
RECLAIMER/INCINERATION FACILITY. CONTAMINATED MATERIAL MUST BE
DISPOSED OF IN WASTE MANAGEMENT FACILITY. CONSULT FED, STATE &
LOCAL DISPOSAL AUTHORITIES FOR PR OCEDURES. DONT REUSE W/O
RECYCLING/RECONDITIONS.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.