Product ID:FUMITOXIN
MSDS Date:11/01/1997
FSC:6840
NIIN:00-442-5698
MSDS Number: CHQJF

EHRLICH J C CHEMICAL CO INC

500 SPRING RIDGE DR
READING, PA 19612-3848
US

Emergency Phone: 610-378-9744

Info Phone: 610-378-9744

Cage: 8C885

EHRLICH J C CHEMICAL CO INC

READING, PA 19612-3848 US

Telephone: 610-378-9744

Cage: 8C885

ALUMINUM PHOSPHIDE (SARA 302) (CERCLA)

CAS: 20859-73-8

RTECS: BD1400000

Fraction By Weight: 55%

EPA Report Quantity: 100 LBS

DOT Report Quantity: 100 LBS

INERT INGREDIENTS (INCLUDING AMMONIUM CARBONATE)

Fraction By Weight: 45%

LD50 LC50 Mixture:LC50 ABOUT 190PPM FOR 1H/LD50 11.5 MG/KG
Routes of Entry: Inhalation:YES Skin:NO Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:TARGET ORGANS:EYES, SKIN, CNS,
RESPIRATORY & GI TRACTS. ACUTE- INHALATION OF PHOSPHINE GAS FORMED
BY AIR MOISTURE/WATER/ ACID MAY CAUSE CNS EFFECTS, POISONING,
CYANOSIS, UNCONSCIOUSNESS & DEATH. INGES TION CAN BE FATAL. DUST
CAN IRRITATE & BURN EYES. MAY CAUSE SKIN IRRITATION. CHRONIC-
UNKNOWN.
Explanation of Carcinogenicity:NONE
Effects of Overexposure:MILD EXPOSURE CAUSES MALAISE, RINGING OF EARS,
FATIGUE, NAUSEA AND PRESSURE IN CHEST. MODERATE POISONING CAUSES
WEAKNESS, VOMITING, PAIN ABOVE THE STOMACH, CHEST PAIN, DIARRHEA
AND DIFFICULTY BREATHIN G. SEVERE POISONING MAY CAUSE FLUID IN THE
LUNGS, DIZZINESS, BLUE OR PURPLE SKIN COLOR, UNCONSCIOUSNESS,
DEATH.

First Aid:CALL PHYSICIAN IF SYMPTOMS PERSIST. EYE: IMMEDIATELY FLUSH
WITH WATER FOR 15 MINUTES. HOLD EYELIDS OPEN. SKIN:WASH WITH SOAP &
WATER. INHALED:REMOVE TO FRESH AIR. PROVIDE CPR/OXYGEN IF NEEDED.
ORAL:IF CONSCIOUS, DRINK TWO GLASSES OF WATER & INDUCE VOMITING.
CALL A PHYSICIAN/POISON CONTROL CENTER IMMEDIATELY. NEVER GIVE
FLUID OR INDUCE VOMITING IF PATIENT IS UNCONSCIOUS OR HAS
CONVULSIONS.

Flash Point:NONE
Lower Limits:NOT RELEVANT
Upper Limits:NOT RELEVANT
Extinguishing Media:USE CARBON DIOXIDE, DRY CHEMICAL OR SAND. DO NOT
USE WATER.
Fire Fighting Procedures:WEAR FULL PROTECTIVE CLOTHING AND NIOSH-
APPROVED SELF-CONTAINED BREATHING APPARATUS WITH FULL FACEPIECE
OPERATED IN POSITIVE PRESSURE MODE.
Unusual Fire/Explosion Hazard:DO NOT CONFINE SPENT ALUMINUM PHOSPHITE
RESIDUES. ANY HYDROGEN PHOSPHIDE GAS RELEASED MAY IGNITE.

Spill Release Procedures:IF AMOUNTS OF SPILL IS UNKNOWN, WEAR SELF-
CONTAINED BREATHING APPARATUS. DO NOT USE WATER TO CLEAN UP SPILL.
WEAR GLOVES AND TRANSFER UNCONTAMINATED SPILL TO SUITABLE CONTAINER
FOR REUSE. CONTAMINATE D SPILL SHOULD BE DEACTIVATED BY
WATER+DETERGENT.
Neutralizing Agent:2% SOLUTION OF DETERGENT IN WATER

Handling and Storage Precautions:STORE IN A DRY, WELL VENTILATED AREA,
AWAY FROM HEAT, INCOMPATIBLES AND UNDER LOCK AND KEY. STORAGE
SHOULD BE AWAY FROM HUMAN, FOOD, FEED AND WATER.
Other Precautions:ALWAYS OPEN CONTAINERS IN OPEN AIR BECAUSE UNDER
CERTAIN CONDITIONS THEY MAY FLASH. WHEN OPENING, VENT THE
CONTAINERS AWAY FROM FACE AND BODY AND OPEN SLOWLY. NEVER OPEN
CONTAINERS IN A FLAMMABLE ATMO SPHERE. KEEP OUT OF REACH OF
CHILDREN.

Respiratory Protection:IF ENGINEERING CONTROLS DO NOT MAINTAIN AIRBORNE
CONCENTRATIONS TO AN ACCEPTABLE LEVEL, A NIOSH-APPROVED SELF
CONTAINED BREATHING APPARATUS MUST BE WORN.
Ventilation:USE GENERAL OR LOCAL EXHAUST VENTILATION TO KEEP FUME OR
DUST LEVELS AS LOW AS POSSIBLE.
Protective Gloves:COTTON, LATEX
Eye Protection:SAFETY GLASSES WITH SIDE SHIELD/GOGGLES
Other Protective Equipment:EYE BATH, WASHING FACILITIES, SAFETY SHOWER
AND IMPERVIOUS CLOTHING
Work Hygienic Practices:OBSERVE GOOD INDUSTRIAL HYGIENE PRACTICES AND
RECOMMENDED PROCEDURES. WASH THOROUGHLY BEFORE EATING,
DRINKING/SMOKING.
Supplemental Safety and Health
THE DATA FOR THE PHYSICAL PROPERTIES ARE FOR THE ALUMINUM PHOSPHIDE,
NOT FOR THE PRODUCT AS A WHOLE.

HCC:R2
NRC/State Lic Num:NOT RELEVANT
Boiling Pt:B.P. Text:>1832F,>100
Melt/Freeze Pt:M.P/F.P Text:>1832F,>100
Vapor Pres:0
Spec Gravity:2.85
Viscosity:NOT RELEVANT
Evaporation Rate & Reference:NOT RELEVANT
Solubility in Water:INSOLUBLE (REACTS)
Appearance and Odor:GREENISH GRAY SOLID. GARLIC OR DECAYING FISH ODOR.

Stability Indicator/Materials to Avoid:YES
WATER, STRONG OXIDIZING AGENTS, ACIDS
Stability Condition to Avoid:MOISTURE

Waste Disposal Methods:IF TABLETS, PELLETS OR BAGS ARE EXPOSED TO
CONTAMINATION BY WATER, ACIDS OR ATMOSPHERIC MOISTURE, IMMEDIATELY
CONTACT PESTCON SYSTEMS 919-859-2500 FOR GUIDANCE. DISPOSE IN
ACCORDANCE WITH ALL APPLICAB LE LOCAL, STATE AND FEDERAL
REGULATIONS.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.