Product ID:SILVALOY 32, AG-CU-ZN-CD
MSDS Date:11/13/1997
FSC:3439
NIIN:00N089202
Status Code:A
MSDS Number: CHTSQ

ENGELHARD CORP

235 KILVERT ST
WARWICK, RI 02886
US

Emergency Phone: 800-424-9300 (CHEMTREC)

Info Phone: 401-739-9550

Cage: ENGEL

ENGELHARD CORP

SOLON, OH 44139 US

Telephone: 216-292-9200

Cage: ENGEL

SILVER (SARA 313) (CERCLA)

CAS: 7440-22-4

RTECS: VW3500000

Fraction By Weight: 19-60%

OSHA PEL 0.01 MG/M3

ACGIH TLV: 0.1 MG/M3; 9495

EPA Report Quantity: 1 LB

DOT Report Quantity: 1 LB

COPPER (SARA 313) (CERCLA)

CAS: 7440-50-8

RTECS: GL5325000

Fraction By Weight: 5-50%

OSHA PEL 0.1MG/M3 FUME/1 DUST

ACGIH TLV: 0.2 MG/M3 FUME; 9495

EPA Report Quantity: 5000 LBS

DOT Report Quantity: 5000 LBS

CADMIUM (SARA 313) (CERCLA)

CAS: 7440-43-9

RTECS: EU9800000

Fraction By Weight: 1-30%

OSHA PEL 0.2 MG/M3 DUST; Z-2

ACGIH TLV: 0.01 MG/M3 DUST;9495

EPA Report Quantity: 10 LBS

DOT Report Quantity: 10 LBS

ZINC (SARA 313) (CERCLA)

CAS: 7440-66-6

RTECS: ZG8600000

Fraction By Weight: 5-40%

OSHA PEL N/K

ACGIH TLV: N/K

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

NONE

RTECS: 9999999VO

OSHA PEL N/K

ACGIH TLV: N/K

POTNTL HLTH EFTS DESCRIBED ABOVE ONLY

RTECS: 9999999ZZ

TO COPPER POISONING, RSLTG IN HEMOLYTIC ANEMIA &

RTECS: 9999999ZZ

CADMIUM, EVEN AT RELATIVELY LOW CONC, MAY RSLT IN

RTECS: 9999999ZZ

INTAKE HAS BEEN ASSOC W/COPPER DEFICIENCY ANEMIA.

RTECS: 9999999ZZ

LOCALIZED BLUE-GREY DISCOLORATION OF EYES, SKIN OR

RTECS: 9999999ZZ

LUNG, PROSTATE, RENAL

RTECS: 9999999ZZ

COUNTERMEASURE PLAN (SPCC). SUCH PLAN SHOULD

RTECS: 9999999ZZ

OF SPILLS, INCL REUSE/DISP AS APPROP (SEE SECTION

RTECS: 9999999ZZ

ACCIDENTAL RELS OF THIS MATL, ABOVE PROC SHOULD BE

RTECS: 9999999ZZ

EXPOSURE

RTECS: 9999999ZZ

MATERIAL SHOULD BE IN ACCORDANCE WITH SECTION 7

RTECS: 9999999ZZ

DISPOSAL/RECYCLING/RECLAMATION

RTECS: 9999999ZZ

CONSULT W/FED, STATE & LOCAL REGULATORY AUTH. NOTE

RTECS: 9999999ZZ

MAY MAKE WASTE MANAGEMENT INFO PRESENTED ABOVE

RTECS: 9999999ZZ

LOCAL REGULATIONS MAY VARY; ALL WASTE MUST BE

RTECS: 9999999ZZ

STATE, AND LOCAL ENVIRONMENTAL CONTROL REGULATIONS.

RTECS: 9999999ZZ

USE ONLY WITH ADEQUATE VENTILATION. DO NOT EAT,

RTECS: 9999999ZZ

(PRACTICES FOR RESPIRATOR PROTECTION).

RTECS: 9999999ZZ

LD50 LC50 Mixture:SEE INGREDIENTS.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:YES
Health Hazards Acute and Chronic:EYE: MAY CAUSE IRRIT. SKIN: MAY CAUSE
IRRIT. INHAL: MAY CAUSE RESP TRACT IRRIT, CHEST PAIN & LABORED
BRTHG. SEV EXPOS MAY LEAD TO PULM EDEMA/EXCESSIVE CADMIUM
ABSORPTION RESULTING IN PULM EMPHYSEMA, & /LIVER & KIDNEY
DYSFUNCTION. INGEST: HARMFUL. MAY CAUSE ABDOM PAIN, NAUS, VOMIT &
DIARR. COPPER (EFTS OF OVEREXP)
Explanation of Carcinogenicity:CADMIUM: IARC MONO, VOL 58, PG 119,
1993: GROUP 1. NTP 7TH ANNUAL RPT ON CARCINS, 1994: ANTIC TO BE
(ING 11)
Effects of Overexposure:HLTH HAZ: POISONING CAN RSLT IN HEMOLYTIC
ANEMIA & KIDNEY, LIVER & SPLEEN DMG. NOTE: INHAL OF FUMES MAY CAUSE
A FLU-LIKE ILLNESS CALLED METAL FUME FEVER. TYPICALLY METAL FUME
FEVER BEGINS 4 TO 12 HRS AFTER SUFFICIENT EXPOS TO FRESHLY FORMED
FUMES. FIRST SYMPS ARE A METALLIC TASTE, DRYNESS & IRRIT OF THROAT.
(SUPDAT)
Medical Cond Aggravated by Exposure:MAY ADVERSELY AFFECT EXISTING MED
CNDTNS, SUCH AS EYE, SKIN, RESP, BLOOD, LIVER &/KIDNEY AILMENTS.
INDIVIDUALS W/WILSON'S DISEASE ARE AT INCRD RISK OF COPPER
POISONING. NOTE: SEE SECTION 2 EXPOS LIMS.

First Aid:EYE: FLUSH W/PLENTY OF H*2O FOR @ LEAST 15 MIN. IF IRRIT
DEVELOPS, CALL MD. SKIN: IMMED WASH SKIN W/SOAP & PLENTY OF H*2O.
IF IRRIT PERSISTS, CALL MD. INHAL: IF EXPOSED TO EXCESSIVE LEVELS
OF METAL FU MES, REMOVE TO FRESH AIR & SEEK MED ATTN. INGEST: IF
PERS IS CONSCIOUS & ABLE TO SWALLOW, GIVE LRG AMTS OF H*2O TO
DILUTE. IF VOMIT OCCURS, KEEP HEAD BELOW HIPS TO HELP PVNT ASPIR.
GET MED ATTN IMMED.

Extinguishing Media:USE CARBON DIOXIDE, CHEM FOAM/DRY CHEM. USE ANY
MEANS FOR EXITNG SURROUNDING FIRE. DO NOT USE WATER ON METAL FIRES.
Fire Fighting Procedures:USE NIOSH APPROVED SCBA & FULL PROTECTIVE
EQUIPMENT .
Unusual Fire/Explosion Hazard:NOT A FIRE/EXPLOSION HAZ IN SOLID FORM.
FINELY DIVIDED DUST MAY IGNITE & BURN RAPIDLY WHEN MIXED W/AIR IN
PROPER PROPORTIONS. TOX METAL FUMES MAY BE (SUPDAT)

Spill Release Procedures:CNTN SPILLAGE & SCOOP UP/VACUUM. NOTIFICATION
OF NATIONAL RESPONSE CENTER (800/424-8802) MAY BE REQD. REFER TO
EPA, DOT & APPLIC STATE & LOCAL REGS FOR CURRENT RESPONSE INFO. IT
IS REC THAT EACH USER ESTABLISH A SPILL PREVENTION, CONTROL &(ING
12)
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

Handling and Storage Precautions:STORE IN A COOL, DRY LOCATION AWAY
FROM INCOMPATIBLE MATERIALS. AVOID BREATHING ANY DUST, MIST OR
FUMES RESULTING FROM THE USE OF THIS PRODUCT.
Other Precautions:AVOID CNTCT W/ANY DUSTS, MISTS/FUMES RSLTG FROM USE
OF THIS PROD. NOTE: CONSULT MOST RECENT OSHA CADMIUM STANDARD
(1910.1027) & ITS ATTACHMENTS, APPENDICES, ETC., FOR FULL
REQUIREMENTS, SOME OF WHICH ARE NOT COVERED IN THIS MSDS. (ING 22)

Respiratory Protection:IF DUST/FUME IS GENERATED, A NIOSH APPRVD RESP
MAY BE NEC. FOLLOW ALL REQUIREMENTS FOR RESP PROGRAMS & SELECTION
SET FORTH IN OSHA REGS (29 CFR 1910.134, REDESIGNATED TO 29 CFR
1910.139 AS OF APRIL 8, 1998) & IN ANSI Z88.2-92 (ING 23)
Ventilation:GEN, LOC EXHST VENT AS NEC TO CONTROL ANY AIR CONTAMINANTS
TO W/IN THEIR PELS/TLVS DURING USE OF THIS PRODUCT.
Protective Gloves:IMPERVIOUS GLOVES .
Eye Protection:ANSI APPROVED CHEM WORKERS GOGGS .
Other Protective Equipment:EYE WASH FOUNTAIN & DELUGE SHOWER WHICH MEET
ANSI DESIGN CRITERIA .
Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING.
Supplemental Safety and Health
SPEC GRAV: 8.71-9.45 (H*2O=1). EXPLO HAZ: RELS IN A FIRE SITUATION.
MATLS TO AVOID: TURPENTINE, MAGNESIUM METAL, AMMONIUM NITRATE,
HYDROGEN SULFIDE. EFTS OF OVEREXP: COUGH & SHORTNESS OF BREATH MAY
OC CUR ALONG W/HDCH, FATIGUE, NAUS, VOMIT,MUSCLE & JOINT PAIN,
FEVER & CHILLS. SYNDROME RUNS ITS COURSE IN 24-48 (ING 6)

Melt/Freeze Pt:M.P/F.P Text:1128F,609C
Spec Gravity:SUPDAT
Solubility in Water:INSOLUBLE
Appearance and Odor:METALLIC WIRE, ROD OR STRIP; ODORLESS.

Stability Indicator/Materials to Avoid:YES
STRONG ACIDS AND BASES, STRONG OXIDIZERS, ACETYLENE AMMONIA, HYDROGEN
PEROXIDE, CHLORINE, BROMINE, IODINE, (SUPDAT)
Stability Condition to Avoid:NONE EXPECTED.
Hazardous Decomposition Products:TOX METAL OXIDES ARE EMITTED WHEN
HEATED ABOVE MELTING POINT. THE AMOUNT OF FUME EVOLVES INCREASES AS
THE TEMP RISES.

Waste Disposal Methods:U S EPA WASTE NUMBER: D006, D011. THIS PROD MAY
BE HAZ WASTE UNDER EPA WASTE REGS. BEFORE DISP, THIS PROD/MIX CNTNG
THIS PROD SHOULD BE TESTED FOR TOX CHARACTS (TC) UNDER CURRENT EPA
HAZ WASTE REGS TC LP TESTING PROCS, 40 CFR PART 261 ET SEQ. (ING
17)

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.