Product ID:QD ENAMEL UNDERCOATER, 6-6
MSDS Date:11/22/1996
FSC:8010
NIIN:00-537-6864
Status Code:A
MSDS Number: CHXQD

PPG INDUSTRIES INC

4325 ROSANNA DR
ALLISON PARK, PA 15101
US

Emergency Phone: 304-843-1300

Info Phone: 412-492-5555

Cage: DO542

PPG INDUSTRIES INC. COATINGS & RESINS GP

9 ALLISON PARK, PA 15101

Telephone: 412-492-5555

Cage: DO542

CALCIUM CARBONATE

CAS: 1317-65-3

RTECS: EV9580000

Fraction By Weight: 50-<60%

OSHA PEL 15 MG/M3 TDUST

ACGIH TLV: 10 MG/M3 TDUST

TITANIUM DIOXIDE

CAS: 13463-67-7

RTECS: XR2275000

Fraction By Weight: 10-<20%

OSHA PEL 15 MG/M3 TDUST

ACGIH TLV: 10 MG/M3 TDUST

SILICA, CRYSTALLINE - QUARTZ; (QUARTZ)

CAS: 14808-60-7

RTECS: VV7330000

Fraction By Weight: 0.1-<1%

OSHA PEL N/K

ACGIH TLV: 0.1 MG/M3 RDUST

STODDARD SOLVENT; (NAPHTHA)

CAS: 8052-41-3

RTECS: WJ8925000

Fraction By Weight: 20-<30%

OSHA PEL 500 PPM

ACGIH TLV: 100 PPM

2-BUTANONE, OXIME; (METHYL ETHYL KETOXIME)

CAS: 96-29-7

RTECS: EL9275000

Fraction By Weight: 0.1-<1%

OSHA PEL N/K

ACGIH TLV: N/K

IGNIT SOURCES (IE, PILOT LIGHTS, ELEC MOTORS,

RTECS: 9999999ZZ

FLASH BACK. DO NOT SMOKE WHILE USING PROD. KEEP

RTECS: 9999999ZZ

EXPLODE WHEN OVERHEATED. DO NOT APPLY TO HOT SURFS.

RTECS: 9999999ZZ

MW POLYMER FRACTIONS. EXTREME HEAT

RTECS: 9999999ZZ

SILICOSIS. THESE EFTS ARE ASSOC W/BRTHG

RTECS: 9999999ZZ

CONTAINS TITANIUM DIOXIDE. ANIMALS INHALING MASSIVE

RTECS: 9999999ZZ

PIGMENT INDICATE NO INCREASED RISK OF CANCER FROM

RTECS: 9999999ZZ

FROM COATINGS IS VERY LIMITED. SINCE OVEREXPS ARE

RTECS: 9999999ZZ

THIS PROD CONTAINS METHYL ETHYL KETOXIME. STUDIES

RTECS: 9999999ZZ

IN SPLEEN & KIDNEY, ANEMIA, LIVER CANCER &

RTECS: 9999999ZZ

MIST, REMOVE TO FRESH AIR. APPLY ARTF RESP

RTECS: 9999999ZZ

ANY TYPE OF OVEREXP OR SYMPS OF OVEREXP OCCUR

RTECS: 9999999ZZ

CONTROL CENTER, EMERGENCY ROOM OR MD IMMED; HAVE

RTECS: 9999999ZZ

EMPTY CNTNRS FOR DISPOSAL. ONLY SPILLED MATL &

RTECS: 9999999ZZ

AVOID FREE FALL OF LIQUIDS IN EXCESS OF A FEW

RTECS: 9999999ZZ

INSTRUCTIONS & LITERATURE CAREFULLY TO DETERMINE

RTECS: 9999999ZZ

EFFECTIVE, ITS LIMITATIONS & HOW IT IS TO BE

RTECS: 9999999ZZ

SUGGESTED EXPOSURE LIMITS, LEL BELOW STATED LIMIT &

RTECS: 9999999ZZ

BEEN DONE ON PROT CLTHG FOR PROD. RECOMS

RTECS: 9999999ZZ

FOR FREQUENT CONTACT OR TOTAL IMMERSION, CONTACT

RTECS: 9999999ZZ

LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:NO
Health Hazards Acute and Chronic:EFTS OF OVEREXP FROM: INGEST: MAY BE
HARMFUL IF SWALLOWED. EYE CNTCT: CAUSES EYE IRRIT. SKIN CNTCT: MAY
CAUSE SLIGHT SKIN IRRIT. INHAL: VAP &/OR SPRAY MIST MAY BE HARMFUL
IF INHALED. RPTD EXPOS TO HIG H VAP CONCS MAY CAUSE IRRIT OF RESP
SYS& PERM BRAIN & NERVOUS SYS DMG. SIGNS & SYMPS OF OVEREXP: EYE
(EFTS OF OVEREXP)
Explanation of Carcinogenicity:QUARTZ, SILICA-CRYSTALLINE: IARC MONO,
VOL 68, 1997:GROUP 1. NTP 7TH ANNUAL REPORT ON CARCINS, 1994:ANTIC
TO BE CARCIN.
Effects of Overexposure:HLTH HAZ: WATERING, HDCHS, NAUS, DIZZ & LOSS OF
COORD ARE INDICATIONS THAT SOLV LEVELS ARE TOO HIGH. INTENTIONAL
MISUSE BY DELIB CONC & INHALING CONTENTS CAN BE HARMFUL/FATAL.
CHRONIC: AVOID LONG-TERM & RPTD CNTCT. LONG-TERM EXPOS TO
CRYSTALLINE SILICA/QUARTZ MAY ALSO LEAD TO DISABLING INJURY KNOWN
AS (ING 10)
Medical Cond Aggravated by Exposure:NOT APPLICABLE.

First Aid:INGEST: IF SWALLOWED, DO NOT INDUCE VOMITING. GENTLY WIPE OUT
INSIDE MOUTH TO REMOVE ANY RESIDUAL MATL. EYES: IN CASE OF EYE
CNTCT, REMOVE CONTACT LENSES & FLUSH EYES IMMED W/GENTLE STREAM OF
LUKEWARM WATER FOR AT LEAST 15 MIN. SKIN: IN CASE OF SKIN CNTCT,
FLUSH IMMED W/PLENTY OF WATER FOR AT LEAST 15 MIN FOLLOWED BY
WASHING W/SOAP & WATER. INHAL: IF AFFECTED BY INHAL OF VAPOR OR
SPRAY (ING 16)

Flash Point Method:PMCC
Flash Point:107F,42C
Lower Limits:1.0%
Extinguishing Media:USE NFPA CLASS B EXTINGS (CARBON DIOXIDE, DRY CHEM
OR UNIVERSAL QA FILM FORMING FOAM) DESIGNED TO EXTING NFPA (SUPDAT)
Fire Fighting Procedures:USE NIOSH APPRVD SCBA & FULL PROT EQUIP .
WATER SPRAY MAY BE INEFTIVE. WATER SPRAY MAY BE USED TO COOL CLSD
CNTNRS TO PVNT PRESS BUILD-UP & POSS (SUPDAT)
Unusual Fire/Explosion Hazard:WHEN PROD IS USED, OVERSPRAY & OTHER
COMBUST MATLS SUCH AS PAINT BOOTH FILTERS, RAGS, MASKING MATLS,
ETC, CONTAM BY COATING MATL ARE SUBJECT TO SPONT (SUPDAT)

Spill Release Procedures:PROVIDE MAXIMUM VENT. ONLY PERS EQUIPPED
W/PROPER NIOSH APPRVD RESP PROT & SKIN & EYE PROT SHOULD BE
PERMITTED IN AREA. REMOVE ALL SOURCES OF IGNIT. TAKE UP SPILLED
MATL W/SAND, VERMICULITE OR OTHER N ONCOMBUST ABSORB MATL & PLACE
IN CLEAN,(ING 19)
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

Handling and Storage Precautions:DO NOT STORE ABOVE 120F (48C). STORE
LARGE QUANTITIES IN BUILDINGS DESIGNED AND PROTECTED FOR STORAGE OF
NFPA CLASS II COMBUSTIBLE LIQUIDS.
Other Precautions:VAPS MAY COLLECT IN LOW AREAS. IF THIS MATL IS PART
OF MULTIPLE COMPONENT SYSTEM, READ MSDS FOR OTHER COMPONENT OR
COMPONENTS BEFORE BLENDING AS RSLTG MIX MAY HAVE HAZS OF ALL OF ITS
PARTS. CNTNRS SHO ULD BE GROUNDED WHEN POURING. (ING 20)

Respiratory Protection:OVEREXP TO VAPS MAY BE PREVENTED BY ENSURING
PROPER VENT CONTROLS, VAP EXHST OR FRESH AIR ENTRY. A NIOSH APPRVD
AIR PURIFYING RESP W/APPROP CHEM CARTRIDGES OR POSITIVE-PRESS,
AIR-SUPPLIED RESP MAY ALS O REDUCE EXPOS. READ RESP MFR'S (ING 21)
Ventilation:PROVIDE GEN DILUTION OR LOCAL EXHAUST VENT IN VOLUME &
PATTERN TO KEEP CONC OF INGREDS LISTED BELOW THE LOWEST (ING 23)
Protective Gloves:NEOPRENE RUBBER OR NITRILE RUBBER.
Eye Protection:ANSI APPRVD CHEM WORKERS GOGGLES .
Other Protective Equipment:ANSI APPRVD EYE WASH & DELUGE SHOWER . WEAR
PROT CLTHG. NO SPECIFIC PERMEATION/DEGRADATION TESTING HAS (ING 24)
Work Hygienic Practices:CLEAN CONTAMINATED CLOTHING AND SHOES.
Supplemental Safety and Health
EXTING MEDIA:CLASS II COMBUST LIQ FIRES. FIRE FIGHT PROC:
AUTOIGNIT/EXPLO WHEN EXPOS TO EXTREME HEAT. IF WATER USED, FOG
NOZZS PREF. EXPLO HAZ:COMBUST. WETTING CONTAM MATLS & NOT PACKING
THEM TIGHTLY TOGETHER IN REFUSE CNTNRS WILL MINIMIZEPOTNTL FOR
THIS TO OCCUR. KEEP PROD AWAY FROM HEAT, SPKS, FLAME & OTHER (ING
6)

Boiling Pt:B.P. Text:>280F,>138C
Vapor Pres:2.1
Vapor Density:HVR/AIR
Spec Gravity:1.556
Evaporation Rate & Reference:18 (BUOAC=100)
Solubility in Water:0.1%
Appearance and Odor:VISCOUS LIQUID WITH ODOR CHARACTERISTIC OF SOLVENTS
LISTED IN INGRED SECTION.
Percent Volatiles by Volume:44.850

Stability Indicator/Materials to Avoid:YES
AVOID CONTACT WITH STRONG ALKALIES, STRONG MINERAL ACIDS OR STRONG
OXIDIZING AGENTS.
Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER.
Hazardous Decomposition Products:MAY PRDCE THE FOLLOWING HAZ DECOMP
PRODS WHEN EXPOSED TO EXTREME HEAT: CARBON MONOXIDE; CARBON
DIOXIDE; LOWER (ING 9)

Waste Disposal Methods:WASTE MATERIAL MUST BE DISPOSED OF IN ACCORDANCE
WITH FEDERAL, STATE, PROVINCIAL AND LOCAL ENVIRONMENTAL CONTROL
REGULATIONS. EMPTY CONTAINERS SHOULD BE RECYCLED OR DISPOSED OF
THROUGH AN APPROVED WAS TE MANAGEMENT FACILITY.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.