Product ID:225754 ALLYLMAGNESIUM BROMIDE 1.0M SOLUTION IN DIETHYL ETHER
MSDS Date:10/01/1997
FSC:6810
NIIN:00F056841
Status Code:A
MSDS Number: CHZVH

SIGMA CHEMICAL COMPANY

3050 SPRUCE ST
SAINT LOUIS, MO 63178-5000
US

Emergency Phone: 314-771-5765/800-325-3010

Info Phone: 314-771-5765/800-325-3010

Cage: 21076

SIGMA CHEMICAL COMPANY

14508 ST LOUIS, MO 63178 US

Telephone: 314-771-5765

Cage: 21076

ALLYLMAGNESIUM BROMIDE

CAS: 1730-25-1

ETHYL ETHER, DIETHYL ETHER, ETHER, ANESTHETIC ETHER

CAS: 60-29-7

RTECS: KI5775000

OSHA PEL 400 PPM

ACGIH TLV: 400 PPM

EPA Report Quantity: 100 LBS

DOT Report Quantity: 100 LBS

Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:HARMFUL IF SWALLOWED, INHALED/ BY SKIN
ABSORPTION. DESTRUCTIVE TO TISSUE OF MUCOUS MEMBRANES/UPPER
RESPIRATORY TRACT, EYES/SKIN. INHALATION: MAY RESULT IN SPASM,
INFLAMMATION/EDEMA OF THE LARYNX/BRONC HI, CHEMICAL
PNEUMONITIS/PULMONARY EDEMA. CAUSES BURNS. MAY AFFECT THE CNS.
POSSIBLE IRREVERSIBLE EFFECTS. MUTAGEN.
Explanation of Carcinogenicity:NONE
Effects of Overexposure:INFLAMMATION, BURNING SENSATION, COUGHING,
WHEEZING, LARYNGITIS, SHORTNESS OF BREATH, HEADACHE, NAUSEA,
VOMITING

First Aid:EYES/SKIN: IMMEDIATELY FLUSH W/COPIOUS AMOUNTS OF WATER FOR
15 MINS. INHALATION: REMOVE TO FRESH AIR. GIVE CPR/OXYGEN IF
NECESSARY. INGESTION: WASH OUT MOUTH W/WATER IF CONSCIOUS. OBTAIN
MEDICAL ATTEN TION IN ALL CASES.

Flash Point:-40F
Extinguishing Media:DRY CHEMICAL POWDER. DON'T USE WATER.
Fire Fighting Procedures:WEAR A SELF CONTAINED BREATHING APPARATUS &
PROTECTIVE CLOTHING TO PREVENT CONTACT W/SKIN & EYES.
Unusual Fire/Explosion Hazard:VAPOR MAY TRAVEL CONSIDERABLE DISTANCE TO
SOURCE OF IGNITION & FLASHBACK. REACTS W/WATER TO LIBERATE
FLAMMABLE/EXPLOSIVE GAS.

Spill Release Procedures:SHUT OFF ALL IGNITION SOURCES. EVACUATE AREA.
COVER W/DRY-LIME/SAND/SODA ASH. PLACE IN COVERED CONTAINERS USING
NON-SPARKING TOOLS & TRANSPORT OUTDOORS. VENTILATE AREA & WASH SITE
AFTER MATERIAL PICKU P IS COMPLETE.

Handling and Storage Precautions:STORE IN A COOL, DRY PLACE. KEEP AWAY
FROM HEAT/SPARKS & OPEN FLAME. HANDLE & STORE UNDER NITROGEN. KEEP
TIGHTLY CLOSED. WEAR PROTECTIVE CLOTHING.
Other Precautions:DON'T BREATHE VAPOR/GET IN EYES, ON SKIN/ON CLOTHING.
AVOID PROLONGED/REPEATED EXPOSURE. NO SMOKING. OVERPACKED CONTAINER
SHOULD BE OPENED ONLY BY A TECHNICALLY QUALIFIED INDIVIDUAL WHO HAS
READ & UND ERSTOOD THE HANDLING INSTRUCTIONS.

Respiratory Protection:WEAR APPROPRIATE NIOSH/MSHA APPROVED RESPIRATOR.
Ventilation:USE ONLY IN A CHEMICAL FUME HOOD.
Protective Gloves:CHEMICAL-RESISTANT
Eye Protection:SAFETY GOGGLES
Other Protective Equipment:PROTECTIVE CLOTHING, SAFETY SHOWER, EYE BATH
Work Hygienic Practices:REMOVE/LAUNDER CONTAMINATED CLOTHING & SHOES
BEFORE REUSE. WASH THOROUGHLY AFTER HANDLING.
Supplemental Safety and Health

Spec Gravity:0.851
Appearance and Odor:GRAY LIQUID

Stability Indicator/Materials to Avoid:YES
OXIDIZING AGENTS, ALCOHOLS, ACIDS, WATER
Stability Condition to Avoid:HEAT/SPARKS/OPEN FLAMES/IGNITION SOURCES,
MOISTURE, STATIC DISCHARGES
Hazardous Decomposition Products:CO, CO2, HYDROGEN BROMIDE GAS

Waste Disposal Methods:ADD MATERIAL TO DRY BUTANOL. EXOTHERMIC.
NEUTRALIZE SOLUTION W/AQUEOUS ACID. FILTER OFF SOLID RESIDUES FOR
DISPOSAL. BURN LIQUID PORTION IN A CHEMICAL INCINERATOR EQUIPPED
W/AN AFTERBURNER & SCRUBBER. DISPOSE OF IAW/LOCAL, STATE & FEDERAL
REGULATION.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.