Product ID:IRON-CRETE, 4032
MSDS Date:11/14/1991
FSC:8040
NIIN:00N037167
Status Code:A
MSDS Number: CJLBQ

MANTEK DIV OF NCH CORP

IRVING, TX 75015
US

Emergency Phone: 214-438-1381

Info Phone: 972-438-1381; 214-438-1381

Preparer: M. DICKSON

Cage: 64796

NCH CORP / MANTEK DIV

152170 IRVING, TX 75015-2170 US

Telephone: 800-527-9919

Cage: 64796

PART A CONTAINING ING 2

(ORAL, RAT) 11 G/KG.

CAS: 1675-54-3

RTECS: TX3800000

PART B CONTAINING INGREDIENTS 4 - 7.

(ORAL, RAT) 1080 MG/KG

CAS: 111-40-0

RTECS: IE1225000

OSHA PEL 1 PPM

ACGIH TLV: 4.2 MG/M3;1 PPM

(ORAL, RAT) 2500 MG/KG.

CAS: 112-24-3

RTECS: YE6650000

OSHA PEL 10 PPM

ACGIH TLV: 10 PPM

(ORAL, RAT) 3990 MG/KG

CAS: 112-57-2

RTECS: KH8585000

OSHA PEL 10 PPM

ACGIH TLV: 20 PPM

QUARTZ (SIO2); (SILICON DIOXIDE)

CAS: 14808-60-7

RTECS: VV7330000

OSHA PEL see Table Z-3

ACGIH TLV: 0.1 MG/M3

LD50 LC50 Mixture:SEE INGREDIENTS
Routes of Entry: Inhalation:NO Skin:YES Ingestion:NO
Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:NO
Health Hazards Acute and Chronic:ACUTE: MAY CAUSE SEVERE SKIN INJURY
(REDDENING AND SWELLING). MAY CAUSE CHEMICAL BURNS IN THE EYE WITH
IRREVERSIBLE DAMAGE. MAY CAUSE RESPIRATORY IRRITATION. SWALLOWING
CAN CAUSE NAUSEA, DIARRHEA, CRA MPING AND WEAKNESS. CHRONIC:
PROLONGED CONTACT WITH SKIN MAY CAUSE SENSITIZATION AND ALLERGENIC
RESPONSES. PROLONGED BREATHING OF VAPORS CAN LEAD TO SAME EFFECTS
AS INGESTION. INHALATION OF SILICON DI OXIDE CAN CAUSE A
PROGRESSIVE LUNG DISEASE KNOWN AS SILICOSIS. STUDIES INDICATETHAT
PERSONS DIAGNOSED WITH SILICOSIS HAVE AN INCREASED RISK OF LUNG
CANCER. THIS HAZARD WOULD APPLY DURING SANDING. (SUP DAT)
Explanation of Carcinogenicity:SILICA, CRYSTALLINE-QUARTZ: IARC
MONOGRAPHS, VOL 68, 1997:GROUP 1. NTP 8TH ANNUAL REPORT ON
CARCINOGENS, 1998: REASONABLY ANTICIPATED TO BE HUMAN CARCINOGEN
Effects of Overexposure:HLTH HAZS: THE HAZARDS PRESENTED BELOW ARE
THOSE OF THE INDIVIDUAL COMPONENTS. DIGLYCIDYL ETHER OF BISPHENOL
A: IRRITANT. DIETHYLENE TRIAMINE: CORROSIVE. TRIETHYLENE TETRAMINE:
CORROSIVE. TETRA ETHYLE NE PENTAMINE: CORROSIVE. SILICON DIOXIDE:
CARCINOGEN.

First Aid:INHAL: GET PERSON OUT OF CONTAM AREA TO FRESH AIR. IF BRTHG
HAS STOPPED, ARTF RESP SHOULD BE STARTED. OXYG MAY BE ADMIN, IF
READILY AVAIL. SEEK MED ATTN IMMED. EYES: FLUSH W/LG AMTS OF WATER
FOR AT LE AST 15 MIN, LIFTING UPPER & LOWER LIDS OCCASNLY. GET MED
ATTN IF IRRIT PERSISTS. TREATMENT IS MOST EFTIVE W/IN ONE MIN.
SKIN: THOROUGHLY WASH EXPOS AREA W/SOAP & WATER. REMOVE CONTAM
CLTHG. LAUNDER CO NTAM CLTHG BEFORE REUSE. APPLY EMOLLIENT RICH
CREAM. INGEST: DO NOT INDUCE VOMIT. KEEP PERSON WARM, QUIET & GET
MED ATTN. ASPIR OF MATL INTO LUNGS DUE TO VOMIT CAN CAUSE CHEM
PNEUMIT WHICH CAN BE FATA L. (SUPDAT)

Flash Point Method:TCC
Flash Point:>93.3C, 200.F
Extinguishing Media:FOAM, CARBON DIOXIDE, DRY CHEMICAL, WATER SPRAY.
Fire Fighting Procedures:USE NIOSH APPROVED SCBA AND FULL PROTECTIVE
EQUIPMENT TO PROTECT FROM EXPOSURE TO ACRID SMOKE AND HAZARDOUS
DECOMPOSITION PRODUCTS.
Unusual Fire/Explosion Hazard:N/A. NFPA HAZARD RATING (0=INSIGNIFICANT;
1=SLIGHT; 2=MODERATE; 3=HIGH; 4=EXTREME): HEALTH:2; FLAMMABILITY:
1; REACTIVITY: 0.

Spill Release Procedures:ELIMINATE ALL IGNITION SOURCES. USE ABSORBENT
SUCH AS PAPER, VERMICULITE, ETC, TO CONTAIN SPILL. DO NOT FLUSH TO
SEWER. PLACE INTO LABELED CONTAINERS.

Handling and Storage Precautions:STORAGE TEMPERATURE: 120F MAX; 32F
MIN; INDOOR. STORE AT MODERATE TEMPERATURES. AVOID CONTACT WITH
SKIN.
Other Precautions:KEEP OUT OF REACH OF CHILDREN. READ ENTIRE LABEL
BEFORE USING PRODUCT.

Respiratory Protection:TYPICAL USAGE OF PRODUCT DOES NOT REQUIRE THE
USE OF A RESPIRATOR. HOWEVER, IN AN EMERGENCY SITUATION, USE A
NIOSH APPROVED ORGANIC VAPOR OR AIR-LINE RESPIRATOR. USE NIOSH
APPROVED SELF-CONTAINED BREA THING APPARATUS IN CONFINED SPACES.
Ventilation:LOCAL EXHAUST RECOMMENDED TO KEEP AIR CONCENTRATION WELL
BELOW ESTABLISHED TLV.
Protective Gloves:IMPERVIOUS NEOPRENE GLOVES.
Eye Protection:ANSI APPROVED CHEMICAL WORKERS GOGGLES & FULL LENGTH
FACESHIELD .
Other Protective Equipment:ANSI APPROVED EYE WASH AND DELUGE SHOWER .
RUBBER APRON.
Supplemental Safety and Health
FIRST AID PROC: NOTES TO MD: GASTRIC LAVAGE IS INDICATED. DO NOT INDUCE
VOMITING. TOXICOLOGICAL INFO: RESP DISEASE MORTALITY OBSERVED IN
WORKERS EXPOSED TO FIBROUS (NY) TALC & EXCESS NON-MALIGNANT RES P
DISEASE MORTALITY OBSERVED IN THOSE EXPOSED TO NON-FIBROUS
(VERMONT) TALC.

Boiling Pt:=260.C, 500.F
Vapor Pres:<0.01 MM HG
Vapor Density:10 (AIR=1)
Evaporation Rate & Reference:<0.01 (BU AC=1)
Solubility in Water:NEGLIGIBLE
Appearance and Odor:DARK GRAY; NO ODOR.
Percent Volatiles by Volume:<2

Stability Indicator/Materials to Avoid:YES
ACIDS AND OTHER EPOXY RESINS; STRONG OXIDIZERS.
Stability Condition to Avoid:MIXTURE OF PART A & B WILL HARDEN AND
GENERATE HEAT.
Hazardous Decomposition Products:ACRID SMOKE. CARBON MONOXIDE AND
OXIDES OF NITROGEN.
Conditions to Avoid Polymerization:OTHER EPOXY RESINS. REACTION OF OUR
PRODUCT WILL NOT CAUSE ABOVE EFFECT.

Waste Disposal Methods:DISPOSE OF IN ACCORDANCE WITH ALL FEDERAL, STATE
AND LOCAL REGULATIONS.

Toxicological Information:PROD CNTNS CHEM LISTED AS CARCIN OR POTNTL
CARCIN BY: IARC. DIGLYCIDYL ETHER OF BISPHENOL A - SKIN-RBT: 500 MG
OPEN MILD; EYE-RBT: 2 MG/24H SEV; ORL-RAT LD50: 11 G/KG. DIETHYLENE
TRIAMINE - ORL-RAT LD 50: 1080 MG/KG; SKN-RBT 10 MG/24H SEV;SKN-RBT
LD50: 1090 MG/KG. TRIETHYLENE TETRAMINE - ORL-RAT LD50: 2500 MG/KG;
SKN-RBT LD50: 820 MG/KG. MNO-SAT (NMOL/PLATE). TETRAETHYLENE
PENTAMINE - ORL-RAT LD50: 3990 MG/KG; SKN-RBT: 495 MG OPEN SEV.
CRYSTALLINE SILICA - INH-HMN TCLO: 16MPPCF/8H/179Y-I TFX:PUL;
IHL-HMN LCLO: 300 UG/M3 10Y-I; INV-DOG LDLO: 20 MG/KG. IN
EPIDEMIOLOGICAL STUDIES, AN EXCESS IN RES P CANCER & NON-MALIGNANT
(SUPDAT)

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.

SARA Title III Information:NO LISTED INGREDIENTS ARE SUBJECT TO THE
REPORTING REQUIREMENTS OF 313 OF TITLE III OF THE SUPERFUND
AMENDMENTS AND REAUTHORIZATION ACT OF 1986 AND 40 CFR PART 372.
State Regulatory Information:WARNING: THIS PRODUCT CONTAINS THE
FOLLOWING CHEMICAL(S) KNOWN TO THE STATE OF CALIFORNIA TO CAUSE (1)
CANCER OR (2) BIRTH DEFECTS OR OTHER REPRODUCTIVE HARM: SILICA (1).