Product ID:NASHUA XD-41
MSDS Date:07/10/1996
FSC:6850
NIIN:00N091430
Status Code:A
MSDS Number: CJLCH

NASHUA

44 FRANKLIN STREET
NASHUA, NH 03061
US

Emergency Phone: 303-623-5716 (POIS CTR)

Info Phone: 603-880-2323

Cage: 82784

NASHUA

NASHUA, NH 03061 US

Telephone: 603-880-2323

Cage: 82784

PRODUCT CONSISTS OF >95% OF CARRIER AND <5% OF TONER.

IRON; (IRON GRANULES) (CARRIER)

CAS: 7439-89-6

RTECS: NO4565500

OSHA PEL 10 MG/M3

ACRYLATE RESIN (CARRIER)

CAS: 9010-88-2

STYRENE ACRYLATE POLYMER (TONER)

CAS: 25213-39-2

3 MG/M3 (M).

CAS: 1333-86-4

RTECS: FF5800000

OSHA PEL 3.5 MG/M3

ACGIH TLV: 3.5 MG/M3

SILANE, DICHLORODIMETHYL-, REACTION PRODUCTS WITH SILICA;

CAS: 68611-44-9

OSHA PEL 5 MG/M3

ACGIH TLV: 10 MG/M3

ZINC STEARATE (TONER)

CAS: 557-05-1

RTECS: ZH5200000

OSHA PEL 15 MG/M3

ACGIH TLV: 10 MG/M3

Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:YES OSHA:NO
Health Hazards Acute and Chronic:NOTE: PERTAINS TO FINISHED PRODUCT).
EYE CONTACT: MAY CAUSE IRRITATION. SKIN CONTACT: MAY CAUSE
IRRITATION. REPEATED CONTACT MAY CAUSE IRRITATION; MAY CAUSE
ALLERGIC SKIN REACTION. INHALATION: INHALAT ION OF DUST COULD CAUSE
UPPER RESPIRATORY IRRITATION. INGESTION: MAY CAUSE IRRITATION OF
THE MUCOUS MEMBRANES OR DIGESTIVE TRACT.
Explanation of Carcinogenicity:CARBON BLACK: IARC MONOGRAPHS ON
EVALUATION OF CARCINOGENIC RISK OF CHEMICALS TO MAN, VOL 65, PG
149, 1996: GROUP 2B.
Effects of Overexposure:SEE HEALTH HAZARDS.

First Aid:EYES: IMMEDIATELY FLUSH WITH PLENTY OF RUNNING WATER FOR AT
LEAST 15 MINUTES. OBTAIN MEDICAL ATTENTION. SKIN: FLUSH AFFECTED
AREAS PROMPTLY WITH WATER FOR 15 MINUTES. REMOVE CONTAMINATED
CLOTHING. IN CASE OF CONTINUED IRRITATION CONSULT MD. INHALATION:
REMOVE TO FRESH AIR. INGESTION: OBTAIN IMMEDIATE MEDICAL ATTENTION.

Extinguishing Media:WATER SPRAY, DRY CHEMICAL, CARBON DIOXIDE OR FOAM.
Fire Fighting Procedures:USE NIOSH APPROVED SCBA AND FULL PROTECTIVE
EQUIPMENT . CONTAINERS SHOULD BE KEPT COOL WITH WATER SPRAY.
Unusual Fire/Explosion Hazard:COMBUSTIBLE DUST. TONER, LIKE MOST
INORGANIC MATERIALS IN POWDER FORM, WHEN DISPERSED IN AIR CAN FORM
EXPLOSIVE MIXTURES THAT CAN PRODUCE TOXIC FUMES SUCH AS CARBON
MONOXIDE & CO*2. NFPA HAZARD RATING : HEALTH - 1; FLAMMABILITY - 1;
REACTIVITY - 0.

Spill Release Procedures:NOTE: REVIEW FIRST AID MEASURES & EXPOS
CONTROLS/PERSONAL PROT SECTIONS BEFORE PROCEEDING W/CLEAN UP. KEEP
UNNEC PEOPLE AWAY. ISOLATE HAZ AREA & DENY ENTRY. CUT OFF ALL
SOURCES OF IGNIT. SWEEP UP/VACU UM SPILLED TONER & CAREFULLY
TRANSFER INTO SEALABLE WASTE CNTNR, SWEEP SLOWLY TO MIN GENERATION
OF DUST DURING CLEAN-UP. IF VACUUM USED, MOTOR MUST BE RATED AS
DUST TIGHT. CONDUCTIVE HOSE (SUPP DATA)

Handling and Storage Precautions:AVOID EYE & SKIN CONTACT, & STORE IN
WELL-VENTILATED AREA. KEEP CONTAINER TIGHTLY CLOSED & KEEP AWAY
FROM HEAT, SPARKS & OPEN FLAME. DO NOT STORE WITH INCOMPATIBLE
MATERIALS. DO NOT STORE OR CONSUME F OOD, DRINK OR TOBACCO IN AREA
WHERE THEY MAY BECOME CONTAMINATED WITH THIS MATERIAL.
Other Precautions:IN CANADA ALL OUTSIDE CONTAINERS MUST BE LABELED AS A
WHMIS CLASS D2A CONTROLLED SUBSTANCE.

Respiratory Protection:FOR BULK HANDLING: USE NIOSH APPROVED DUST MASK
IF DUST IS PRESENT. BE SURE TO MAINTAIN NORMAL ROOM VENTILATION (10
CHANGES OF AIR PER HOUR).
Ventilation:ROOM VENTILATION IS SUFFICIENT. AVOID USE OF PRODUCT IN
UNVENTILATED AREAS. ALWAYS CONTROL AIRBORNE LEVELS BELOW EXPOSURE
GUIDELINES (USE 50% OF TLV).
Protective Gloves:CHEMICAL RESISTANT GLOVES.
Eye Protection:ANSI APPROVED CHEMICAL WORKERS GOGGLES .
Other Protective Equipment:ANSI APPROVED EYE WASH & DELUGE SHOWER .
OFFICE EQUIP:NO PERSONAL PROT EQUIP IS SUGGESTED. FOR BULK
HNDLG:FOR SKIN PROT USE APRONS. DISPOSABLE COVERALLS ARE OPTIONAL,
& DISCARD AFTER USE.
Supplemental Safety and Health
SPILL PROC:BONDED TO MACHINE SHOULD BE USED TO REDUCE STATIC BUILD-UP.
RESIDUE CAN BE REMOVED W/SOAP & COLD WATER. GARMENTS MAY BE
WASHED/DRY CLEANED, AFTER REMOVAL OF LOOSE TONER.

Spec Gravity:7.0 (H*2O=1)
Solubility in Water:NEGLIGIBLE
Appearance and Odor:BLACK GRANULAR POWDER; SLIGHT ODOR.
Percent Volatiles by Volume:N/A (WT)

Stability Indicator/Materials to Avoid:YES
AVOID STRONG OXIDIZERS.
Stability Condition to Avoid:FLAME OR EXCESSIVE HEAT.
Hazardous Decomposition Products:CO, CARBON MONOXIDE.
Conditions to Avoid Polymerization:WILL NOT OCCUR.

Waste Disposal Methods:ACCORDING TO FEDERAL REGULATION 40 CFR 261, THIS
MATERIAL IS NOT A HAZARDOUS WASTE WHEN DISCARDED. HOWEVER, STATE
AND LOCAL REQUIREMENTS MAY BE MORE RESTRICTIVE. THEREFORE,
CONSULTATION WITH PROPER ST ATE & LOCAL AUTHORITIES IS ADVISED.
INCINERATION IS RECOMMENDED & ONLY IN A CLOSED CONTAINER.

Toxicological Information:CARBON BLACK:IARC ON APRIL 12, 1996 PUBLISHED
"MONOGRAPH VOL 65", WHICH RECLASSIFIES CARBON BLACK FROM CATEGORY 3
TO CATEGORY 2B (KNOWN ANIMAL CARCIN, POSS HUMAN CARCIN). THIS
CHANGE WAS BASED ON RSLT S OF RAT INHAL STUDIES OF CARBON BLACK,
DESPITE LACK OF ANY PARALLEL EVID OF HUMAN/OTHER ANIMAL SPECIES. IN
ADDN, FROM TOX STANDPOINT CARBON BLACK INDUSTRY IS REVIEWING
OPPORTUNITIES TO RESEARCH TO SI GNIFICANTLY INCR THEIR KNOWLEDGE OF
LUNG TUMOR FORM IN RATS & TO DEVELOP CREDIBLE EVID THAT RESPONSE
MECHANISM IN RAT DOES NOT APPLY TO OTHER SPECIES, PARTICULARLY
HUMANS. IN ADDN, THE INDUSTRY MUST S TAY ABREAST OF POTNTL (OTHER
INFO)

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.

Ecological:GENERAL: THIS CHEMICAL FORMULATION HAS NOT BEEN TESTED FOR
ENVIRONMENTAL EFFECTS. ALTHOUGH, IN A SPILL SITUATION THIS
FORMULATION MAY BE AESTHETICALLY UNPLEASANT, IT IS WATER INSOLUBLE
& IS NOT EXPECT ED TO SHOW ANY ADVERSE ENVIRONMENTAL EFFECTS.

Transport Information:DOT, IMO, IATA/ICAO, TRANSPORT CANADA:
NON-REGULATED. IN U.S.: ALL OUTSIDE CONTAINERS MUST BE MARKED
ACCORDING TO OSHA RIGHT-TO-KNOW REGULATIONS 29 CFR 1910.1200 AS
FOLLOWS: CARBON BLACK - DUST INHALA TION; IN CANADA: MUST BE
LABELED UNDER WHMIS AS A D2A CONTROLLED SUBSTANCE. SEE EMERGENCY
RESPONSE GUIDE (DOT) #32.

SARA Title III Information:SARA TITLE III: SUPERFUND AMENDMENTS &
REAUTHORIZATION ACT OF 1986 (SARA TITLE III) REQUIRES SUBMISSION OF
ANNUAL REPORTS OF RELEASE OF TOXIC CHEMICALS THAT APPEAR IN 40 CFR
372 (FOR SARA 313). SARA H AZARD CATEGORIES: IMMEDIATE & DELAYED:
COMPONENTS PRESENT IN THIS PRODUCT AT A LEVEL WHICH COULD REQUIRE
REPORTING UNDER THE STATUTE ARE: NONE.
Federal Regulatory Information:OSHA: HAZARD COMMUNICATION RULE 29 CFR
1910.1200: CARBON BLACK. TSCA: ALL INGREDIENTS IN THIS FINISHED
PRODUCT ARE LISTED ON THE EPA TSCA INVENTORY. CERCLA HAZARDOUS
SUBSTANCE (40 CFR 302): NOT LISTED . INTERNATIONAL REGULATIONS:
CARBON BLACK - 1333-86-4: EINECS - #215--609--9; WHMIS (CANADA) -
UNDER WHMIS CARBON BLACK CLASSIFIED AS A D2A CONTROLLED SUBSTANCE;
CANADIAN DOMESTIC SUBSTANCE LIST.
State Regulatory Information:CARBON BLACK - 1333-86-4: FLORIDA AND
RHODE ISLAND.