Product ID:KOBAN 30WP TURF FUNGICIDE, 85063
MSDS Date:10/12/1994
FSC:6840
NIIN:00N091529
Status Code:A
MSDS Number: CJMCJ

SCOTT CO

14111 SCOOTSLAWN RD
MARYSVILLE, OH 43041
US

Emergency Phone: 800-424-9300

Info Phone: 513-644-0011

Cage: 6K952

SCOTT CO

MARYSVILLE, OH 43041 US

Telephone: 513-644-0011

Cage: 6K952

1,2,4-THIADIAZOLE,

CAS: 2593-15-9

RTECS: XI3875000

NUISANCE DUSTS CONTAINING ING 3

SILICA, CRYSTALLINE-QUARTZ

CAS: 14808-60-7

RTECS: VV7330000

OSHA PEL see Table Z-3

ACGIH TLV: 0.1 MG/M3

LD50 LC50 Mixture:LD50: (ORAL,RAT) 1077 MG/KG
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:NO
Health Hazards Acute and Chronic:ACUTE: ACTIVE INGREDIENTS ARE
MODERATELY TOXIC BY INGESTION AND SKIN CONTACT. EXCESSIVE EXPOSURE
TO ETRIDIAZOL MAY CAUSE LIVER DAMAGE. ABSORPTION THROUGH THE INTACT
SKIN MAY CONTRIBUTE TO EXPOSURE. IN GESTION OF LARGE AMOUNTS OF
PRODUCT MAY CAUSE THROAT IRRITATION, NAUSEA, AND DIARRHEA.
INHALATION OF HIGH DUST LEVELS MAY CAUSE IRRITATION AND COUGHING.
NAUSEA MAY DEVELOP IN SEVERE CASES. PROLONGED O R REPEATED SKIN
CONTACT MAY CAUSE SLIGHT IRRITATION. SLIGHT EYE IRRITANT. RESULTS
OF A LIFETIME FEEDING STUDY INDICATE THAT ETRIDIAZOL IS
CARCINOGENIC TO RATS AT LEVELS OF (EFTS OF OVEREXP)
Explanation of Carcinogenicity:SILICA, CRYSTALLINE-QUARTZ: IARC
MONOGRAPHS, VOLUME 68, PAGE 41, 1997: GROUP 1. NTP 8TH ANNUAL
REPORT ON CARCINOGENS, 1998: REASONABLY ANTICIPATED TO BE HUMAN
CARCINOGEN.
Effects of Overexposure:HLTH HAZS: 640 PPM AND 1280 PPM IN THE DIET. NO
INCREASE IN TUMORS WAS FOUND AT A DOSAGE LEVEL OF 100 PPM.
MUTAGENIC EFFECTS OF ACTIVE INGREDIENT IN BACTERIA ARE REPORTED IN
THE NIOSH REGISTRY OF TOXI C EFFECTS. TARGET ORGANS: SKIN, LIVER,
EYES, RESPIRATORY TRACT, AND GASTROINTESTINAL TRACT.
Medical Cond Aggravated by Exposure:SKIN ABRASIONS AND SORES.

First Aid:EYES: FLUSH WITH WATER FOR AT LEAST 15 MINUTES HOLDING
EYELIDS OPEN. GET MED ATTN IF IRRITATION PERSISTS. INGEST: NEVER
GIVE ANYTHING BY MOUTH TO UNCONSCIOUS OR CONVULSING PERSON. HAVE
CONSCIOUS PERSO N DRINK 1 TO 2 GLASSES OF WATER, THEN INDUCE
REPEATED VOMITING UNTIL VOMIT IS CLEAR. CALL PHYSICIAN. SKIN:
REMOVE CONTAMINATED CLOTHING. WASH WITH SOAP AND WATER. GET MEDICAL
ATTENTION IF IRRITATION D EVELOPS OR PERSISTS. INHAL: REMOVE TO
FRESH AIR. TREAT SYMPTOMATICALLY.

Flash Point:NOT FLAMMABLE
Extinguishing Media:USE MEANS SUITABLE FOR EXTINGUISHING SURROUNDING
FIRE.
Fire Fighting Procedures:EVACUATE AREA. FLOOD WITH WATER. USE NIOSH
APPROVED SCBA AND FULL PROTECTIVE EQUIPMENT .

Spill Release Procedures:VENTILATE AREA. CLEANUP PERSONNEL REQ PROT
CLTHG & NIOSH APPRVD RESP PROT. AVOID DUSTING OR MISTING CONDITIONS
DURING CLEANUP. IF MATERIAL IS UNCONTAMINATED, COLLECT AND REUSE AS
RECOMMENDED FOR PRODU CT. IF CONTAMINATED, PUT IN APPROPRIATE
CONTAINER AND DISPOSE. KEEP SPILLS AWAY FROM DRINKING WATER
SUPPLIES. AFTER CLEANING UP SPILL, FLUSH AREA WITH WATER.

Handling and Storage Precautions:SEE LABEL FOR STORAGE AND DISPOSAL
INSTRUCTIONS. KEEP IN TIGHTLY CLOSED CONTAINER. STORE IN A COOL,
DRY AREA AWAY FROM INCOMPATIBLE MATERIALS & HEAT SOURCES. STORE
AWAY FROM FEED & FOODSTUFFS, AS WELL AS HOUSEHOLD CLEANING
PROUDCTS.
Other Precautions:WASH HANDS WITH SOAP & WATER AFTER HANDLING PRODUCT.
KEEP OUT OF REACH OF CHILDREN. DISPOSE OF CONTAINER IN AN APPROVED
WASTE FACILITY.

Respiratory Protection:USE NIOSH APPROVED PESTICIDE RESPIRATOR PREFIX
TC-21C FOR OUTDOOR EXPOSURES.
Ventilation:NONE REQD FOR ROUTINE OUTDOOR USE. IF PROD IS USED INDOORS,
LOC EXHST SYS WHICH CAPTURES THE (SUPDAT)
Protective Gloves:USE WATERPROOF GLOVES.
Eye Protection:ANSI APPROVED CHEMICAL WORKERS GOGGLES .
Other Protective Equipment:EYEWASH & DELUGE SHWR MTG ANSI DESIGN CRIT .
AVOID SKIN CONT. WEAR COVERALLS OVER SHORT-SLEEVED SHIRT AND SHORT
PANTS, CHEMICAL RESISTANT FOOTWEAR PLUS SO SOCKS & CHEMICAL RESIST
APRON (SUPDAT)
Work Hygienic Practices:WASH HANDS WITH SOAP AND WATER AFTER HANDLING
PRODUCT.
Supplemental Safety and Health
VENT: CONTAMINANT AT ITS SOURCE IS REC TO PVNT DISPERSION INTO WORKROOM
AIR. IF THIS IS NOT FEASIBLE, GEN DILUTION VENT IS REC. OTHER PROT
EQUIP: WHEN CLEANING, MIXING AND LOADING.

Boiling Pt:B.P. Text:DECOMPOSE ON HEATING
Spec Gravity:41 LBS/FT 3 (H*2O =1)
Solubility in Water:50 PPM @ 25C
Appearance and Odor:TAN POWDER, CHARACTERISTIC ODOR.

Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZERS. HYDROLYZES WITH ACIDS AND BASES.
Stability Condition to Avoid:EXTREME HEAT. CONTACT WITH STRONG
OXIDIZERS, ACIDS, AND BASES.
Hazardous Decomposition Products:WHEN HEATED TO DECOMPOSITION IT EMITS
TOXIC CHLORINE AND OXIDES OF SULFUR AND NITROGEN.

Waste Disposal Methods:IF PRODUCT IS NOT CONTAMINATED, COLLECT & REUSE
AS RECOMMENDED FOR PRODUCT. IF PRODUCT IS CONTAMINATED, DISPOSE OF
IN AN APPROVED LANDFILL DISPOSAL FACILITY, IN ACCORDANCE WITH
APPLICABLE FEDERAL, STA TE, AND LOCAL REGULATIONS. DISPOSE OF
CONTAINER IN AN APPROVED WASTE FACILITY.

Toxicological Information:ORAL LD50(RAT): 1077 MG/KG. ORAL
LD50(RABBIT): 779 MG/KG. DERMAL LD50(RABBIT): 1370 MG/KG.
INHALATION LC50(RAT, 1 HR.): >200 MG/L.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.

Ecological:EPA REG. #: 58185-5

Transport Information:DOT CLASSIFICATION: NOT HAZARDOUS. UN REGISTER:
NONE. ENGINEERING CONTROLS: NONE REQUIRED.