Product ID:"EASTMAN" MPK
MSDS Date:06/18/1999
FSC:6810
NIIN:01-459-1987
Status Code:A
MSDS Number: CJNKY

EASTMAN CHEM PRODUCTS A SUB OF EASTMAN KODAK CO

WILCOX DR AND LINCOLN ST
KINGSPORT, TN 37662
US

Emergency Phone: 800-EASTMAN

Info Phone: 615-229-6094/2000

Cage: 74364

TELECHEM INTERNATIONAL, INC

SUNNYVALE, CA 94089-2115 US

Telephone: 916-941-3688

Cage: 1KH20

METHYL PROPYL KETONE

CAS: 107-87-9

RTECS: SA7875000

OSHA PEL 700 MG/M3;200 PPM

ACGIH TLV: 705 MG/M3;200 PPM

METHYL ISOBUTYL KETONE

CAS: 108-10-1

RTECS: SA9275000

OSHA PEL 410 MG/M3;100 PPM

ACGIH TLV: 205 MG/M3;50 PPM

EPA Report Quantity: 5000 LBS

DOT Report Quantity: 5000 LBS

LD50 LC50 Mixture:ORAL RAT LD50: 3.73 GM/KG.
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:EYES: HIGH VAPOR CONCENTRATIONS MAY
CAUSE IRRITATION. SKIN: EXPECTED TO BE A LOW HAZARD FOR USUAL
INDUSTRIAL OR COMMERCIAL HANDLING BY TRAINED PERSONNEL. INHALATION:
HIGH VAPOR CONCENTRATIONS MAY CAUS E DROWSINESS AND IRRITATION.
INGESTION: EXPECTED TO BE A LOW INGESTION HAZARD.
Explanation of Carcinogenicity:NOT LISTED BY NTP, IARC, ACGIH, OSHA.
Effects of Overexposure:EYES: IRRITATION. INHALATION: DROWSINESS,
IRRITATION.

First Aid:EYES: IN CASE OF IRRITATION FROM AIRBORNE EXPOSURE, MOVE TO
FRESH AIR. IF EASY TO DO, REMOVE CONTACT LENSES. GET MEDICAL
ATTENTION IF SYMPTOMS PERSIST. SKIN: WASH WITH SOAP AND WATER. GET
MEDICAL ATTE NTION IF SYMPTOMS OCCUR. INHALATION: MOVE TO FRESH
AIR. TREAT SYMPTOMATICALLY, GET MEDICAL ATTENTION IF SYMPTOMS
PERSIST. INGESTION: GET MEDICAL ATTENTION.

Flash Point Method:TCC
Flash Point:=8.C, 46.4F
Autoignition Temp:=448.9C, 840.F
Lower Limits:1.56
Upper Limits:8.7
Extinguishing Media:WATER SPRAY, DRY CHEMICAL, CARBON DIOXIDE (C02),
ALCOHOL FOAM.
Fire Fighting Procedures:WEAR SELF-CONTAINED BREATHING APPARATUS AND
PROTECTIVE CLOTHING. USE WATER SPRAY TO KEEP FIRE-EXPOSED
CONTAINERS COOL. WATER MAY BE INEFFECTIVE IN FIGHTING THE FIRE.
Unusual Fire/Explosion Hazard:FLAMMABLE. VAPORS MAY CAUSE A FLASH FIRE
OR IGNITE EXPLOSIVELY. VAPORS MAY TRAVEL CONSIDERABLE DISTANCE TO A
SOURCE OF IGNITION AND FLASH BACK. PREVENT BUILDUP OF VAPORS OR
GASES TO EXPLOSIVE CONCENTR ATIONS.

Spill Release Procedures:USE PERSONAL PROTECTIVE EQUIPMENT. ELIMINATE
ALL IGNITION SOURCES. ABSORB SPILL WITH VERMICULITE OR OTHER INERT
MATERIAL. THEN PLACE IN A CONTAINER FOR CHEMICAL WASTE. FOR LARGE
SPILLS: USE WATER SPRA Y TO DISPERSE VAPORS AND DILUTE SPILL TO A
NONFLAMMABLE MIXTURE. PREVENT RUNOFF FROM ENTERING DRAINS, SEWERS,
OR STREAMS.

Handling and Storage Precautions:KEEP CONTAINER CLOSED, IN A
WELL-VENTILATED PLACE AWAY FROM HEAT, SPARKS, AND FLAME. KEEP FROM
CONTACT WITH OXIDIZING MATERIALS. USE ONLY WITH ADEQUATE
VENTILATION. COMPLY WITH ALL NATIONAL, STATE, A ND LOCAL CODES
PERTAINING TO THE STORAGE, HANDLING, DISPENSING, AND DISPOSAL OF
FLAMMABLE LIQUIDS.
Other Precautions:SINCE EMPIED CONTAINERS RETAIN PRODUCT RESIDUE,
FOLLOW LABEL WARNINGS EVEN AFTER CONTAINER IS EMPIED. RESIDUAL
VAORS MAY EXPLODE ON IGNTION: DO NOT CUT, DRILL, GRIND, OR WELD ON
OR NEAR THIS CONTAINER . AVOID BREATHING HIGH VAPOR
CONCENTRATIONS.I

Respiratory Protection:IF ENGINEERING CONTROLS DO NOT MAINTAIN AIRBORNE
CONCENTRATIONS BELOW RECOMMENDED EXPOSURE LIMITS, AN APPROVED
RESPIRATOR MUST BE WORN. RESPIRATOR TYPE: ORGANIC VAPOR. IF
RESPIRATORS ARE USED, A PROGR AM SHOULD BE INSTITUTED TO ASSURE
COMPLIANCE WITH OSHA STANDARD 63 FR 1152, JANUARY 8, 1998.
Ventilation:USE GOOD GENERAL VENTILATION , PROCESS ENCLOSURES, LOCAL
EXHAUST VENTILATION, OR OTHER ENGINEERING CONTROLS TO MAINTAIN
AIRBORNE LEVELS BELOW RECOMMENDED LIMITS
Protective Gloves:IT IS A GOOD INDUSTRIAL HYGIENE PRACTICE TO MINIMIZE
SKIN CONTACT.
Eye Protection:IT IS A GOOD INDUSTRIAL HYGIENE PRACTICE TO MINIMIZE EYE
CONTACT.
Other Protective Equipment:EYE WASH STATION AND WASHING FACILITIES.
Work Hygienic Practices:NONE PROVIDED BY MFR.
Supplemental Safety and Health
NONE PROVIDED BY MFR.

HCC:F2
Boiling Pt:=101.C, 213.8F
Melt/Freeze Pt:=-78.C, -108.4F
Vapor Pres:27.8 MM HG @ 20 DEG C
Vapor Density:2.9 (AIR=1
Spec Gravity:0.81 @ 20 DEG C (WATER=1)
Evaporation Rate & Reference:2.3 (BUAC=1)
Solubility in Water:AT AMBIENT TEMP: MODERATE
Appearance and Odor:LIQUID, COLORLESS, KETONE ODOR.

Stability Indicator/Materials to Avoid:YES
MATERIAL CAN REACT VIOLENTLY WITH STRONG BASES, STRONG OXIDIZING
AGENTS, STRONG REDUCING AGENTS.
Stability Condition to Avoid:NONE PROVIDED BY MFR.
Hazardous Decomposition Products:CARBON DIOXIDE, CARBON MONOXIDE.
Conditions to Avoid Polymerization:WILL NOT OCCUR

Waste Disposal Methods:DISPOSAL MAY BE SUBJECT TO NATIONAL, STATE, OR
LOCAL LAWS. MIX WITH COMPATIBLE CHEMICAL WHICH IS LESS FLAMMABLE
AND INCINERATE. SINCE EMPTIED CONTAINERS RETAIN PRODUCT RESIDUE,
FOLLOW LABEL WARNINGS E VEN AFTER CONTAINER IS EMPTIED. RESIDUAL
VAPORS MAY EXPLODE ON IGNITION: DO NOT CUT, DRILL, GRIND, O R WELD
ON OR NEAR THIS CONTAINER.

Toxicological Information:BASED ON ANIMAL DATA AND STRUCTURE-ACTIVITY
RELATIONSHPS, THIS PRODUCT IS NOT EXPECTED TO CAUSE NERVOUS SYSTEM
DAMAGE.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.

Ecological:DATA FOR THE MAJOR CONPONENT OF THIS MATERIAL HAVE BEEN USED
TO ESTIMATE THE ENVIRONMENTAL IMPACT OF THIS MATERIAL. IT HAS THE
FOLLOWING PROPERTIES: A HIGH BIOCHEMICAL OXYGEN DEMAND AND A
POTENTIAL TO CAUSE OXYGEN DEPLETION IN AQUEOUS SYSTEMS, A LOW
POTENTIAL TO AFFECT AQUATIC ORGANISMS, A HIGH POTENTIAL TO
BIODEGRADE (LOW PERSISTENCE) WITH UNACCLIMATED MICROORGANISMS FROM
ACTIVATED SLUDGE. WHEN DILUTED WITH A LARGE AMOUNT OF WATER. THIS
MATERIAL RELEASED DIRECTLY OR INDIRECTLY INTO THE ENVIRONMENT IS
NOT EXPECTED TO HAVE A SIGNIFICANT IMPACT.

Transport Information:DOT (USA) STATUS: REGULATED, HAZARD CLASS 3, PKG
II. AIR, INTERNATIONAL CIVIL AVIATION ORGANIZATION (ICAC), ICAO
STATUS: REGULATED, HAZARD CLASS 3, PKG II. SEA, INTERNATIONAL
MARITIME DANGEROUS GOODS (IMDG), IMDG STATUS: REGULATED, HAZARDOUS
CLASS 3.2, PKG II.

SARA Title III Information:CHEMICAL(S) SUBJECT TO THE REPORTING
REQUIREMENTS OF SECTION 313 OR TITLE III OF THE SUPERFUND
AMENDMENTS AND REAUTHORIZATION ACT (SARA) OF 1986 AND 40 CFR PART
372: METHYL ISOBUTYL KETONE. SARA (U.S. A.) SECTIONS 311 AND 312
HAZARD CLASSIFICATIONS: FIRE HAZARD,IMMEDIATE (ACUTE) HEALTH
HAZARD.
Federal Regulatory Information:US TOXIC SUBSTANCES CONTROL ACT (TSCA):
ALL COMPONENTS OF THIS PRODUCT ARE LISTED ON THE TSCA INVENTORY.
ANY IMPURITIES PRESENT IN THIS PRODUCT ARE EXEMPT FROM LISTING.
CANADIAN ENVIRONMENTAL PROTECT ION ACT (CEPA) AND DOMESTIC
SUSTANCES LIST (DSL): ALL COMPONENTS OF THIS PRODUCT ARE LISTED ON
TE DSL. ANY IMPURITIES PRESENT IN THIS PRODUCT ARE EXEMPT FROM
LISTING. EUROPEAN INVENTORY OF EXISTING C OMMERCIAL SUBSTANCES
(EINECS): ALL COMPONENTS OF THIS PRODUCT ARE LISTED ON EINECS.
State Regulatory Information:AUSTRALIAN INVENTORY OF CHEMICAL
SUBSTANCES (AICS) AND NATIONAL INDUSTRIAL CHEMICALS NOTIFICATION
AND ASSESSMENT SCHEME (NICAS): ALL COMPONENTS OF THIS PRODUCT ARE
LISTED ON AICS OR OTHERWISE COMPLY W ITH NICNAS. JAPANESE HANDBOOK
OF EXISTING AND NEW CHEMICAL SUBSTANCES: ALL COMPONENTS OF THIS
PRODUCT ARE LISTED IN THE HANDBOOK OR HAVE BEEN APPROCED IN JAPAN
BY NEW SUBSTANCE NOTIFICATION.