Product ID:N-HEPTANE (PURE GRADE), P07400
MSDS Date:04/30/1993
FSC:6810
NIIN:00-470-4631
Status Code:A
MSDS Number: CJNQL

PHILLIPS CHEMICAL COMPANY

613 ADAMS STREET
BARTLESVILLE, OK 74004
US

Emergency Phone: 918-661-8118

Info Phone: 918-661-9091/

Cage: TO311

PHILLIPS CHEMICAL COMPANY

BARTLESVILLE, OK 74004 US

Telephone: 918-661-9091/

Cage: TO311

N-HEPTANE

CAS: 142-82-5

RTECS: MI7700000

OSHA PEL 2000 MG/M3;500 PPM

ACGIH TLV: 1640 MG/M3;400 PPM

DIMETHYLCYCLOPENTANE

CAS: 28729-52-4

ISOOCTANE

CAS: 26635-64-3

METHYLCYCLOHEXANE

CAS: 108-87-2

RTECS: GV6125000

OSHA PEL 2000 MG/M3;500 PPM

ACGIH TLV: 1610 MG/M3;400 PPM

OTHER COMPONENTS

Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Health Hazards Acute and Chronic:TARGET ORGAN TOXIN: LUNG ASPIRATION
HAZARD. ACUTE: EYE-MAY CAUSE MILD IRRITATION. SKIN-MAY CAUSE
BURNING & ITCHING,ESPECIALLY AFTER PROLONGED & DIRECT CONTACT WITH
LIQUID. INHALATION-RESPIRATORY ARRE
ST,CONVULSION,SEMI-CONSCIOUSNESS OR UNCONSCIOUSNESS MAY RESULT FROM
EXTREME EXPOSURE. INGESTION-MAY CAUSE WEAKNESS & GASTROINTESTINAL
TRACT IRRITATION. IF SWALLOWED,MAY BE ASPIRATED RESULTING ININFLAM
MATION &POSSIBLE FLUID ACCUMULATION INTHE LUNGS.
Effects of Overexposure:INHALATION-MAY CAUSE IRRITATION TO THE MUCOUS
MEMBRANES OF THE RESPIRATORY TRACT, NAUSEA, LOSS OF
APPETITE,LASSITUDE, LIGHT-HEADEDNESS, GIDDINESS,DIZZINESS &
INCOORDINATION.

First Aid:EYE-FLUSH EYES WITH RUNNING WATER FOR AT LEAST 15MIN. IF
IRRITATION OR ADVERSE SYMPTOMS DEVELOP, SEEK MEDICALAID. SKIN-WASH
SKIN WITH SOAP & WATER FOR AT LEAST 15 MIN. IF IRRITATION OR
ADVERSE SYMPTO MS DEVELOP, SEEK MEDICAL AID. INHALATION-REMOVE FROM
EXPOSURE. IFBREATHING IS DIFFICULT, GIVE OXYGEN.IF BREATHING
CEASES, ADMINISTER ARTIFICIAL RESPIRATION FOLLOWED BY OXYGEN. SEEK
IMMEDIATE MEDICAL A ID. INGESTION-DO NOT INDUCE VOMITING.
SEEKIMMEDIATE MEDICAL AID. NOTE TOPHYSICIAN: GASTRIC LAVAGE USING A
CUFFED ENDOTRACHEAL TUBE MAY BE PERFORMED AT YOUR DISCRETION.

Flash Point Method:TCC
Flash Point:=-3.9C, 25.F
ASTM D56
Lower Limits:1.0
Upper Limits:7.0
Extinguishing Media:DRY CHEMICAL, FOAM OR CARBON DIOXIDE (CO2)
Fire Fighting Procedures:EVACUATE AREA OF ALL UNNECESSARY PERSONNEL.
SHUT OFF SOURCE, IF POSSIBLE. USE SELF-CONTAINED BREATHING
APPARATUS AND OTHER PROTECTIVE EQUIPMENT AND/OR GARMENTS DESCRIBED
IN SECTION C IF CONDITIONS W ARRANT. WATER FOG OR SPRAY MAY BE
USED TO COOL EXPOSED CONTAINERS AND EQUIPMENT.
Unusual Fire/Explosion Hazard:DO NOT SPRAY WATER DIRECTLY ON
FIRE-PRODUCT WILL FLOAT AND COULD BE REIGNITED ON SURFACE OF WATER.
CARBON OXIDES FORMED WHEN BURNED. HIGHLY FLAMMABLE VAPORS WHICH
ARE HEAVIER THAN AIR MAY ACCUMULATE IN LOW AREAS AND/OR SPREAD
ALONG GROUND AWAY FROM HANDLING SITE.

Spill Release Procedures:EVACUATE AREA OF ALL UNNECESSARY PERSONNEL.
WEAR PROTECTIVE EQUIPMENT &/OR GARMETS IF EXPOSURE CONDITIONS
WARRANT. SHUT OFF SOURCE, IF POSSIBLE & CONTAIN SPILL. PROTECT FROM
IGNITION. KEEP OUT OF WATE R SOURCES & SEWERS. ABSORB IN DRY,INERT
MATERIAL.TRANSFER TO DISPOSAL DRUMS USING NON-SPARKING EQUIPMENT.

Handling and Storage Precautions:STORE IN TIGHTLY CLOSED CONTAINER.
STORE IN A WELL-VENTILATED AREA. KEEP AWAY FROM HEAT, SPARKS, AND
FLAMES. BOND & GROUND DURING TRANSFER. HEPTANE WILL ATTACK SOME
FORMS OF PLASTIC & RUBBER.
Other Precautions:AVOID CONTACT WITH EYES, SKIN OR CLOTHING. AVOID
BREATHING VAPORS, MIST, FUME OR DUST. DO NOT SWALLOW. MAY BE
ASPIRATED INTO LUNGS. WEAR PROTECTIVE EQUIPMENT &/OR GARMETS IF
CONDITIONS WARRANT. USE WI TH ADEQUATE VENTILATION.

Respiratory Protection:NOT GENERALLY REQUIRED UNLESS NEEDED TO PREVENT
RESPIRATORY IRRITATION. IF EXPOSURE TO CONCENTRATIONS ABOVE THE
RECOMMENDED EXPOSURE LIMIT IS POSSIBLE, USE NIOSH/MSHA APPROVED
SELF-CONTAINED BREATHIN G APPARATUS (SCBA).
Ventilation:USE ADEQUATE VENTILATION TO CONTROL CONCENTRATION BELOW
RECOMMENDED EXPOSURE LIMITS.
Protective Gloves:USE GLOVES RESISTANT TO THE MATERIAL BEING USED
(BUNA-N OR POLYVINYL ALCOHOL).
Eye Protection:USE SAFETY GLASSES WITH SIDE SHIELDS.
Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING. LAUNDER
CONTAMINATED CLOTHING BEFORE REUSE.
Supplemental Safety and Health
FOR SPLASH PROTECTION, USE CHEMICAL GOGGLES AND FACE SHIELD. NOTE:
PERSONAL PROTECTION INFORMATION SHOWN IS BASED UPON GENERAL
INFORMATION AS TO NORMAL USES & CONDITIONS. WHERE SPECIAL OR
UNUSUAL USES OR CONDITIONS EXIST, IT IS SUGGESTED THAT THE EXPERT
ASSISTANCE OF AN INDUSTRIAL HYGIENIST BE SOUGHT.

HCC:F2
Boiling Pt:=98.3C, 209.F
Vapor Pres:1.6 PSIA AT 100F
Vapor Density:3.4
Spec Gravity:0.688 AT 60/60F
Evaporation Rate & Reference:(BUTYL ACETATE=1) >1
Solubility in Water:NEGLIGIBLE
Appearance and Odor:CLEAR LIQUID.MILDSWEETODOR.

Stability Indicator/Materials to Avoid:YES
OXYGEN AND STRONG OXIDIZING AGENTS
Hazardous Decomposition Products:CARBON OXIDES FORMED WHEN BURNED.
Conditions to Avoid Polymerization:WILLNOT OCCUR.

Waste Disposal Methods:INSURE CONFORMITY WITH ALL APPLICABLE DISPOSAL
REGULATIONS; INCINERATE OR PLACE IN PERMITTED WASTE MANAGEMENT
FACILITY.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.

Transport Information:SHIPPING NAME:HEPTANES. HAZARD CLASS: 3
(FLAMMABLELIQUID). ID#: UN1206. PACKING GROUP: II. MARKINGS:
HEPTANES,UN1206. LABEL: FLAMMABLE LIQUID. PLACARD: FLAMMABLE/1206.
SHIPPING DESCRIPTION: HEPTANES,3 (FLAMMABLE LIQUID), UN 1206,PG
II. PACKAGING REFERENCES: 49 CFR 173.150, 173.202,173.242.

SARA Title III Information:ASOF THE PREPARATIONDATE,THISPRODUCT DID NOT
CONTAIN A CHEMICAL OR CHEMICALS SUBJECT TO THE REPORTING
REQUIREMENTS OF SECTION 313 OF TITLE III OF THE SUPERFUND
AMENDMENTS AND REAUTHORIZATION ACTOF 198 6 AND 40 CFRPART 372.
Federal Regulatory Information:PRODUCT AND/OR COMPONENTS ENTERED ON
EPA'S TSCA INVENTORY: YES. THIS PRODUCT IS IN U.S. COMMERCE, AND IS
LISTED IN THE TOXIC SUBSTANCE CONTROL ACT (TSCA) INVENTORY OF
CHEMICALS; HENSE, IT MAY BE SUBJ ECT TO APPLICABLE TSCA PROVISIONS
AND RESTRICTIONS.