Product ID:STANNOUS CHLORIDE SOLUTION, 4050-0105
MSDS Date:03/12/1997
FSC:6810
NIIN:00N092001
Status Code:A
MSDS Number: CJPWK

BACHARACH INC

625 ALPHA DRIVE
PITTSBURGH, PA 15238
US

Emergency Phone: 800-424-9300

Info Phone: 412-963-2223

Cage: 05083

BACHARACH INC

PITTSBURGH, PA 15238 US

Telephone: 412-963-2130

Cage: 05083

STANNOUS CHLORIDE DIHYDRATE; (STANNOUS CHLORIDE) . LD50

CAS: 10025-69-1

RTECS: XP8850000

OSHA PEL 2 MG/M3

ACGIH TLV: 2 MG/M3

(ORAL,RAT) 2140 MG/KG

CAS: 7664-93-9

RTECS: WS5600000

OSHA PEL 1 MG/M3

ACGIH TLV: 1 MG/M3

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

WATER

CAS: 7732-18-5

RTECS: ZC0110000

LD50 LC50 Mixture:SEE INGREDIENTS 1 & 2
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:YES OSHA:NO
Health Hazards Acute and Chronic:ACUTE: EYE CONT: MAY CAUSE SEVERE
BURNS WITH CORNEAL ULCERATION AND POSSIBLE BLINDNESS. SKIN CONT:
MAY CAUSE SEVERE BURNS. INHALATION: MAY CAUSE IRRITATION OF THE
NOSE, THROAT & RESPIRATORY TRACT. HIG H CONCENTRATIONS MAY PRODUCE
BLOODY NASAL SECRETIONS AND PULMONARY EDEMA. INGESTION: MAY CAUSE
BURNS TO THE GASTROINTESTINAL TRACT, METALLIC TASTE, NAUSEA,
VOMITING, DIARRHEA, ANEMIA, LIVER DAMAGE. CH RONIC: REPEATED
EXPOSURE TO THE MIST MAY CAUSE INFLAMMATION OF THE UPPER
RESPIRATORY TRACT, CHRONIC BRONCHITIS AND ETCHING OF DENTAL ENAMEL.
PROLONGED OVEREXP TO STANNUOUS CHLORIDE HAS (EFTS OF OVEREX P)
Explanation of Carcinogenicity:SULFURIC ACID: IARC MONOGRAPHS ON THE
EVALUATION OF CARCINOGENIC RISK OF CHEMICALS TO MAN, VOL 54, PG 41,
1992: GROUP 1. ANIMAL: PULMONARY IRRIT.
Effects of Overexposure:HLTH HAZS: BEEN FOUND TO CAUSE LIVER CHANGES,
TESTICULAR DEGENERATION, PANCREATIC ATROPHY AND GASTROINTESTINAL
IRRITATION IN LABORATORY ANIMALS.
Medical Cond Aggravated by Exposure:INDIVIDUALS WITH PRE-EXISTING SKIN
AND RESPIRATORY DISORDERS MAY BE AT INCREASED RISK FROM EXPOSURE.

First Aid:EYE CONT: FLUSH THOROUGHLY W/COPIOUS AMOUNTS OF RUNNING WATER
FOR 20 MINUTES, LIFTING LIDS OCCASIONALLY. GET IMMEDIATE ATTENTION.
SKIN CONT: FLUSH THOROUGHLY W/WATER FOR 20 MINUTES. REMOVE
CONTAMINATE D CLOTHING & LAUNDER BEFORE RE-USE. GET MED ATTN.
INHAL: REMOVE TO FRESH AIR & GIVE ARTF RESP IF NEEDED. GET IMMED
MED ATTN. INGEST: NEVER GIVE ANYTHING BY MOUTH TO UNCONSCIOUS OR
CONVULSING PERSON. I MMED GIVE VICTIM 1-2 GLASSES OF WATER OR MILK
TO DRINK. DO NOT INDUCE VOMITING. GET IMMED MED ATTN.

Extinguishing Media:THIS MATERIAL IS NOT COMBUSTIBLE. USE ANY MEDIA
THAT IS APPROPRIATE FOR THE SURROUNDING FIRE.
Fire Fighting Procedures:USE NIOSH APPROVED SCBA AND FULL PROTECTIVE
EQUIPMENT . USE WATER TO KEEP EXPOSED CONTAINERS COOL.
Unusual Fire/Explosion Hazard:NONE KNOWN. HAZARDOUS COMBUSTION
PRODUCTS: HYDROGEN CHLORIDE, TIN OXIDE, SULFURIC ACID, OXIDES OF
SULFUR.

Spill Release Procedures:WEAR SUITABLE PROTECTIVE EQUIPMENT. DIKE AND
CONTAIN WITH INERT ABSORBENT. CAREFULLY NEUTRALIZE WITH SODA ASH &
ABSORB. PLACE IN SUITABLE CONTAINER. WASH RESIDUE WITH WATER.
Neutralizing Agent:NEUTRALIZE WITH SODA ASH.

Handling and Storage Precautions:STORE IN A COOL, WELL VENTILATED AREA,
AWAY FROM ALKALIS, OXIDIZERS AND OTHER INCOMPATIBLE MATERIALS. KEEP
CONTAINER TIGHTLY CLOSED. CORROSIVE. EMTPY CONTAINERS RETAIN
RESIDUES AND MAY BE HAZARDOUS-FO LLOW ALL PRECAUTIONS WHEN
HANDLING.
Other Precautions:WORK PRACTICES: PREVENT CONTACT WITH THE EYES, SKIN &
CLOTHING. WEAR RECOMMENDED PROTECTIVE CLOTHING. WASH THOROUGHLY
AFTER HANDLING. DO NOT EAT, DRINK OR SMOKE IN THE WORK AREA. KEEP
CONTAINERS TIGHT LY CLOSED WHEN NOT IN USE.

Respiratory Protection:IF THE CONCENTRATION EXCEEDS EXPOSURE LIMITS USE
AN NIOSH APPRVD DUST/MIST/ACID GAS RESPIRATOR. AT CONCENTRATIONS
ABOVE 10 TIMES THE TLV AN NIOSH APPRVD SUPPLIED AIR OR
SELF-CONTAINED RESPIRATOR MAY B E REQUIRED.
Ventilation:USE GENERAL OR LOCAL EXHAUST VENTILATION AS NEEDED TO
MAINTAIN CONCENTRATION BELOW THE PEL.
Protective Gloves:IMPERVIOUS SUCH AS RUBBER OR NEORPENE GLOVES.
Eye Protection:ANSI APPRVD CHEM WORKERS GOGGLES & FULL LENGTH
FACESHIELD .
Other Protective Equipment:EYE WASH & DELUGE SHOWER MEETING ANSI DESIGN
CRITERIA . PROTECTIVE APRON OR COVERALLS.
Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING. DO NOT EAT,
DRINK OR SMOKE IN THE WORK AREA. DO NOT WEAR CONTACT LENSES.
Supplemental Safety and Health
FEDERAL REGULATORY: OTHER CHRONIC EFFECTS); CLASS E (CORROSIVE
MATERIAL). EUROPEAN COMMUNITY LABELING CLASSIFICATION: HARMFUL
(XI). EUROPEAN COMMUNITY RISK AND SAFETY PHRASES: R34,
S24/25,S26,S36/37/3 9,S45.

Boiling Pt:B.P. Text:NOT AVAILABLE
Melt/Freeze Pt:M.P/F.P Text:NOT AVAILABLE
Vapor Pres:14 MM HG @ 20C (WATER)
Vapor Density:0.7(WATER)
pH:<1
Solubility in Water:COMPLETE
Appearance and Odor:SLIGHTLY CLOUDY LIQUID, ODORLESS.
Percent Volatiles by Volume:87

Stability Indicator/Materials to Avoid:YES
ALKALIS, OXIDIZERS, BROMINE TRIFLUORIDE, CALCIUM ACETYLIDE, CHLORINE,
ETHYLENE OXIDE, HYDRAZINE HYDRATE, METAL NITRATES, POTASSIUM,
SODIUM, TURPENTINE.
Stability Condition to Avoid:AVOID HEATING MATERIAL TO BOILING.
Hazardous Decomposition Products:HYDROGEN CHLORIDE, TIN OXIDE, SULFURIC
ACID, OXIDES OF SULFUR.

Waste Disposal Methods:DISPOSE IN ACCORDANCE WITH ALL LOCAL, STATE AND
FEDERAL REGULATIONS. RCRA HAZARDOUS WASTE CODES: D002.

Toxicological Information:ACUTE TOXICITY DATA: LD50 STANNOUS CHLORIDE:
700 MG/KG ORAL RAT;LD50 FOR SULFURIC ACID: 2140 MG/KG ORAL RAT.
IRRITANCY DATA: MATL IS CORR TO ALL TISS. SENSIT: NONE OF
COMPONENTS HAVE BEEN RPTD TO CAUS E SENSIT IN ANIMALS/ HUMANS.
REPRO TOX:NONE OF COMPONENTS HAVE BEEN RPTD TO CAUSE REPRO TOX IN
LAB ANIMALS/HUMANS. TERATOGENICITY: NONE OF COMPONENTS HAVE BEEN
RPTD TO CAUSE TERATOGENIC EFTS IN LAB AN IMALS/HUMANS.
MUTAGENICITY: STANNOUS CHLORIDE HAS BEEN FOUND TO BE MUTAGENIC IN
SOME TEST SYS. SYNERGISTIC EFTS: THERE ARE NO CHEMS KNOWN TO CAUSE
ANY ADDITIVE ADVERSE HLTH EFTS.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.

Ecological:THE ECOLOGICAL EFFECTS OF THIS PRODUCT HAVE NOT BEEN
EVALUATED.

Transport Information:US DOT SHIPPING NAME: SULFURIC ACID MIXTURE,
(SULFURIC ACID 5%), 8, UN 1830, PG II. DOT LABELS REQUIRED:
CORROSIVE. EMERGENCY RESPONSE GUIDE NUMBER: 137. IATA SHIPPING
NAME: SULPHURIC ACID MIXTURE, 8, UN 1830, PG II. IATA LABELS
REQUIRED: CORROSIVE (CARGO AIRCRAFT 1-30 LITERS).

SARA Title III Information:SARA 311/312: HAZARD CATEGORIES FOR SARA
SECTION 311/312 REPORTING: ACUTE HEALTH, CHRONIC HEALTH. SARA 313:
THIS PRODUCT CONTAINS FOLLOWING CHEMICALS SUBJECT TO ANNUAL RELEASE
REPORTING REQUIREMENTS U NDER SARA SECTION 313 (40 CFR 372):
SULFURIC ACID 5%.
Federal Regulatory Information:CERCLA SECTION 103 REPORTABLE QTY:
20,000 LBS(SULFURIC ACID - 1000 LBS). US TOXIC SUBSTANCES CTL ACT:
ALL COMPONENTS OF PROD ARE LISTED ON EPA TSCA INVENTORY. EUROPEAN
INVENTORY OF COMMERCIAL CHEM SUB STANCES: ALL OF COMPONENTS OF
PROD ARELISTED ON EINECS INVENTORY. JAPAN MITT: ALL COMPONENTS OF
PROD ARE EXISTING CHEM SUBSTANCES AS DEFINED IN CHEM SUBSTANCE CTL
LAW. CANADIAN ENVIR PROT ACT: ALL OF COMPONENTS OF PROD ARE LISTED
ON CANADIAN DOMESTIC SUBSTANCES LIST. CANADIAN WHMIS
CLASSIFICATION: CLASS D-DIVISION 2B(TOX MATL CAUSING (SUPDAT)
State Regulatory Information:CALIFORNIA PROPOSITION 65: THIS PRODUCT
CONTAINS THE FOLLOWING SUBSTANCES KNOWN TO THE STATE OF CALIFORNIA
TO CAUSE CANCER AND/OR REPRODUCTIVE HARM: NONE.