Product ID:DABCO T-12 CATALYST, T12
MSDS Date:06/01/1998
FSC:8010
NIIN:00N086444
Status Code:A
MSDS Number: CJPWZ

Emergency Phone: 800-523-9374

Info Phone: 800-345-3148

Cage: 00742

Telephone: 800-345-3148/ 800-752-1597

Cage: 00742

DIPROPYLENE GLYCOL

CAS: 25265-71-8

RTECS: UB8765000

TRIETHYLENEDIAMINE

CAS: 280-57-9

RTECS: HM0354200

LD50 LC50 Mixture:LD50: (ORAL,RAT) 3200 MG/KG
Routes of Entry: Inhalation:NO Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:EXPOS STDS: NO STDS ESTABLISHED FOR
PROD. MAINTAIN AIR CONTAMINANT CONCS IN WORKPLACE @ LOWEST FEASIBLE
LEVELS. HLTH HAZS: SEV EYE IRRITANT. MOD SKIN IRRITANT. MILD RESP
TRACT IRRITANT. ACUTE: PROD VA P IN LOW CONCS CAN CAUSE
LACRIMATION, CONJ & CORNEAL EDEMA WHEN ABSORBED INTO TISS OF EYE
FROM ATM. CORNEAL EDEMA MAY GIVE RISE TO PERCEPTION OF "BLUE HAZE"
OR "FOG" AROUND LIGHTS. THE EFT IS TRANSIEN T & HAS NO KNOWN
RESIDUAL EFT. CONT W/EYES CAUSES SEV IRRIT & PAIN. CONT W/SKIN MAY
CAUSE DRYNESS (DEFAT), ITCHING AND/OR RASH. CONT W/SKIN CAUSES
IRRIT, REDNESS & DISCOMFORT WHICH IS TRANSIENT. (EFTS OF OVEREXP)
Explanation of Carcinogenicity:THIS PRODUCT CONTAINS NO CARCINOGENS IN
CONCENTRATIONS OF 0.1 PERCENT OR GREATER.
Effects of Overexposure:HLTH HAZS: INHAL OF MISTS MAY CAUSE IRRIT IN
RESP TRACT. INHAL OF VAPS MAY CAUSE IRRIT IN RESP TRACT. COUGH &
CHEST PAIN MAY RSLT. RISK OF EXPOS TO HAZ CONCS OF VAP UNDER NORMAL
WORKING CNDTNS IN WELL VENTILATED SPACE IS MINIMAL. HOWEVER,CNDTNS
SUCH AS SPRAYING/SUDDEN RELEASE OF HOT LIQ, WHICH GENERATE AEROSOL,
MISTS/FOG SHOULD BE AVOIDED. PROD IS ABSORBED THRU SKIN & MAY CAUSE
NAUS, HDCH & GEN DI SCOMFORT. SIGNS & SYMPS OF EXPOS (POSS LONGER
TERM EFTS): RPTD AND/OR PRLNGD EXPOS MAY RSLT IN: KIDNEY DISORDERS
(SUCH AS EDEMA/PROTEINURIA), ADVERSE EYE EFTS (SUPDAT)
Medical Cond Aggravated by Exposure:EYE DISEASE. KIDNEY DISORDERS. SKIN
DISORDERS AND ALLERGIES.

First Aid:EYE CONT: HOLD EYELIDS APART & IMMED FLUSH W/PLENTY OF WATER
FOR AT LST 15 MINS. SEEK MED ADVICE. SKIN CONT: REMOVE PROD & IMMED
FLUSH AREA W/WATER FOR AT LST 15 MINS. REMOVE CONTAMD CLTHG &
SHOES. DE STROY CONTAMD LEATHER APPAREL. SEEK MED ADVICE. LAUNDER
CONTAMD CLTHG PRIOR TO REUSE. INHAL: MOVE TO FRESH AIR. IF BRTHG
HAS STOPPED/IS LABORED GIVE ASSISTED RESP (E.G. MOUTH-TO-MOUTH).
PVNT ASPIR OF VOMIT. TURN VICTIM'S HEAD TO SIDE. SEEK MED ADVICE.
INGEST: CALL PHYS IMMED. REMOVE STOMACH CONTENTS BY GASTRIC
SUCTION/INDUCE VOMIT ONLY AS DIRECTED BY MED PERSONNEL. (SUPDAT)

Flash Point Method:CC
Flash Point:>110.C, 230.F
Extinguishing Media:FIRE HAZARD CLASSIFICATION (OSHA/NFPA) CLASS IIIB.
IGNITION WILL GIVE RISE TO CLASS B FIRE. IN CASE OF FIRE USE: WATER
STREAMS.
Fire Fighting Procedures:USE NIOSH APPROVED SCBA AND FULL PROTECTIVE
EQUIPMENT . FIREFIGHTERS SHOULD WEAR BUTYL RUBBER BOOTS, GLOVES,
AND BODY SUIT.
Unusual Fire/Explosion Hazard:MAY GENERATE TOXIC/IRRITATING COMBUST
PRODS. SUDDEN RXN & FIRE MAY RSLT IF PROD IS MIXED W/AN OXIDIZING
AGENT. MAY GENERATE CARBON MONOXIDE GAS. MAY GENERATE TOXIC
NITROGEN OXIDE GASES. MAY GENERATE A MMONIA GAS. PERSONNEL IN
VICINITY AND DOWNWIND SHOULD BE EVALUATED.

Spill Release Procedures:CONTAINMENT TECHNIQUES (REMOVAL OF IGNIT
SOURCES, DIKING ETC): SHUT OFF/REMOVE ALL IGNIT SOURCES. STOP LEAK,
IF POSS. REDUCE VAP SPREADING W/WATER SPRAY. CONSTRUCT DIKE TO PVNT
SPREADING (INCL MOLTEN LIQS UNTIL THEY FREEZE). CLEAN-UP PROC: IF
RECOVERY IS NOT FEASIBLE, ADMIX W/DRY SOIL, SAND/NON-REACTIVE
ABSORB & PLACE IN APPROP CHEM WASTE CNTNR. TRANSFER TO CNTNRS BY
SUCTION, (OTHER INFO)

Handling and Storage Precautions:KEEP AWAY FROM: ACIDS, OXIDIZERS. KEEP
IN COOL, DRY, VENTILATED STORAGE & IN CLSD CNTNRS. STORE IN STEEL
CNTNRS PREF LOCATED OUTDOORS, ABOVE GROUND, & SURROUNDED BY DIKES
TO CNTN SPILLS/LEAKS. DO NOT STORE IN REACTIVE METAL CNTNRS. AVOID
CONT W/SKIN OR EYES. AVOID BRTHG VAPS.
Other Precautions:HNDL IN WELL VENTILATED WORK SPACE. WHEN HNDLG, DO
NOT EAT, DRINK/SMOKE. OTHER PREC: EMER SHOWERS & EYE WASH STATIONS
SHOULD BE READILY ACCESSIBLE. ADHERE TO WORK PRACTICE FULES
ESTABLISHED BY GOVERNM ENT REGS (E.G. OSHA).

Respiratory Protection:NOT REQUIRED UNDER NORMAL CONDITIONS IN A
WELL-VENTILATED WORKPLACE. NIOSH APPROVED RESPIRATOR APPROPRIATE
FOR EXPOSURE OF CONCERN .
Ventilation:NO SPECIFIC CONTROLS NEEDED.
Protective Gloves:NEOPRENE RUBB, IMPERMEABLE, CUFFED BUTYL RUBB, OR
NITRILE RUBB GLOVES.
Eye Protection:ANSI APPROVED CHEMICAL WORKERS GOGGLES .
Other Protective Equipment:ANSI APPROVED EYE WASH & DELUGE SHOWER .
LONG SLEEVED CLOTHING.
Work Hygienic Practices:WASH AT END OF EACH WORKSHIFT & BEFORE EATING,
SMKNG/USING TOILET. USE APPROP HAND & SKIN LOTIONS TO PROTECT SKIN.
DISCARD CONTAMD LEATHER ARTICLES.
Supplemental Safety and Health
EFTS OF OVEREXP: (SUCH AS CONJ/CORNEAL DMG), ADVERSE SKIN EFTS (SUCH AS
DEFAT, RASH/IRRIT), ADVERSE SKIN EFTS (SUCH AS RASH, IRRIT/CORR).
DRYNESS OF NASAL PASSAGES MAY BE EXPERIENCED WHEN MATL IS INHA LED
OVER LONG PERIOD OF TIME. TARGET ORGANS: EYE, SKIN, KIDNEY. FIRST
AID: NEVER GIVE ANYTHING BY MOUTH TO UNCON PERSON.

Boiling Pt:>149.C, 300.2F
Vapor Pres:2 @ 21C
Vapor Density:2 (AIR =1)
Spec Gravity:1.13 (WATER =1)
pH:9.00
Solubility in Water:COMPLETELY (100%)
Appearance and Odor:COLORLESS MOBILE LIQUID, AMMONIACAL ODOR.

Stability Indicator/Materials to Avoid:YES
MINERAL ACIDS (I.E. SULFURIC, PHOSPHORIC, ETC). ORG ACIDS (I.E. ACETIC
ACID, CITRIC ACID ETC). OXIDIZING AGENTS (I.E. PERCHLORATES,
NITRATES ETC). REACTIVE METALS (I.E. SODIUM, CALCIUM, ZINC ETC).
SODIUM, CALCIUM ZINC ETC).
Hazardous Decomposition Products:(FROM BURNING, HEATING/RXN W/OTHER
MATLS): CO IN FIRE. CO*2 IN FIRE. AMMONIA WHEN HEATED. NITROGEN
OXIDES IN FIRE. IRRITATING & TOXIC FUMES @ ELEVATED TEMPS. NITRIC
ACID IN FIRE. (ECOLOGICAL INFO)

Waste Disposal Methods:COMPLY WITH ALL FEDERAL, STATE AND LOCAL
REGULATIONS.

Toxicological Information:ACUTE ORAL TOX (LD50,RAT) 3200.00 MG/KG.
ACUTE DERMAL TOX (LD50,RABBIT) >2000 MG/KG (NO DEATHS). ACUTE INHAL
TOX (LC50, RAT) >8.10 MG/L/1 HR. AMES TEST: NEG (ACTIVATED &
NONACTIVATED) INDUST CHEMS SUC H AS THIS MATL W/ACUTE TOX VALUES
SHOWN & WHOSE VAPS/MISTS ARE NOT LIKELY TO BE ENCOUNTERED BY HUMANS
WHEN USED IN ANY REASONABLY FORESEEABLE MANNER WOULD NOT REQ TOXIC
LBL ACCORD TO U.S. DOMESTIC & I NTERNATIONAL TRANSPORT REQS. IRRIT
EFTS DAT: SEV IRRITANT TO EYES OF RABBIT. MOD IRRITANT TO SKIN OF
RABBIT. CHRONIC/SUBCHRONIC DATA: RPTS IN (ECOLOGICAL INFO)

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.

Ecological:NO DATA. OTHER INFO: MIXED W/ACIDS. HEAT GENERATED MAY BE
SUFFICIENT TO CAUSE VIGOROUS BOILING CREATING HAZARD DUE TO
SPLASHING/SPLATTERING OF HOT MATL. HAZ DECOMP PRODS: ALDEHYDES.
NITROGEN OXIDE CAN REACT W/WATER VAPORS TO FORM CORR NITRIC ACID
(TLV=2 PPM). TOX INFO: LITERATURE CITE A MODERATE TO LOW ORDER TO
TOX FOR DIPROPYLENE GLYCOL (DPG), AND EVIDENCE OF SOME KIDNEY DMG
IN RATS AFTER INGESTI ON.

Transport Information:DOT NON-BULK SHIPPING NAME. CHEMICALS, N.O.I. -
NOT DOT REGULATED. DOT BULK SHIPPING NAME - REFER TO BILL OF
LADING. IMO SHIPPING DATA - REFER TO BILL OF LADING. ICAO/IATA
SHIPPING DATA - CHEMICALS, N .O.I. - NOT IATA REGULATED.

SARA Title III Information:TOXIC SUBSTANCES CONTROL ACT (TSCA): ALL
COMPONENTS ARE INCL IN EPA TOXIC SUBSTANCES CTL ACT (TSCA) CHEM
SUBSTANCE INVENTORY. OSHA HAZARD COMMUNICATION STD (29CFR1910.1200)
HAZARD CLASS(ES): IRRITANT. KIDNEY TOXIN. EPA SARA TITLE III
SECTION 312 (40CFR370) HAZARD CLASS. IMMED HLTH HAZARD. EPA SARA
TITLE III 313 (40CFR372) TOXIC CHEMICALS "DE MINIMIS" LEVEL ARE
NONE.
Federal Regulatory Information:CANADA DSL-INCL ON INVENTORY. WHMIS
HAZARD CLASSIFICATION-CLASS D DIVISION 2B. WHMIS TRADE SECRET
REGISTRY NUMBER(S)-NOT APPLICABLE. WHMIS SYMBOLS-STYLIZED T.
EUROPEAN ECONOMIC COMMUNITY (EEC). EINECS /ELINCS MASTER
INVENTORY-INCLUDED ON INVENTORY. EEC SYMBOL-HARMFUL (XN). EEC RISK
(R) PHRASES-IRRITATING TO EYES & SKIN (R36/38). HARMFUL BY INHAL
(R20). EEC SFTY PHRASES-IN CASE OF CONT W/EYES, RINSE IMMED
W/PLENTY OF WATER & SEEK MED ADVICE (S26). AUSTRAILA-AICS-INCLUDED
ON INVENTORY.
State Regulatory Information:STATE REGS: PROPOSITION 65 SUBSTANCES
(COMPONENT(S) KNOWN TO STATE OF CALIFORNIA TO CAUSE CANCER AND/OR
REPRODUCTIVE TOXICITY & SUBJECT TO WARNING & DISCHARGE REQUIREMENTS
UNDER "SAFE DRINKING WATER A ND TOXIC ENFORCEMENT ACT OF
1986"):NONE. NEW JERSEY TRADE SECRET REGISTRY NUMBER (S): NONE.