Product ID:HEMATOXYLIN 1
MSDS Date:09/01/1991
FSC:6550
NIIN:00N092191
Status Code:A
MSDS Number: CJQMB

RICHARD-ALLAN MEDICAL INDUSTRIES

8850 M89
RICHLAND, MI 49083
US

Emergency Phone: 800-424-9300

Info Phone: 616-629-5811

Preparer: KATHERINE R. JOSEPH

Cage: 51883

RICHARD-ALLAN MEDICAL INDUSTRIES

351 RICHLAND, MI 49083 US

Telephone: 616-385-4466

Cage: 51883

15.3%.

CAS: 107-21-1

RTECS: KW2975000

OSHA PEL 50 PPM 8HR TWA

ACGIH TLV: 50 PPM 8 HR TWA

EPA Report Quantity: 1 LB

DOT Report Quantity: 1 LB

ACETIC ACID, GLACIAL

CAS: 64-19-7

RTECS: AF1225000

OSHA PEL 25 MG/M3;10 PPM

ACGIH TLV: 25 MG/M3;10 PPM

EPA Report Quantity: 5000 LBS

DOT Report Quantity: 5000 LBS

Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:ACUTE: SKIN EFFECTS: PROLONGED OR
REPEATED CONTACT CAN CAUSE IRRITATION. PROLONGED OR REPEATED
CONTACT MAY CAUSE REDNESS, BURNING, AND DRYING AND CRACKING OF
SKIN. EYE EFFECTS: CAN CAUSE SEVERE IRRITA TION, REDNESS, TEARING,
BLURRED VISION. SYSTEMIC EFFECTS - INGESTION: CAN CAUSE IRRITATION
TO THE DIGESTIVE TRACT, POSSIBLE SIGNS OF NERVOUS SYSTEM DEPRESSION
(E.G., HEADACHE, DROWSINESS, DIZZINESS, L OSS OF COORDINATION AND
FATIGUE), VISUAL DISTURBANCES, KIDNEY DAMAGE, CONVULSIONS, COMA.
MAY ALSO CAUSE CIRCULATORY COLLAPSE, UREMIA OR DEATH. INHALATION:
MAY CAUSE IRRITATION OF THE NOSE AND THROAT. CHRONIC: OVEREXPOSURE
(EFTS OF OVEREXP)
Effects of Overexposure:HLTH HAZ: TO THE COMPONENTS OF THIS MATERIAL
HAS BEEN SUGGESTED AS A CAUSE OF THE FOLLOWING EFFECTS IN HUMANS.
BRAIN AND NERVOUS SYSTEM DAMAGE, PROBABLE FETUS DAMAGE (BASED ON
TESTS WITH LABORATORY AN IMALS), CHRONIC BRONCHITIS, AND EROSION OF
THE TEETH.
Medical Cond Aggravated by Exposure:RESPIRATORY SYMPTOMS ASSOCIATED
WITH PRE-EXISTING LUNG DISORDERS MAY BE AGGRAVATED BY EXPOSURE TO
THIS MATERIAL.

First Aid:SKIN:REMOVE CONTAM CLTHG (INCL SHOES) IMMED.WASH AFFECTED
AREA OF YOUR BODY W/SOAP OR MILD DETERGENT & LG AMTS OF WATER UNTIL
NO EVID OF CHEM REMAINS - AT LST 15-20 MINS. EYES:IMMED FLUSH
W/PLENTY OF WATER FOR AT LST 15 MINS, OCCAS LIFTING UPPER & LOWER
LIDS. CALL MD. IF YOU HAVE APPRECIABLE EYE IRRIT FROM
SPLASH/EXCESSIVE EXPOS, YOU SHOULD BE REFERRED TO AN OPTHAMOLOGIST
FOR EVAL. INHAL:MOVE PATI ENT TO FRESH AIR IMMED. IF BRTHG IS
DFCLT, ADMIN OXYG. IF BRTHG HAS STOPPED, GIVE ARTF RESP. KEEP
AFFECTED PERS WARM & AT REST. INGEST:DO NOT INDUCE VOMIT. GIVE TAP
WATER, MILK (2-3 GLASSES), MILK OF MAGNESIA/EGG WHITES BEATEN
(SUPP DATA)

Flash Point Method:CC
Flash Point:>93.3C, 200.F
Lower Limits:SEE INGS
Upper Limits:SEE INGS
Extinguishing Media:ALCOHOL FOAM, DRY CHEMICALS, CARBON DIOXIDE, WATER
IN FLOODING AMOUNTS AS FOG. SOLID STREAMS MAY NOT BE EFFECTIVE.
Fire Fighting Procedures:USE NIOSH APPROVED SCBA AND FULL PROTECTIVE
EQUIPMENT . COOL FIRE-EXPOSED CONTAINERS W/WATER FROM SIDE UNTIL
WELL AFTER FIRE IS OUT. USE OF WATER SPRAY TO FLUSH SPILLS CAN ALSO
DILUTE SPILL TO P RODUCE NON-FLAMMABLE MIXTURES. WATER RUNOFF,
HOWEVER, SHOULD BE CONTAINED FOR TREATMENT.
Unusual Fire/Explosion Hazard:FLAMM CLASS (OSHA): II. VAPS ARE HVR/AIR
& MAY TRAVEL ALONG GROUNG/MAY BE MOVED BY VENT & IGNITED BY PILOT
LIGHTS, OTHER FLAMES, SPKS, HEATERS, SMOKING, ELEC MOTORS, STATIC
DISCHARGE/OTHER SOURCES AT LOCATIONS DIST FROM MATL HNDLG POINT.
HAZ SYMBOLOGY:HLTH - 1 (SLIGHTLY HAZ); FLAMM - 1 (ABOVE 200F);
REACT - 0 (STABLE).

Spill Release Procedures:EMERS:IF SPILL OF APPRECIABLE QTY OCCURS,
LEAVE AREA QUICKLY UNLESS YOU HAVE SPECIFIC EMER DUTIES. DO NOT
TOUCH SPILLED MATL. DESIGNATED PERS MAY STOP LEAK & SHUT OFF IGNIT
SOURCES IF THESE PROCS CAN BE DONE W/OUT RISK. DESIGNATED PERS
SHOULD ISOLATE HAZ AREA & DENY ENTRY EXCEPT FOR NEC PEOPLE
PROTECTED BY SUITABLE PROT CLTHG & NIOSH APPRVD RESPS ADEQ OR
EXPOS. USE WATER SPRAY TO REDUCE(SUPP DATA)

Handling and Storage Precautions:KEEP CONTAINER CLOSED. KEEP AWAY FROM
HEAT AND OPEN FLAME. STORE AT ROOM TEMPERATURE: 15-30C (59-86F).

Respiratory Protection:NIOSH APPROVED RESPIRATORS ARE ADVISED IN THE
ABSENCE OF PROPER ENVIRONMENTAL CONTROL.
Ventilation:GENERAL MECHANICAL VENTILATION OR FUME HOOD.
Protective Gloves:CHEMICAL RESISTANT GLOVES.
Eye Protection:ANSI APPROVED CHEMICAL WORKERS GOGGLES .
Other Protective Equipment:EYE WASH & DELUGE SHOWER MEETING ANSI DESIGN
CRITERIA .
Supplemental Safety and Health
FIRST AID PROC:W/WATER. NEVER GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS
PERSON. GET MED ATTN IMMED. -- SPILL PROC:VAPS. DO NOT SMOKE, &
PROHIBIT ALL FLAMES/FLARES IN HAZ AREA. OCCUP SPILL: FOR SM CNTNR
S, PLACE LEAKING CNTNR IN WELL VENTED AREA. TAKE UP SM SPILLS
W/ABSORB MATL & TRANSFER TO HOOD. PLACE WASTE (OTHER INFO)

Boiling Pt:>98.3C, 209.F
B.P. Text:98.3-158.9C (209-318F)
Vapor Pres:32 MM HG
Vapor Density:1.1(AIR=1)
Spec Gravity:1.052 @ 21C (WATER=1)
Evaporation Rate & Reference:0.3 (BUTYL ACETATE=1)
Solubility in Water:COMPLETE
Appearance and Odor:PURPLE LIQUID; FAINT SWEET ODOR.
Percent Volatiles by Volume:76

Stability Indicator/Materials to Avoid:YES
AVOID CONTACT WITH STRONG OXIDIZING AGENTS, HYDROXIDES, AMINES, OXIDES
AND CARBONATES. AVOID CONTAMINATION WITH ACETALDEHYDE, CHROMIC ACID
AND ALKALIES.
Hazardous Decomposition Products:THERMAL DECOMPOSITION OR BURNING MAY
PRODUCE CARBON MONOXIDE AND/OR CARBON DIOXIDE AND/OR NITROGEN
OXIDES.

Waste Disposal Methods:YOUR EMPLOYER MUST DISPOSE OF WASTE CONTAINING
ALCOHOLS I/A/W APPLIC LOC, STATE & FED LAWS (EACH HAS UNIQUE
REQUIREMENTS) & IN A MANNER THAT MINIMIZES EXPOS OF EMPLOYEES AT
SITE & OF CLEAN-UP CREW. HE MATOXYLIN 1 IS CONSIDERED TO BE A
HAZARDOUS WASTE - HAZARDOUS WASTE CODE D001.

Toxicological Information:SEE INGREDIENTS.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.

Ecological:PRODUCT IS A MIXTURE OF LISTED COMPONENTS.

Transport Information:DOT SHIPPING NAME IS 'DYE INTERMEDIATE LIQUID'.
DOT HAZARD CLASS IS 'NONE'. SHIPPING CONTAINERS: BOTTLES.

SARA Title III Information:CERCLA ("SUPERFUND") REPORTABLE QUANTITY:
NOT APPLICABLE. SARA SECTION 313 CHEMICALS: NONE.
State Regulatory Information: