Product ID:2,4-DINITROPHENOL, D7004
MSDS Date:04/01/1999
FSC:6505
NIIN:00N092728
Status Code:A
MSDS Number: CJTMW

Emergency Phone: 314-771-5765

Info Phone: 314-771-5765

Cage: 21076

Telephone: 314-771-5765

Cage: 21076

(ORAL, RAT) 30 MG/KG

CAS: 51-28-5

RTECS: SL2800000

EPA Report Quantity: 10 LBS

DOT Report Quantity: 10 LBS

LD50 LC50 Mixture:SEE INGREDIENT AND TOXICOLOGICAL INFO
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:ACUTE EFFECTS: MAY BE FATAL IF
INHALED, SWALLOWED OR ABSORBED THROUGH SKIN. CAUSES EYE AND SKIN
IRRITATION. MATERIAL IS IRRITATING TO MUCOUS MEMBRANES AND UPPER
RESPIRATORY TRACT. DISRUPTS OXIDATIVE P HOSPHORYLATION WHICH
RESULTS IN INCREASED METABOLISM, CONSUMPTION OF OXYGEN AND
PRODUCTION OF HEAT. EXPOSURE IS CHARACTERIZED BY SUDDEN ONSET OF
FATIGUE, THIRST AND SWEATING. SYMPTOMS INCLUDE NAUSEA, VOMITING,
ANOREXIA, WEAKNESS, DIZZINESS, VERTIGO, HEADACHE AND SWEATING.
CHRONIC EFFECTS: DAMAGE TO THE LIVER. DERMATITIS. TARGET ORGANS:
CENTRAL NERVOUS SYSTEM. EYES. LIVER, KIDNEYS. BLOOD, LUNGS.
Effects of Overexposure:SEE HEALTH HAZARDS.

First Aid:EYES: IN CASE OF CONTACT, IMMEDIATELY FLUSH EYES WITH COPIOUS
AMOUNTS OF WATER FOR AT LEAST 15 MINUTES. SKIN: IN CASE OF CONTACT,
IMMEDIATELY FLUSH SKIN WITH COPIOUS AMOUNTS OF WATER FOR AT LEAST
15 M INUTES WHILE REMOVING CONTAMINATED CLOTHING AND SHOES.
INHALATION: IF INHALED, REMOVE TO FRESH AIR. IF NOT BREATHING GIVE
ARTIFICIAL RESPIRATION. IF BREATHING IS DIFFICULT, GIVE OXYGEN.
INGESTION: IF SWALLOWED, WASH OUT MOUTH WITH WATER PROVIDED PERSON
IS CONSCIOUS. CALL A PHYSICIAN. WASH CONTAMINATED CLOTHING BEFORE
REUSE.

Extinguishing Media:WATER SPRAY. CARBON DIOXIDE, DRY CHEMICAL POWDER OR
APPROPRIATE FOAM.
Fire Fighting Procedures:USE NIOSH APPROVED SCBA AND FULL PROTECTIVE
EQUIPMENT TO PREVENT CONTACT WITH SKIN AND EYES. FLAMMABLE SOLID.
Unusual Fire/Explosion Hazard:MAY EXPLODE WHEN HEATED. EMITS TOXIC
FUMES UNDER FIRE CONDITIONS.

Spill Release Procedures:WEAR NIOSH APPROVED SELF-CONTAINED BREATHING
APPARATUS, RUBBER BOOTS AND HEAVY RUBBER GLOVES. SWEEP UP, PLACE IN
A BAG AND HOLD FOR WASTE DISPOSAL. AVOID RAISING DUST. VENTILATE
AREA AND WASH SPILL SI TE AFTER MATERIAL PICKUP IS COMPLETE.

Handling and Storage Precautions:KEEP TIGHTLY CLOSED. LIGHT SENSITIVE.
STORE IN A COOL, DRY PLACE. DRY MATERIAL IS AN EXPLOSIVE. MATERIAL
IS MOISTENED WITH 15% WATER.
Other Precautions:DO NOT BREATHE DUST. AVOID CONTACT WITH EYES, SKIN
AND CLOTHING. AVOID PROLONGED OR REPEATED EXPOSURE. READILY
ABSORBED THROUGH SKIN. WASH THOROUGHLY AFTER HANDLING. HIGHLY
TOXIC. IRRITANT.

Respiratory Protection:WEAR APPROPRIATE NIOSH APPROVED RESPIRATOR.
Ventilation:USE ONLY IN A CHEMICAL FUME HOOD.
Protective Gloves:CHEMNICAL-RESISTANT GLOVES.
Eye Protection:ANSI APPROVED CHEMICAL WORKERS GOGGLES .
Other Protective Equipment:ANSI APPROVED EYE WASH AND DELUGE SHOWER .
OTHER PROTECTIVE CLOTHING.
Supplemental Safety and Health

Melt/Freeze Pt:>106.C, 222.8F
M.P/F.P Text:106-108C
Vapor Density:6.35
Appearance and Odor:YELLOW POWDER.

STRONG OXIDIZING AGENTS. STRONG BASES. ACID CHLORIDES. ACID ANHYDRIDES.
SENSITIVE TO LIGHT.
Hazardous Decomposition Products:TOXIC FUMES OF CARBON MONOXIDE, CARBON
DIOXIDE, NITROGEN OXIDES.

Waste Disposal Methods:DISSOLVE OR MIX THE MATERIAL WITH A COMBUSTIBLE
SOLVENT AND BURN IN A CHEMICAL INCINERATOR EQUIPPED WITH AN
AFTERBURNER AND SCRUBBER. OBSERVE ALL FEDERAL, STATE AND LOCAL
ENVIRONMENTAL REGULATIONS.

Toxicological Information:RTECS 3: SL2800000 PHENOL, 2,4-DINITRO-.
IRRIT DATA: SKN-RBT 300 MG/4W-I MLD JIHTAB 30,10,1948. TOXICITY
DATA: ORL-HMN LDLO: 36 MG/KG JAMAAP 101,1333,1933. ORL-RAT LD50: 30
MG/KG TXAPA9 21,315,1972. I PR-RAT LD50: 20 MG/KG JPPMAB
17,814,1965. SCU-RAT LD50: 25 MG/KG JPETAB 49,187,1933. IVN-RAT
LD50: 72 MG/KG TXAPA9 6,232,1964. ORL-MUS LD50: 45 MG/KG FATOAO
28,493,1965. IPR-MUS LD50: 26 MG/KG BCPCA6 18,1389,1969. SCU-MUS
LD50: 58 MG/KG TXAPA9 6,232,1964. IVN-MUS LD50: 56 MG/KG TXAPA9
6,232,1964. ORL-CAT DL50: 75 MG/KG 85 GMAT -,62,1982. ORL-RBT DL50:
30 MG/KG FATOAO 28,493,1965. ORL-GPG LD50: 81 MG/KG FATOAO
(ECOLOGICAL INFO)

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.

Ecological:DATA NOT YET AVAILABLE.--TOXICOLOGICAL INFO: 28,493,1965.
IPR-GPG LD50: 28 MG/KG ARZNAD 8,381,1958. IMS-PGN LD50: 6500 UG/KG
JPETAB 53,58,1935. UNR-MAM LD50: 40 MG/KG 30ZDA9 -,97,1971. ORL-BWD
LD50: 1 3 MG/KG TXAPA9 21,315,1972. TARGET ORGAN DATA: BEHAVIORAL
(ALTERED SLEEP TIME; CONVULSIONS OR EFFECT ON SEIZURE THRESHOLD;
CHANGE IN MOTOR ACTIVITY; ATAXIA; TETANY; COMA). CARDIAC (CHANGE IN
RATE). LU NGS, THORAX OR RESPIRATION (RESPIRATORY STIMULATION).
EFFECTS ON EMBRYO OR FETUS (FETOTOXICITY). NUTRITIONAL AND GROSS
METABOLIC (BODY TEMPERATURE INCREASE). (TRANSPORT INFO)

Transport Information:CONTACT SIGMA CHEMICAL COMPANY FOR TRANSPORTATION
INFORMATION. --ECOLOGICAL INFO: ONLY SELECTED REGISTRY OF TOXIC
EFFECTS OF CHEMICAL SUBSTANCES (RTECS) DATA IS PRESENTED HERE. SEE
ACTUAL ENTRY IN RTE CS FOR COMPLETE INFO.

SARA Title III Information:THIS PRODUCT IS SUBJECT TO SARA SECTION 313
REPORTING REQUIREMENTS.
Federal Regulatory Information:EUROPEAN INFORMATION - HIGHLY FLAMMABLE.
TOXIC. R 23/24/25 TOXIC BY INHALATION, IN CONTACT W/SKIN & IF
SWALLOWED. R 33 DANGER OF CUMULATIVE EFFECTS. S 28 AFTER CONTACT
W/SKIN, WASH IMMEDIATELY W/PLENT Y OF WATER. S 37 WEAR SUITABLE
GLOVES. S 45 IN CASE OF ACCIDENT OF IF YOU FEEL UNWELL, SEE MEDICAL
ADVICE IMMEDIATELY (SHOW LABEL WHERE POSSIBLE). REVIEWS, STANDARDS
& REGULATIONS: OEL=MAK. EPA FIFRA 1988 PESTICIDE SUBJECT TO
REGISTRATION OR RE-REGISTRATION FEREAC 54, 7740, 1989. NOHS 1974:
HZD 2711 0; NIS 1; TNF 19; NOS 1; TNE 38. NOES 1983: HZD 27110; NIS
1; TNF 7; NOS 3; TNE 130; TFE 14. (STATE REG INFO)
State Regulatory Information:N/P. --FED REG INFO: EPA TSCA SECTION 8(B)
CHEMICAL INVENTORY. EPA TSCA SECTION 8(D) UNPUBLISHED HEALTH/SAFETY
STUDIES ON EPA IRIS DATABASE. EPA TSCA TEST SUBMISSION (TSCATS)
DATA BASE, JUNE 1998.