Product ID:P2069, PHENOL: CHLOROFORM: ISOAMYL ALCOHOL 25:24:1 (SUP DAT)
MSDS Date:07/01/1999
FSC:6810
NIIN:00N092700
Status Code:A
MSDS Number: CJTPW

SIGMA CHEMICAL CO

ST LOUIS, MO 63178
US

Emergency Phone: 314-771-5765

Info Phone: 314-771-5765

Cage: 21076

SIGMA CHEMICAL COMPANY

14508 ST LOUIS, MO 63178 US

Telephone: 314-771-5765

Cage: 21076

PHENOL (ACS REAGENT)

CAS: 108-95-2

RTECS: SJ3325000

OSHA PEL 19 MG/M3;5 PPM

ACGIH TLV: 19 MG/M3;5 PPM

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

CHLOROFORM (ACS GRADE)

CAS: 67-66-3

RTECS: FS9100000

OSHA PEL C240 MG/M3;C50 PPM

ACGIH TLV: 49 MG/M3;10 PPM

EPA Report Quantity: 10 LBS

DOT Report Quantity: 10 LBS

ISOAMYL ALCOHOL (ACS REAGENT)

CAS: 123-51-3

RTECS: EL5425000

OSHA PEL 360 MG/M3;100 PPM

ACGIH TLV: 361 MG/M3;100 PPM

Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:NO
Health Hazards Acute and Chronic:HIGHLY TOXIC (USA). TOXIC (EU). MAY
CAUSE CANCER. MAY CAUSE HERITABLE GENETIC DAMAGE. TOXIC BY
INHALATION, IN CONTACT WITH SKIN AND IF SWALLOWED. CAUSES BURNS.
VESICANT. TARGET ORGANS: CENTRAL NERVOUS SYSTEM, LIVER.
Explanation of Carcinogenicity:CHLOROFORM: IARC MONOGRAPHS, SUPPLEMENT,
VOLUME 7, PAGE 152, 1998: GROUP 2B. NTP 8TH ANNUAL REPORT ON
CARCINOGENS, 1998: REASONABLY ANTICIPATED TO BE HUMAN CARCINOGEN.
HUMAN: LIVER/KIDNEY TUMORS, CENT RAL NERVOUS SYSTEM EFFECTS.
Effects of Overexposure:SEE HEALTH HAZARDS.

First Aid:IN CASE OF ACCIDENT OR IF YOU FEEL UNWELL, SEEK MEDICAL
ADVICE IMMEDIATELY (SHOW THE LABEL WHERE POSSIBLE). EYES:
IMMEDIATELY RINSE WITH PLENTY OF WATER FOR AT LEAST 15 MINUTES AND
SEEK MEDICAL ADVICE . SKIN: FLUSH WITH COPIOUS AMOUNTS OF WATER.
SEE MD . TAKE OFF IMMEDIATELY ALL CONTAMINATED CLOTHING.
INHALATION: REMOVE TO FRESH AIR. SUPPORT BREATHING (GIVE OXYGEN OR
ARTIFICIAL RESPIRATION) ( ). INGESTION: CALL MD IMMEDIATELY .

Extinguishing Media:USE MEDIA SUITABLE FOR SURROUNDING FIRE .
Fire Fighting Procedures:WEAR NIOSH APPROVED SCBA AND FULL PROTECTIVE
EQUIPMENT .

Spill Release Procedures:EVACUATE AREA. WEAR NIOSH APPROVED
SELF-CONTAINED BREATHING APPARATUS, RUBBER BOOTS AND HEAVY RUBBER
GLOVES. COVER WITH DRY LIME OR SODA ASH, PICK UP, KEEP IN A CLOSED
CONTAINER AND HOLD FOR WASTE DIS POSAL. VENTILATE AREA AND WASH
SPILL SITE AFTER MATERIAL PICKUP IS COMPLETE.

Handling and Storage Precautions:VESICANT. COMBUSTIBLE. UNPLEASANT
ODOR.

Respiratory Protection:WEAR NIOSH APPROVED RESPIRATOR APPROPRIATE FOR
EXPOSURE OF CONCERN .
Protective Gloves:WEAR IMPERVIOUS GLOVES .
Eye Protection:ANSI APPROVED CHEMICAL WORKERS GOGGLES .
Other Protective Equipment:EYEWASH AND DELUGE SHOWER MEETING ANSI
DESIGN CRITERIA . WEAR SUITABLE PROTECTIVE CLOTHING.
Work Hygienic Practices:TAKE OFF IMMEDIATELY ALL CONTAMINATED CLOTHING.
Supplemental Safety and Health
TRADE NAME/PART NUMBER: INCLUDES BOTTLE OF EQUILIBRATION BUFFER.

Stability Indicator/Materials to Avoid:YES

Waste Disposal Methods:THIS COMBUSTIBLE MATERIAL MAY BE BURNED IN A
CHEMICAL INCINERATOR EQUIPPED WITH AN AFTERBURNER AND SCRUBBER.
OBSERVE ALL FEDERAL, STATE AND LOCAL ENVIRONMENTAL REGULATIONS.

Toxicological Information:RTECS #: AY7535000 ALANINE, PHENYL-, L-.
TOXICITY DATA: IPR-RAT LD50: 5287 MG/KG ABBIA4 58,253,1955. IPR-MUS
LD50: >1322 MG/KG YKKZAJ 97,1117,1977. TARGET ORGAN DATA: MATERNAL
EFFECTS (UTERUS, CERVIX, VAGINA). SPECIFIC DEVELOPMENTAL
ABNORMALITIES (CARDIOVASCULAR SYSTEM). ONLY SELECTED REGISTRY OF
TOXIC EFFECTS OF CHEMICAL SUBSTANCES (RTECS) DATA IS PRESENTED
HERE. SEE ACTUAL ENTRY IN RTECS FOR COM PLETE INFORMATION.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.

Ecological:DATA NOT YET AVAILABLE.

Transport Information:CONTACT SIGMA CHEMICAL COMPANY FOR TRANSPORTATION
INFORMATION.

Federal Regulatory Information:HIGHLY TOXIC (USA). TOXIC (EUROPE).
State Regulatory Information: