Product ID:LEAD AMMONIUM CITRATE ACETATE COMPLEX, L4009
MSDS Date:01/01/1999
FSC:6810
NIIN:00N093244
Status Code:A
MSDS Number: CJWMM

Emergency Phone: 314-771-5765

Info Phone: 314-771-5765

Cage: 21076

Telephone: 314-771-5765

Cage: 21076

(ORAL,RAT) 4665 MG/KG.

CAS: 6080-56-4

RTECS: OF8050000

LEAD

CAS: 7439-92-1

RTECS: OF7525000

ACGIH TLV: 0.15 MG/M3

EPA Report Quantity: 1 LB

DOT Report Quantity: 1 LB

LD50 LC50 Mixture:SEE INGREDIENTS & TOXICOLOGICAL INFO.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:ACUTE: HARMFUL IF SWALLOWED, INHALED,
OR ABSORBED THROUGH SKIN. MAY CAUSE IRRITATION. CHRONIC: NOTE: LEAD
APPEARS ON THE NAVY LISTING OF OCCUPATIONAL CHEMICAL REPRODUCTIVE
HAZARDS. SEEK CONSULTATION F ROM APPROPRIATE HEALTH PROFESSIONALS
CONCERNING THE LATEST HAZARD LIST INFORMATION AND SAFE HANDLING AND
EXPOSURE INFORMATION . CARCINOGEN. MUTAGEN. REPRODUCTIVE HAZARD.
TARGET ORGAN(S): BLOOD, CENTRAL NERVOUS SYSTEM, PERIPHERAL NERVOUS
SYSTEM, GASTROINTESTINAL SYSTEM, SKELETAL MUSCLE, KIDNEYS. TARGET
ORGAN DATA: BLOOD (OTHER CHANGES). EFFECTS ON NEWBORNS (GROWTH
STATISTICS; BIOCHEMICAL AND METABOLIC; BEHAVIORAL; (EFTS OF
OVEREXP)
Explanation of Carcinogenicity:LEAD: IARC MONOGRAPHS, SUPPLEMENT. VOL
7, PG 230, 1987: GROUP 2B.
Effects of Overexposure:HLTH HAZS: PHYSICAL; OTHER POSTNATAL MEASURES
OR EFFECTS).

First Aid:INGESTION: WASH OUT MOUTH WITH WATER PROVIDED PERSON IS
CONSCIOUS. CALL MD. SKIN: FLUSH WITH COPIOUS AMOUNTS OF WATER FOR
AT LEAST 15 MINUTES. REMOVE CONTAMINATED CLOTHING AND SHOES. CALL
MD. INHALATI ON: REMOVE TO FRESH AIR. IF BREATHING BECOMES
DIFFICULT, CALL MD. EYES: FLUSH WITH COPIOUS AMOUNTS OF WATER FOR
AT LEAST 15 MINUTES. ASSURE ADEQUATE FLUSHING BY SEPARATING THE
EYELIDS WITH FINGERS. CA LL MD.

Extinguishing Media:CARBON DIOXIDE, DRY CHEMICAL POWDER OR APPROPRIATE
FOAM.
Fire Fighting Procedures:USE NIOSH APPROVED SCBA AND FULL PROTECTIVE
EQUIPMENT .
Unusual Fire/Explosion Hazard:EMITS TOXIC FUMES UNDER FIRE CONDITIONS.

Spill Release Procedures:WEAR NIOSH APPROVED SELF-CONTAINED BREATHING
APPARATUS, RUBBER BOOTS AND HEAVY RUBBER GLOVES. SWEEP UP, PLACE IN
A BAG AND HOLD FOR WASTE DISPOSAL. AVOID RAISING DUST. VENTILATE
AREA AND WASH SPILL SI TE AFTER MATERIAL PICKUP IS COMPLETE.
Neutralizing Agent:SEE DISPOSAL CONSIDERATIONS SECTION.

Handling and Storage Precautions:DO NOT BREATHE DUST. IN CASE OF
ACCIDENT OR IF YOU FEEL UNWELL, SEEK MEDICAL ADVICE IMMEDIATELY
(SHOW THE LABEL WHERE POSSIBLE). CAUTION: SUBSTANCE NOT YET FULLY
TESTED. AVOID EXPOSURE - OBTAIN SPECIA L INSTRUCTIONS BEFORE USE.
Other Precautions:TOXIC. MAY CAUSE CANCER. MAY CAUSE HERITABLE GENETIC
DAMAGE. TOXIC BY INHALATION, IN CONTACT WITH SKIN AND IF SWALLOWED.
DANGER OF CUMULATIVE EFFECTS. REPRODUCTIVE HAZARD. MAY CAUSE HARM
TO THE UNBORN CHILD.

Respiratory Protection:NIOSH APPROVED RESPIRATOR.
Ventilation:MECHANICAL EXHAUST REQUIRED.
Protective Gloves:COMPATIBLE CHEMICAL-RESISTANT GLOVES.
Eye Protection:ANSI APPROVED CHEMICAL WORKERS GOGGLES AND FULL LENGTH
FACESHIELD .
Other Protective Equipment:EYE WASH AND DELUGE SHOWER MEETING ANSI
DESIGN CRITERIA . WEAR SUITABLE PROTECTIVE CLOTHING.
Supplemental Safety and Health
WASTE DISP METH: FEDERAL, STATE AND LOCAL ENVIRONMENTAL REGULATIONS.

Solubility in Water:SOLUBLE
Appearance and Odor:SOLID.

Stability Indicator/Materials to Avoid:YES
Hazardous Decomposition Products:TOXIC FUMES OF: CARBON MONOXIDE,
CARBON DIOXIDE, LEAD/LEAD OXIDES, NITROGEN OXIDES.
Conditions to Avoid Polymerization:WILL NOT OCCUR.

Waste Disposal Methods:MATL SHOULD BE DISSOLVED IN 1) WATER; 2) ACID
SOLN OR 3) OXIDIZED TO WATER-SOLUBLE STATE. PRECIPITATE MATL AS
SULFIDE, ADJUSTING PH OF SOLN TO 7 TO COMPLETE PRECIPITATION.
FILTER INSOLUBLES & DISPOSE OF THEM IN HAZ-WASTE SITE. DESTROY ANY
EXCESS SULFIDE W/SODIUM HYPOCHLORITE. NEUTRALIZE SOLN BEFORE
FLUSHING DOWN DRAIN. OBSERVE ALL (SUPP DATA)

Toxicological Information:TOXICITY DATA: LEAD ACETATE (II), TRIHYDRATE:
LD50:(ORAL,RAT) 4665 MG/KG - ATDAEI 1,713,1992. LD50:(IPR,MUS) 174
MG/KG - TXAPA9 63,461,1982. ONLY SELECTED REGISTRY OF TOXIC EFFECTS
OF CHEMICAL SUBSTAN CES (RTECS) DATA IS PRESENTED HERE. SEE ACTUAL
ENTRY IN RTECS FOR COMPLETE INFORMATION.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.

Ecological:DATA NOT YET AVAILABLE.

Transport Information:CONTACT SIGMA CHEMICAL COMPANY FOR TRANSPORTATION
INFORMATION.

SARA Title III Information:U.S. INFORMATION: THIS PRODUCT IS SUBJECT TO
SARA SECTION 313 REPORTING REQUIREMENTS - LEAD COMPOUNDS.
Federal Regulatory Information:EUROPEAN INFO: CAUTION: SUBSTANCE NOT
YET FULLY TESTED. TOXIC. R 20/22 - HARMFUL BY INHAL & IF SWALLOWED.
R 33 - DANGER OF CUMULATIVE EFTS. R 61 - MAY CAUSE HARM TO THE
UNBORN CHILD. S 45 - IN CASE OF ACCIDENT/IF YOU FEEL UNWELL, SEEK
MED ADVICE IMMED (SHOW THE LABEL WHERE POSSIBLE). S 53 - AVOID
EXPOS- OBTAIN SPECIAL INSTRUCTIONS BEFORE USE. REVIEW, STANDARDS &
REGS: OEL=MAK. IARC CANCER REVIEW: ANIMAL SUFFICIENT EVIDENCE
IMEMDT 1, 20, 1972. NIOSH REL TO LEAD, INORGANIC-AIR:10H TWA <0.1
MG(PB )/M3 - NIOSH* DHHS #92-100,1992. NOES 1983: HZD X5250; NIS 3;
TNF 95; NOS 3; TNE 845; TFE 433. (STATE REGS)
State Regulatory Information:DATA NOT AVAILABLE. FED REGS: NTP 7TH
ANNUAL REPORT ON CARCINOGENS, 1992: ANTICIPATED TO BE CARCINOGEN.