Product ID:ACROLEIN
MSDS Date:10/02/1997
FSC:6810
NIIN:00N091017
Status Code:A
MSDS Number: CJXPC

Emergency Phone: 888-253-1635

Info Phone: 888-253-1635

Cage: 0SHS3

Telephone: 888-253-1635

Cage: 0SHS3

ACROLEIN

CAS: 107-02-8

RTECS: AS1050000

OSHA PEL 0.25 MG/M3;0.1 PPM

ACGIH TLV: 0.23 MG/M3;0.1 PPM

EPA Report Quantity: 1 LB

DOT Report Quantity: 1 LB

LD50 LC50 Mixture:SEE TOXICOLOGICAL INFORMATION.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:ACUTE: IF INHALED, SEVERE IRRITATION
OF THE NOSE, THROAT AND UPPER RESPIRATORY TRACT WILL RESULT. CAN BE
ABSORBED THROUGH THE SKIN. SKIN AND EYE CONTACT MAY RESULT IN
BURNS. POSSIBLE DERMATITIS FROM S KIN CONTACT. INGESTION CAUSES
IRRITATION AND BURNING SENSATIONS OF THE UPPER GASTROINTESTINAL
TRACT. INHALATION MAY BE FATAL DUE TO SPASMS, INFLAMMATION, EDEMA,
OF THE LARYNX AND BRONCHI, CHEMICAL PNE UMONITIS AND PULMONARY
EDEMA. SEVERE LACHRYMATOR. SYMPTOMS INCLUDE BURNING SENSATION,
COUGHING, WHEEZING, SHORTNESS OF BREATH, AND HEADACHES. SYMPTOMS
MAY INCLUDE NAUSEA, VOMITING, AND LARYNGITIS. (EF FECTS OF
OVEREXPOSURE)
Effects of Overexposure:HEALTH HAZARDS: CHRONIC: SUSPECTED HUMAN
CARCINOGEN. EYES, LUNG AND LIVER DAMAGE. CARDIOVASCULAR PROBLEMS.
POSSIBLE CANCER HAZARD. OTHER EFFECTS OF OVEREXPOSURE: NONE.
Medical Cond Aggravated by Exposure:CARDIOVASCULAR PROBLEMS.

First Aid:INHAL: IMMEDIATELY REMOVE TO FRESH AIR. IF BREATHING IS
DIFFICULT, GIVE OXYGEN. IF BREATHING HAS STOPPED, GIVE ARTIFICIAL
RESPIRATION. EYES: IMMEDIATELY FLUSH EYES, INCLUDING UNDER EYELIDS,
GENTLY BUT THOROUGHLY W/PLENTY OF RUNNING WATER FOR AT LEAST 15
MINUTES. SEEK MEDICAL ATTENTION AS SOON AS POSSIBLE. SKIN:
IMMEDIATELY FLUSH W/LARGE AMOUNTS OF WATER. USE SOAP IF AVAILABLE.
REMOVE CONTAMINATED CLOTHING, INCLUDING SHOES, AFTER FLUSHING HAS
BEGUN. GET PROMPT MEDICAL ATTENTION. INGEST: HAVE CONSCIOUS & ALERT
PERSON DRINK 1-2 GLASSES OF WATER. CONTACT MD IMMEDIATELY. INDUCE
VOMITING. IN EVENT O F EXPOS, CONSULT MD. NOTE TO MD: NONE.

Flash Point:=-26.C, -14.8F
Autoignition Temp:=220.C, 428.F
Lower Limits:2.80%
Upper Limits:31.00%
Extinguishing Media:CARBON DIOXIDE, FOAM, OR DRY CHEMICAL. WATER MAY BE
EFFECTIVE FOR COOLING CYLINDERS, BUT MAY NOT EFFECT EXTINGUISHMENT.
Fire Fighting Procedures:WEAR NIOSH APPROVED SELF-CONTAINED BREATHING
APPARATUS AND FULL PROTECTIVE EQUIPMENT . KEEP FIRE-EXPOSED
CYLINDERS COOL WITH WATER SPRAY. MOVE CYLINDERS AWAY FROM FIRE IF
THIS CAN BE DONE SAFELY .
Unusual Fire/Explosion Hazard:TOXIC CARBON MONOXIDE MAY BE GIVEN OFF
DURING COMBUSTION. CYLINDER RUPTURE MAY OCCUR UNDER FIRE
CONDITIONS. DO NOT EXPOSE TO HEAT OR FLAME. CAN REACT VIOLENTLY
WITH OXIDIZING MATERIALS. VAPORS MAY TRA VEL A CONSIDERABLE
DISTANCE TO THE SOURCE OF IGNITION AND FLASH BACK.

Spill Release Procedures:EVACUATE AND VENTILATE AREA. REMOVE ALL
SOURCES OF IGNITION. COVER WITH AN ACTIVATED CARBON ABSORBENT, TAKE
UP, AND PLACE IN CLOSED CONTAINERS FOR DISPOSAL. USE NON-SPARKING
TOOLS. SPECIALIZED EQUIPME NT: NONE.

Handling and Storage Precautions:SECURE CYLINDER WHEN USING TO PROTECT
FROM FALLING. USE SUITABLE HAND TRUCK TO MOVE CYLINDERS. USE
SPARK-PROOF TOOL AND EXPLOSION-PROOF EQUIPMENT. USE ONLY IN A
CHEMICAL FUME HOOD. AVOID EXPOSURE TO D IRECT SUNLIGHT.
Other Precautions:STORE IN WELL VENTILATED AREAS. KEEP VALVE PROTECTION
CAP ON CYLINDERS WHEN NOT IN USE. STORE AWAY FROM HEAT, FLAME, AND
SPARKS. KEEP AWAY FROM OXIDIZING AGENTS. REFRIGERATE AT 2-8C.

Respiratory Protection:USE A NIOSH APPROVED SELF-CONTAINED BREATHING
APPARATUS IN CASE OF EMERGENCY OR NON-ROUTINE USE.
Ventilation:PROVIDE ADEQUATE GENERAL AND LOCAL EXHAUST VENTILATION TO
MAINTAIN CONCENTRATIONS BELOW EXPOSURE AND FLAMMABLE LIMITS.
Protective Gloves:IMPERVIOUS GLOVES.
Eye Protection:ANSI APPROVED CHEMICAL WORKERS GOGGLES .
Other Protective Equipment:ANSI APPROVED EMERGENCY EYEWASH AND DELUGE
SHOWER . COVERALLS, BOOTS, AND/OR OTHER RESISTANT PROTECTIVE
CLOTHING. SAFETY SHOES WHEN HANDLING CYLINDERS.
Work Hygienic Practices:TO PREVENT STATIC SPARKS, ELECTRICALLY-GROUND
AND BOND ALL EQUIPMENT USED WITH AND AROUND MATERIAL.
Supplemental Safety and Health
ODOR THRESHOLD: 1.8 PPM. EMERGENCY OVERVIEW: POISONOUS, FLAMMABLE
LIQUID AND VAPOR. MAY BE FATAL IF INHALED. CAN CAUSE EYE AND SKIN
BURNS. MAY CAUSE IRRITATION TO RESPIRATORY TRACT.

Boiling Pt:=53.C, 127.4F
Vapor Pres:210 MM HG @ 20C
Vapor Density:1.94 AIR=1
Spec Gravity:0.84 @ 20C (H*2O=1)
Solubility in Water:SOLUBLE
Appearance and Odor:COLORLESS TO PALE YELLOW LIQUID WITH PUNGENT ODOR.

Stability Indicator/Materials to Avoid:NO
OXIDIZING AGENTS, ACIDS AND BASES. REDUCING AGENTS. OXYGEN. AMINES,
AMMONIA, AND ALCOHOLS. ALKALI AND ALKALINE EARTH METALS.
Stability Condition to Avoid:SPARKS, FLAME, HEAT AND OTHER SOURCES OF
IGNITION. CONTACT WITH AIR.
Hazardous Decomposition Products:TOXIC CARBON MONOXIDE.

Waste Disposal Methods:RETURN CYLINDERS TO SUPPLIER WITH ANY VALVE
OUTLET PLUGS OR CAPS SECURED AND VALVE PROTECTION CAP IN PLACE.
FOLLOW FEDERAL, STATE AND LOCAL REGULATIONS. NON-RETURNABLE
CYLINDERS MUST NOT BE REFILLED. DISPOSE OF NON-REFILLABLE
CYLINDERS IN ACCORDANCE WITH FEDERAL, STATE, AND LOCAL REGULATIONS.

Toxicological Information:LETHAL CONCENTRATION (LC50): 15.65 PPM, RAT 1
HOUR. LETHAL DOSE 50 (LD50): NOT APPLICABLE. TERATOGENICITY: NOT
APPLICABLE. REPRODUCTIVE EFFECTS: NOT APPLICABLE. MUTAGENICITY: NOT
APPLICABLE.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.

Ecological:NO ADVERSE ECOLOGICAL EFFECTS ARE EXPECTED.

Transport Information:CONCENTRATION: 99+%. DOT DESCRIPTION (US ONLY):
PROPER SHIPPING NAME: ACROLEIN; HAZARD CLASS: 6.1 (POISON), PACKING
GROUP I; IDENTIFICATION NUMBER: UN1092; REPORTABLE QUANTITIES: 1
LB; LABELING: POISO N, FLAMMABLE LIQUID. ADR/RID (EU ONLY): CLASS
6.1, 8 (A) 2. SPECIAL PRECAUTIONS: CYLINDERS SHOULD BE TRANSPORTED
IN A SECURE UPRIGHT POSITION IN A WELL VENTILATED TRUCK.

SARA Title III Information:THE THRESHOLD PLANNING QUANTITY FOR THIS
MATERIAL IS 1000 LBS.
Federal Regulatory Information:OSHA: PROCESS SAFETY MANAGEMENT:
MATERIAL IS LISTED IN APPENDIX A OF 29 CFR 1910.119 AS HIGHLY
HAZARDOUS CHEMICAL. TSCA: MATERIAL IS LISTED IN TSCA INVENTORY. EU
NUMBER: 203-453-4. NUMBER IN ANNEX 1 O F DIR 67/548: MATERIAL IS
LISTED IN ANNEX 1. EU CLASSIFICATION: NOT AVAILABLE. R: 11, 25, 26,
34. S: 26, 36/37/39, 38, 45.
State Regulatory Information: