Product ID:UNADS
MSDS Date:02/28/1990
FSC:6810
NIIN:00N003994
Status Code:A
MSDS Number: CJYLM

Emergency Phone: 203-853-1400

Info Phone: 203-853-1400

Cage: 1N612

Telephone: 203-853-1400

Cage: 1N612

TETRAMETHYLTHIURAM MONOSULFIDE

CAS: 97-74-5

LD50 LC50 Mixture:LD50:(ORAL,RAT) 1,250-1,390 MG/KG & TOX.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:ACUTE: INGESTION OR INHALATION: LIABLE
TO PRODUCE UNPLEASANT SYMPTOMS IF ALCOHOL IS CONSUMED WITHIN HOURS
OF EXPOSURE (ANTABUSE EFFECT). INGESTION: HARMFUL IF SWALLOWED.
CHRONIC: SKIN: PROLONGED OR R EPEATED CONTACT MAY CAUSE SKIN
SENSITIZATION. SOME PEOPLE MAY DEVELOP AN ALLERGIC REACTION ON
REPEATED EXPOSURE.
Explanation of Carcinogenicity:NONE.
Effects of Overexposure:SEE HEALTH HAZARDS.
Medical Cond Aggravated by Exposure:UNKNOWN.

First Aid:EYES: FLUSH WITH WATER FOR AT LEAST 15 MINUTES. CONSULT MD.
SKIN: WASH WITH SOAP AND WATER. LAUNDER CONTAMINATED CLOTHING
BEFORE REUSE. INHALATION: EXPOSE TO FRESH AIR. KEEP WARM AND QUIET.
GIVE ARTIF ICIAL RESPIRATION IF NOT BREATHING. CONSULT MD.
INGESTION: SEEK MEDICAL ATTENTION IMMEDIATELY.

Flash Point Method:CC
Flash Point:=156.C, 312.8F
Extinguishing Media:CARBON DIOXIDE, FOAM, AND DRY CHEMICAL.
Fire Fighting Procedures:USE NIOSH APPROVED SCBA AND FULL PROTECTIVE
EQUIPMENT .
Unusual Fire/Explosion Hazard:NONE KNOWN. HMIS RATINGS: HEALTH - 1;
FLAMMABILITY - 1; REACTIVITY - 0.

Spill Release Procedures:SWEEP SPILLAGE AND TRANSFER TO A CLOSED
CONTAINER FOR DISPOSAL. WET DOWN RESIDUALS WITH SOAP AND WATER.

Handling and Storage Precautions:AVOID CONTACT WITH SKIN. AVOID
INHALATION OF DUST. USE WITH ADEQUATE VENTILATION. STORE IN A COOL,
DRY AREA.
Other Precautions:WARNING! HARMFUL IF SWALLOWED. MAY CAUSE SKIN
SENSITIZATION UPON REPEATED EXPOSURE.

Respiratory Protection:IF DUST CONTROL REQUIRED, USE NIOSH APPROVED
DUST RESPIRATOR.
Ventilation:EFFECTIVE EXHAUST TO DRAW DUST & VAPORS AWAY FROM WORKERS
TO PREVENT ROUTINE INHAL. IF LOCAL EXHAUST VENT IS USED, A CAPTURE
VELOCITY OF 150-200 FPM IS REC.
Protective Gloves:RUBBER GLOVES.
Eye Protection:ANSI APPROVED CHEMICAL WORKERS GOGGLES .
Other Protective Equipment:ANSI APPROVED EMERGENCY EYE WASH AND DELUGE
SHOWER .
Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING.
Supplemental Safety and Health
PHYSICAL AND CHEMICAL DATA: DENSITY: 1.38 MG/M3 @ 25C.

Spec Gravity:1.38 MG/M3 @ 25C
Solubility in Water:NEGLIGIBLE
Appearance and Odor:YELLOW POWDER.

Stability Indicator/Materials to Avoid:YES
STRONG ACIDS AND OXIDIZING AGENTS.
Hazardous Decomposition Products:TOXIC FUMES MAY BE EVOLVED, OXIDES OF
CARBON, NITROGEN, AND SULFUR AT COMBUSTION TEMPERATURES.
Conditions to Avoid Polymerization:WILL NOT OCCUR.

Waste Disposal Methods:DISPOSAL MUST BE I/A/W FEDERAL, STATE AND LOCAL
REGULATIONS . NOT CLASSIFIED AS A RCRA HAZARDOUS WASTE. DISPOSE OF
ACCORDING TO APPLICABLE ENVIRONMENTAL REGULATIONS.

Toxicological Information:ACUTE ORAL LDL0 500 MG/KG RATS, 100 MG/KG
DOGS, 100 MG/KG RABBITS AND 10 MG/KG GUINEA PIGS. EYE IRRITATION -
NOT IRRITATING TO EYES OF RABBITS. SKIN IRRITATION - MAY CAUSE SKIN
SENSITIZATION. INGESTIO N OR INHALATION OF THIS PRODUCT MAY CAUSE
UNPLEASANT SYMPTOMS IF ALCOHOL IS CONSUMED WITHIN HOURS OF EXPOSURE
(ANTABUSE EFFECT). AMES TEST SHOWS RELATIVELY LOW MUTAGENIC EFFECT.

SARA Title III Information:SARA TITLE III SECTION 313 INGREDIENT: NONE.
State Regulatory Information:

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.