CKBLC - CADOX M-50A
- MSDS: CKBLC
- Manufacturer: AKZO NOBEL CHEMICALS INC
- Product Name: CADOX M-50A
- National Stock Number: 6810-01-143-7185
Product Identification
Product ID:CADOX M-50A
MSDS Date:04/01/1999
FSC:6810
NIIN:01-143-7185
MSDS Number: CKBLC
Responsible Party
CHICAGO, IL 60606
US
Emergency Phone: 914-693-6946
Info Phone: 800-828-7929
Cage: 97854
Contractor
Telephone: 609-625-8101
Cage: 5U815
Ingredients
METHYL ETHYL KETONE PEROXIDE
CAS: 1338-23-4
RTECS: EL9450000
EPA Report Quantity: 10 LBS
DOT Report Quantity: 10 LBS
HYDROGEN PEROXIDE
CAS: 7722-84-1
RTECS: MX0899000
OSHA PEL 1.4 MG/M3;1 PPM
ACGIH TLV: 1.4 MG/M3;1 PPM
2,2,4-TRIMETHYLPENTANEDIOL-1,3-DIISOBUTYRATE
CAS: 6846-50-0
WATER
CAS: 7732-18-5
RTECS: ZC0110000
METHYL ETHYL KETONE
CAS: 78-93-3
RTECS: EL6475000
OSHA PEL 590 MG/M3;200 PPM
ACGIH TLV: 590 MG/M3;200 PPM
EPA Report Quantity: 5000 LBS
DOT Report Quantity: 5000 LBS
Hazards
Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:TARGET ORGANS: EYES, SKIN, RESPIRATORY
SYSTEM. ACUTE - INHALATION: VAPOR, MIST OR AEROSOL IS EXPECTED TO
BE SEVERELY IRRITATING TO RESPIRATORY TRACT. SKIN CONTACT: SKIN
CONTACT CAN CAUSE CHEMICAL BUR NS WITH SEVERE BLISTERING. EYE
CONTACT: DIRECT EYE CONTACT WITH THIS CHEMICAL CAN CAUSE AN
IMMEDIATE SEVERE REACTION AND MAY RESULT IN LOSS OF FUNCTIONAL
VISION IN THE INVOLVED EYE. USE OF FULLY PROTE CTIVE GOGGLES IS
ESSENTIAL WHEN USING THIS PRODUCT. INGESTION: IF SWALLOWED, THIS
MATERIAL CAN CAUSE SEVERE IRRITATION OR BURNS OF THE MOUTH, THROAT,
ESOPHAGUS AND STOMACH.
Explanation of Carcinogenicity:THIS PRODUCT IS NOT CLASSIFIED AS A
CARCINOGEN BY IARC, NTP, OSHA OR ACGIH.
Effects of Overexposure:SKIN CONTACT CAN CAUSE CHEMICAL BURNS WITH
SEVERE BLISTERING. IF SWALLOWED, THIS MATERIAL CAN CAUSE SEVERE
IRRITATION OR BURNS OF THE MOUTH, THROAT, ESOPHAGUS AND STOMACH.
Medical Cond Aggravated by Exposure:PERSONS WITH PRE-EXISTING SKIN
AND/OR RESPIRATORY DISEASE MAY BE AT INCREASED RISK IF EXPOSED TO
THIS PRODUCT.
First Aid
First Aid:INHALATION: REMOVE TO FRESH AIR. IF BREATHING IS DIFFICULT,
GIVE OXYGEN WITH A PHYSICIAN'S ADVICE. IF NOT BREATHING, GIVE
ARTIFICIAL RESPIRATION. GET MEDICAL ATTENTION. EYE CONTACT:
IMMEDIATELY FLUSH EYES WITH LARGE QUANTITIES OF RUNNING WATER FOR
A MINIMUM OF 15 MINUTES. HOLD EYELIDS APART DURING FLUSHING. DO NOT
NEUTRALIZE WITH CHEMICAL AGENTS. OBTAIN MEDICAL ATTENTION AS SOON
AS POSSIBLE. SKIN CONTACT: IMMEDIATELY REMOVE CONTAMINATED
CLOTHING AND SHOES. WASH SKIN WITH SOAP AND PLENTY OF WATER. DO NOT
NEUTRALIZE WITH CHEMICAL AGENTS. INGESTION: DO NOT INDUCE VOMITING.
CALL A PHYSICIAN IMMED IATELY. GIVE VICTIM PLENTY OF WATER.
Fire Fighting
Flash Point Method:SCC
Flash Point:=82.C, 179.6F
Autoignition Temp:Autoignition Temp Text:N/D
Lower Limits:N/D
Upper Limits:N/D
Extinguishing Media:USE WATER FOG, DRY CHEMICAL, CARBON DIOXIDE, OR
FOAM EXTINGUISHING AGENTS. EXTINGUISH LARGE FIRES WITH LARGE
AMOUNTS OF WATER SPRAY, FOG OR FOAM FROM A SAFE/PROTECTED POSITION.
Fire Fighting Procedures:AS IN ANY FIRE, PREVENT HUMAN EXPOSURE TO
FIRE, SMOKE, FUMES OR PRODUCTS OF COMBUSTION. EVACUATE
NON-ESSENTIAL PERSONNEL FORM THE FIRE AREA. FIREFIGHTERS SHOULD
WEAR FULL-FACE, SELF-CONTAINED BREATHIN G APPARATUS AND IMPERVIOUS
PROTECTIVE CLOTHING. IF POSSIBLE, MOVE CONTAINERS FROM THE FIRE
AREA.
Unusual Fire/Explosion Hazard:IF NOT LEAKING, KEEP FIRE EXPOSED
CONTAINERS COOL WITH A WATER FOG OR SPRAY TO PREVENT RUPTURE DUE TO
EXCESSIVE HEAT. HIGH PRESSURE WATER MAY SPREAD PRODUCT FROM BROKEN
CONTAINERS INCREASING CONTAMINA TION OR FIRE HAZARD.THIS IS A
COMBUSTIBLE LIQUID. DECOMPOSITIONPRODUCTS CAN IGNITE WITH EXPLOSIVE
FORCE.
Accidental Release
Spill Release Procedures:REMOVE ALL SOURCES OF IGNITION FROM SPILL
AREA. STOP SOURCE OF SPILL. USE NON-SPARKING TOOLS. DIKE AREA.
EVACUATE ALL NON-ESSENTIAL PERSONNEL UPWIND. WEAR A NIOSH-APPROVED,
POSITIVE PRESSURE SELF-CONT AINED BREATHING APPARATUS AND
PROTECTIVE EQUIPMENT. SOAK UP LIQUID WITH A SUITABLE ABSORBENT.
SWEEP UP ABSORBED MATERIAL AND PLACE IN A CHEMICAL WASTE CONTAINER
FOR DISPOSAL.
Handling
Handling and Storage Precautions:TO ENSURE PRODUCT QUALITY, STORAGE
TEMPERATURES SHOULD NOT EXCEED 86F (30C). TO PREVENT POSSIBLE
SELF-ACCELERATING DECOMPOSITION, TEMEPRATURES IN STORAGE FACILITY
MUST NOT EXCEED 131F (55C). KEEP CON TAINER TIGHTLY CLOSED. STORE
AWAY FROM AMINES, ACIDS, ALKALIS AND HEAVY METAL COMPOUNDS (METAL
SOAP)
Other Precautions:WEAR PROTECTIVE CLOTHING WHEN HANDLING PRODUCT. WASH
THOROUGHLY AFTER HANDLING. ELECTRICALLY GROUNDED TANKS AND
CONTAINERS SHOULD ALWAYS BE USED AS SHOULD NON-SPARKING,
ELECTRICALLY GROUNDED HAND TOOL S AND APPLIANCES. EMPTIED CONTAINER
MAY RETAIN PRODUCT RESIDUES. FOLLOW ALL WARNINGS EVEN AFTER CONT
AINER IS EMPTIED.
Exposure Controls
Respiratory Protection:USE A NIOSH-APPROVED ORGANIC VAPOR RESPIRATOR
WITH DUST, MIST AND FUME FILTERS TO REDUCE POTENTIAL FOR INHALATION
EXPOSURE IF USE CONDITIONS GENERATE VAPOR, MIST OR AEROSOL AND
ADEQUATE VENTILATION IS NOT AVAILABLE. WHERE EXPOSURE POTENTIAL
NECESSITATES A HIGHER LEVEL OF PROTECTION, USE A NIOSH-APPROVED,
POSITIVE PRESSURE AIR-SUPPLIED RESPIRATOR.
Ventilation:LOCAL EXHAUST VENTILATION, ENCLOSED SYSTEM DESIGN,
CONTINUOUS MONITORING DEVICES, PROCESS ISOLATION AND REMOTE CONTROL
ARE TECHNIQUES TO BE USED.
Protective Gloves:PERMEATION RESISTANT GLOVES.
Eye Protection:CHEMICAL GOGGLES AND/OR A FULL FACE SHIELD
Other Protective Equipment:PERMEATION RESISTANT CLOTHING, GLOVES AND
FOOTWARE. SAFETY SHOWERS AND EYE WASH FOUNTAINS AND QUICK OPENING
VALVES WHICH STAY OPEN.
Work Hygienic Practices:UNPROTECTED SKIN EXPOSED TO VAPOR, AEROSOL OR
MIST MUST BE THOROUGHLY WASHED BEFORE EATING, DRINKING, SMOKING AND
AT THE END OF THE WORKSHIFT.
Supplemental Safety and Health
DANGER! ORGANIC PEROXIDE. HEAT OR CONTAMINATION MAY CAUSE HAZARDOUS
DECOMPOSITION. CAUSES SEVERE EYE AND SKIN BURNS. CAUSES RESPIRATORY
TRACT IRRITAITON. COMBUSTIBLE LLIQUID AND VAPORS.
Chemical Properties
HCC:P1
Boiling Pt:B.P. Text:N/D
Melt/Freeze Pt:M.P/F.P Text:N/D
Vapor Pres:N/D
Vapor Density:N/D
Spec Gravity:1.0 @ 20 DEG C
pH:N/D
Evaporation Rate & Reference:N/D
Solubility in Water:N/D
Appearance and Odor:CLEAR, COLORLESS LIQUID WITH A FAINT KETONE ODOR.
Percent Volatiles by Volume:N/D
Stability
Stability Indicator/Materials to Avoid:YES
AVOID CONTACT WITH STRONG ACIDS, STRONG ALKALIS, STRONG OXIDIZERS,
ACCELERATORS AND REDUCING AGENTS.
Stability Condition to Avoid:THIS PRODUCT IS STABLE AT TEMPERATURES UP
TO 131 F. THE SELF-ACCELERATING DECOMPOSITION TEMPERATURE (SADT) IS
AN EXPERIMENTALLY DERIVED TEMPERATURE. THE SADT IS 140F (60C).
Hazardous Decomposition Products:DECOMPOSITION PRODUCTS INCLUDE CARBON
DIOXIDE, CARBON MONOXIDE, ETHANE AND METHANE.
Conditions to Avoid Polymerization:HAZARDOUS POLYMERIZATION IS NOT
EXPECTED TO OCCUR UNDER NORMAL TEMPERATURES AND PRESSURES.
Disposal
Waste Disposal Methods:THIS UNUSED PRODUCT IS LISTED BY EPA HAZADROUS
WASTE NUMBER U160 (MEKP) AND MEET EPA HAZARDOUS WASTE DEFINITION
FOR CHARACTERISTICS OF REACTIVITY (D003) AND CORROSIVITY (D002). IT
IS RESPONSIBILITY OF WASTE GENERATOR TO EVALUATE WHETHER WASTE
MEETS EPA'S DEFINITION OF HAZARDOUS WASTE BY CHARACTERIST IC OR
LISTING.
Toxicology
Toxicological Information:INHALATIO0N TOXICITY DATA IS NOT AVAILABLE
FOR THIS PRODUCT. DERMAL TOXICITY DATA IS NOT AVAILABLE FOR THIS
PRODUCT. THIS PRODUCT CAN BE EXPECTED TO BE CORROSIVE TO EYES BASED
UPON TEST WITH A SIMILAR PRODUCT. INGESTION TOXICITY DATA IS NOT
AVAILABLE FOR THIS PRODUCT. THIS PRODUCT IS NOT CLASSIFIED AS A
CARCINOGEN BY IARC, NTP OR OSHA OR ACGIH. THERE IS NO MUTAGENICITY
DATA FOR THIS PRODUCT. DEVEL OPMENT INHALATION TOXICITY STUDIES
WITH METHYL ETHYL KETONE IS RATS AND MICE RESULTED IN FETAL
TOXICITY AT MATERNALLY TOXIC DOSES.
Other Information
Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
Ecology
Ecological:CHEMICAL FATE: THIS PRODUCT IS EXPETCTED TO BE READILY
BIODEGRADABLE.
Transport
Transport Information:SHIPPING DESCRIPTION: ORGANIC PEROXIDE TYPE E,
LIQUID. (METHYL ETHYL KETONE PEROXIDE, <=40%) 5.2, UN3107, PG II.
NORTH AMERICAN EMERGENCY RESPONSE GUIDE NO.: 145. REQUIRED LABELS:
ORGANIC PEROXIDE. EN VIRONMENTAL HAZARDOUS SUBSTANCE: THIS PRODUCT
CONTAINS METHYL ETHYL KETONE PEROXIDE (RQ=10 LBS) WHICH IS AN
ENVIRONMENTALLY HAZARDOUS SUBSTANCE PER 49 CFR 172.1010, APPENDIX
A.
Regulatory
SARA Title III Information:SARA 302-LISTED. SARA 313-LISTED.
Federal Regulatory Information:TSCA-LISTED. CERCLA-CERCLA HAZARDOUS
SUBSTANCE.
State Regulatory Information:MASSACHUSETTES SUBSTANCE LIST, NEW JERSEY
R-T-K HAZARD SUBSTANCE, PENN. HAZARDOUS SUBSTANCE LIST.