Product ID:VANILLIN,104 3256
MSDS Date:04/02/1987
FSC:NIIN:Submitter:N EN
Status Code:A
MSDS Number: CKCDR

Emergency Phone: (800)424-9300

Info Phone: 800-227-6701

Cage: 038S2

Telephone: 800-227-6701

Cage: 038S2

VANILLIN

CAS: 121-33-5

RTECS: YW5775000

Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:INHALATION: LOW HAZARD FOR USUAL
INDUSTRIAL HANDLING. SKIN: LOW HAZARD FOR USUAL INDUSTRIAL
HANDLING. EYE: NO SPECIFIC HAZARD KNOWN. CONTACT MAY CAUSE
TRANSIENT IRRITATION. INGESTION: EXPECTED TO BE A LOW INGESTION
HAZARD. EXPOSURE LIMITS: NOT ESTABLISHED.
Effects of Overexposure:SEE HEALTH HAZARDS.

First Aid:INHALATION: REMOVE TO FRESH AIR FOLLOWING OVEREXPOSURE. SKIN:
WASH AFTER EACH CONTACT. EYE: FLUSH EYES WITH PLENTY OF WATER FOR
AT LEAST 15 MINUTES. INGESTION: DRINK 1-2 GLASSES OF WATER. SEEK
MEDICAL ATTENTION.

Extinguishing Media:WATER SPRAY; DRY CHEMICAL; CARBON DIOXIDE.
Fire Fighting Procedures:USE NIOSH APPROVED SCBA AND FULL PROTECTIVE
EQUIPMENT .
Unusual Fire/Explosion Hazard:THIS MATERIAL IN SUFFICIENT QUANTITY AND
REDUCED PARTICLE SIZE IS CAPABLE OF CREATING A DUST EXPLOSION.

Spill Release Procedures:SWEEP UP MATERIAL AND PACKAGE FOR SAFE FEED TO
AN INCINERATOR.

Handling and Storage Precautions:KEEP FROM CONTACT WITH OXIDIZING
MATERIALS.

Respiratory Protection:GOOD VENTILATION SHOULD BE SUFFICIENT.
SUPPLEMENTARY VENTILATION OR NIOSH APPROVED RESPIRATORY PROTECTION
MAY BE NEEDED IN SPECIAL CIRCUMSTANCES.
Ventilation:GOOD VENTILATION SHOULD BE SUFFICIENT. SUPPLEMENTARY
VENTILATION OR NIOSH APPROVED RESPIRATORY PROTECTION MAY BE NEEDED
IN SPECIAL CIRCUMSTANCES.
Protective Gloves:IMPERVIOUS GLOVES .
Eye Protection:ANSI APPROVED CHEMICAL WORKERS GOGGLES .
Other Protective Equipment:ANSI APPROVED EYE WASH AND DELUGE SHOWER .
IF PROLONGED OR REPEATED SKIN CONTACT IS NECESSARY, GLOVES OR OTHER
PROTECTION MAY BE REQUIRED.
Supplemental Safety and Health
PHYSICAL DATA - VOLATILE FRACTION BY WEIGHT: NEGLIGIBLE.

Melt/Freeze Pt:=83.C, 181.4F
Vapor Pres:NEGLIGIBLE
Spec Gravity:1.06 (H*2O=1)
Evaporation Rate & Reference:NEGLIG(N-BUTYL ACETATE=1)
Solubility in Water:SLIGHT (BY WEIGHT)
Appearance and Odor:WHITE CRYSTALLINE SOLID; VANILLA ODOR.

Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZERS.
Hazardous Decomposition Products:COMBUSTION WILL PRODUCE CARBON DIOXIDE
AND PROBABLY CARBON MONOXIDE.

Waste Disposal Methods:DISPOSE OBY INCINERATION OR CONTRACT WITH
LICENSED CHEMICAL WASTE DISPOSAL AGENCY. DISCHARGE, TREATMENT OR
DISPOSAL MAY BE SUBJECT TO FEDERAL, STATE AND LOCAL LAWS.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.

Ecological:ECOTOXICITY: NOT AVAILABLE. ENVIRONMENTAL FATE: NOT
AVAILABLE. PHYSICAL/CHEMICAL: NOT AVAILABLE. OTHER: NOT
AVAILABLE.

Transport Information:US DOT SHIPPING NAME: VANADIUM PENTOXIDE. HAZARD
CLASS: 6.1. UN NUMBER: UN2862. PACKING GROUP: II. IMO SHIPPING
NAME: VANADIUM PENTOXIDE. HAZARD CLASS: 6.1. UN NUMBER: 2862.
PACKING GROUP: II. IATA SH IPPING NAME: VANADIUM PENTOXIDE. HAZARD
CLASS: 6.1; UN NUMBER: 2862; PACKING GROUP: II. RID/ADR SHIPPING
NAME: VANADIUM PENTOXIDE; DANGEROUS GOODS CODE: 6.1 (58B); UN
NUMBER: 2862. CANADIAN TDG SHIPPI NG NAME: VANADIUM PENTOXIDE;
HAZARD CLASS: 6.1(9.2); UN NUMBER: UN2862.

SARA Title III Information:SECTION 302 (RQ) CAS# 1314-62-1: FINAL RQ =
1000 POUNDS (454 KG). SECTION 302 (TPQ) CAS# 1314-62-1: TPQ
=100/10,000 POUNDS; 1000 POUNDS. SARA CODES CAS#1314-62-1: ACUTE,
CHRONIC, FLAMMABLE. SECTION 31 3 NO CHEMICALS ARE REPORTABLE UNDER
SECTION 313. CLEAN AIR ACT: THIS MATERIAL DOES NOT CONTAIN ANY
HAZARDOUS AIR POLLUTANTS, CLASS 1 OZONE DEPLETORS OR CLASS 2 OZONE
DEPLETORS. CLEAN WATER ACT: CAS#14 14-62-1 IS LISTED AS A HAZARDOUS
SUBSTANCE UNDER THE CWA. NONE OF THE CHEMICALS IN THIS PRODUCT ARE
LISTED AS PRIORITY POLLUTANTS UNDER CWA. NONE OF THE CHEMICALS IN
THIS PRODUCT ARE LISTED AS TOXIC P OLLUTANTS UNDER CWA.
Federal Regulatory Information:TSCA CAS# 1314-62-1 IS LISTED ON TSCA
INVENTORY. HEALTH & SAFETY REPORTING LIST: NONE OF THE CHEMICALS
ARE ON THE HEALTH & SAFETY REPORTING LIST. CHEMICAL TEST RULES:
NONE OF THE CHEMICALS IN THIS PRO DUCT ARE UNDER A TEST RULE.
SECTION 12B: NONE OF THE CHEMICALS ARE LISTED UNDER TSCA SECTION
12B. TSCA SIGNIFICANT NEW USE RULE: NONE OF THE CHEMICALS IN THIS
MATERIAL HAVE A SNUR UNDER TSCA. OSHA: NO NE OF THE CHEMICALS IN
THIS PRODUCT ARE CONSIDERED HIGHLY HAZARDOUS BY OSHA. CLEAN AIR
ACT: THIS MAT ERIAL DOES NOT CONTAIN ANY HAZARDOUS AIR POLLUTANTS.
THIS MATERIAL DOES NOT CONTAIN ANY CLASS 1 OZONE DEPLETORS.
(OTHER INFORMATION)
State Regulatory Information:VANADIUM (V) OXIDE CAN BE FOUND ON THE
FOLLOWING STATE RIGHT TO KNOW LISTS: CALIFORNIA, NEW JERSEY,
FLORIDA, PENNSYLVANIA, MINNESOTA, MASSACHUSETTS. CALIFORNIA NO
SIGNIFICANT RISK LEVEL: NONE OF THE C HEMICALS IN THIS PRODUCT ARE
LISTED. EUROPEAN/INTERNATIONAL REGULATIONS: EUROPEAN LABELING IN
ACCORDANCE WITH EC DIRECTIVES - HAZARD SYMBOLS: XN. RISK PHRASES: R
20 HARMFUL BY INHALATION. SAFETY PHRA SES: S 22 DO NOT INHALE DUST.