Product ID:1-BUTANOL
MSDS Date:08/03/1998
FSC:NIIN:Submitter:D DG
MSDS Number: CKDCY

Emergency Phone: 800-227-1150

Info Phone: 800-227-1150

Cage: 59896

Telephone: 800-227-1150/910-584-0381

Cage: 59896

1-BUTANOL

CAS: 71-36-3

RTECS: EO1400000

OSHA PEL 300 MG/M3;100 PPM

EPA Report Quantity: 5000 LBS

DOT Report Quantity: 5000 LBS

LD50 LC50 Mixture:ORAL LD50(RAT): 790MG/KG
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Health Hazards Acute and Chronic:TARGET ORGANS: EYE, SKIN, KIDNEYS,
LIVER, RESPIRATORY SYSTEM. EYES-MAY CAUSE IRRITATION. SKIN-MAY
CAUSE IRRITATION. INGESTION-MAY CAUSE GASTROINTESTINAL DISCOMFORT.
INHALATION-MAY CAUSE IRRITATION T O RESPIRATORY TRACT.
Explanation of Carcinogenicity:NOT LISTED AS CAUSING CANCER BY NTP,
IARC, OR OSHA.
Medical Cond Aggravated by Exposure:EYE, SKIN, AND RESPIRATORY
DISORDERS.

First Aid:EYES: FLUSH WITH WATER FOR 15 MINUTES, RAISING & LOWERING
EYELIDS OCCASIONALLY. GET MEDICAL ATTENTION. SKIN: THOROUGHLY WASH
EXPOSED AREA FOR 15 MINUTES. REMOVE CONTAMINATED CLOTHING. LAUNDER
CONTAMIN ATED CLOTHING BEFORE RESUE. GET MEDICALATTENTION IF
IRRITATION PERSISTS. INGESTION: IF SWALLOWED, IF CONSCIOUS, GIVE
PLENTY OF WATER. IMMEDIATELY CALL A PHYSICIAN OR POISON CONTROL
CENTER. NEVER GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS PERSON.
INHALATION: REMOVE TO FRESH AIR. GIVE OXYGEN IF BREATHING IS
DIFFICULT; GIVE ARTIFICIAL RESPIRATION IF BREATHING HAS STOPPED.
KEEP PERSON WARM, QUIET, & GET MEDICAL ATTENTION.

Flash Point Method:TCC
Flash Point:=35.C, 95.F
Autoignition Temp:=342.C, 647.6F
Lower Limits:1.4
Upper Limits:11.2
Extinguishing Media:DRY CHEMICAL, CO2 OR APPROPRIATE FOAM.
Fire Fighting Procedures:FIREFIGHTERS SHOULD WEAR FULL PROTECTIVE
EQUIPMENT AND NIOSH APPROVED SELF-CONTAINED BREATHING APPARATUS.
Unusual Fire/Explosion Hazard:VAPOR CAN TRAVEL DISTANCES TO IGNITION
SOURCE AND FLASH BACK.

Spill Release Procedures:VENTILATE AREA OF SPILL. ELIMINATE ALL SOURCES
OF IGNITION. REMOVE ALL NON-ESSENTIAL PERSONNEL FROM AREA. CLEAN-UP
PERSONNEL SHOULD WEAR PROTECTIVE EQUIPMENT AND CLOTHING. ABSORB
MATERIAL WITH SUITABL E ABSORBANT AND CONTAINERIZE FOR DISPOSAL.

Handling and Storage Precautions:KEEP CONTAINER TIGHTLY CLOSED IN A
COOL AREA AWAY FROM IGNITION SOURCES AND OXIDIZERS. ELECTRICALLY
GROUND ALL EQUIPMENT WHEN HANDLING THIS EQUIPMENT.
Other Precautions:DO NOT BREATHE VAPORS.

Respiratory Protection:A NIOSH/MSHA CHEMICAL CARTRIDGE RESPIRATOR
SHOULD BE WORN IF PEL OR TLV IS EXCEEDED.
Ventilation:LOCAL EXHAUST: YES. MECHANICAL (GENERAL): YES.
Protective Gloves:RUBBER, NEOPRENE, PVC OR EQUIVALENT.
Eye Protection:SPLASH PROOF CHEMICAL SAFETY GOGGLES AT ALL TIMES.
Other Protective Equipment:LAB COAT, EYE WASH, AND SAFETY SHOWER.
Work Hygienic Practices:LAUNDER CONTAMINATED CLOTHING BEFORE RESUE.
Supplemental Safety and Health
PRODUCT CODES: 84-0490; 84-9790; 84-9792; 84-9794

HCC:F3
Boiling Pt:=118.C, 244.4F
Melt/Freeze Pt:=-89.C, -128.2F
Vapor Pres:4
Vapor Density:2.6
Spec Gravity:0.81
Evaporation Rate & Reference:0.46 (BUAC=1)
Solubility in Water:MODERATE 1-10%
Appearance and Odor:COLORLESS LIQUID WITH AN ALCOHOL ODOR.
Percent Volatiles by Volume:100

Stability Indicator/Materials to Avoid:YES
Stability Condition to Avoid:HEAT, FLAME, OTHER SOURCES OF IGNITION

Waste Disposal Methods:DISPOSE OF IN ACCORDANCE WITH LOCAL, STATE &
FEDERAL REGULATIONS. ALWAYS CONTACT A PERMITTED WASTE DISPOSER
(TSD) TO ASSURE COMPLIANCE.

Toxicological Information:ORAL-RAT LD50: 790 MG/KG. SKN-RBT LD50: 4200
MG/KG. IHL-HMN TCLO: 25 PPM.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.

Ecological:EPA WASTE NUMBERS: U031 (TOXIC WASTE).

Transport Information:DESCRIPTION: BUTANOLS, 3, UN1120, III.

SARA Title III Information:HAZARD CATEGORY FOR SARA SECTION 311/312
REPORTING: ACUTE. SARA SECTION 313 CHEMICALS NAME LIST: YES.
Federal Regulatory Information:EPA TSCA STATUS: ON TSCA INVENTORY.
CERCLA SEC. 103 RQ (LBS): 5000.