Product ID:P-NITROPHENOL
MSDS Date:05/14/1998
FSC:6810
NIIN:00-234-2013
Status Code:A
MSDS Number: CKDSL

Emergency Phone: 201-796-7100

Info Phone: 201-796-7100

Cage: 18464

Telephone: 201-796-7100

Cage: 18464

P-NITROPHENOL

CAS: 100-02-7

RTECS: SM2275000

EPA Report Quantity: 100 LBS

DOT Report Quantity: 100 LBS

LD50 LC50 Mixture:ORAL RAT LD50: 250 MG/KG.
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:EYES: CAUSES SEVERE IRRITATION. SKIN:
CAUSES SEVERE IRRITATION. IF ABSORBED. CAUSES SYMPTOMS SIMILAR TO
THOSE OF INGESTION. INHALATION: RESPIRATORY TRACT IRRITATION AND
EFFECTS SIMILAR TO INGESTION SY MPTOMS. INGESTION: HARMFUL IF
SWALLOWED. MAY CAUSE GASTROINTESTINAL TRACT IRRITATION, KIDNEY
DAMAGE, CENTRAL NERVOUS SYSTEM DEPRESSION, UNCONSCIOUSNESS, COMA,
POSSIBLE DEATH DUE TO RESPIRATORY FAILURE . MAY CAUSE
METHEMOGLOBINEMIA, CYANOSIS, CONVULSIONS, COLLAPSE, DEATH. TARGET
ORGANS: BLOOD, CENTRAL NERVOUS SYSTEM.
Explanation of Carcinogenicity:NOT LISTED BY ACGIH, IARC, NIOSH, NTP,
OR OSHA.
Effects of Overexposure:EYES: IRRITATION. SKIN: IRRITATION. IF
ABSORBED, SYMPTOMS SIMILAR TO INGESTION. INHALATION: RESPIRATORY
TRACT IRRITATION. SYMPTOMS SIMILAR TO INGESTION. INGESTION: GI
TRACT IRRITATION, NAUSEA, VOMITI NG, DIARRHEA, CNS DEPRESSION,
EXCITEMENT, HEADACHE, DIZZINESS, DROWSINESS, NAUSEA, COLLAPSE,
UNCONSCIOUSNESS, COMA, DEATH DUE TO RESPIRATORY FAILURE,
CONVULSIONS, DEATH, DIZZINESS, DROWSINESS, HEADAC HE, BREATH
SHORTNESS, BLUISH SKIN, RAPID HEART RATE, CHOCOLATE-BROWN COLORED
BLOOD, SHOCK.

First Aid:EYES: FLUSH WITH PLENTY OF WATER FOR AT LEAST 15 MINUTES,
OCCASIONALLY LIFTING UPPER AND LOWER LIDS. GET MEDICAL AID
IMMEDIATELY. SKIN: GET MEDICAL AID IMMEDIATELY. FLUSH WITH PLENTY
OF SOAP AND WA TER FOR AT LEAST 15 MINUTES WHILE REMOVING
CONTAMINATED CLOTHING AND SHOES. WASH CLOTHING BEFORE REUSE.
INHALATION: GET MEDICAL AID IMMEDIATELY. MOVE TO FRESH AIR
IMMEDIATELY. IF NOT BREATHING, GIVE ARTIFICIAL RESPIRATION. IF
BREATHING DIFFICULT, GIVE OXYGEN. INGESTION: IF CONSCIOUS AND
ALERT, GIVE 2-4 GLASSES OF WATER OR MILK. NEVER GIVE ANYTHING BY
MOUTH TO AN UNCONSCIOUS PERSON. GET MEDICAL HE LP IMMEDIATELY.

Flash Point:NOT AVAILABLE.
Autoignition Temp:=282.8C, 541.F
Extinguishing Media:IN CASE OF FIRE USE WATER SPRAY, DRY CHEMICAL,
CARBON DIOXIDE, OR CHEMICAL FOAM.
Fire Fighting Procedures:EVACUATE AREA AND FIGHT FIRE FROM A SAFE
DISTANCE. AS IN ANY FIRE, WEAR A SELF-CONTAINED BREATHING
APPARATUS IN PRESSURE-DEMAND, MSHA/NIOSH (APPROVED OR EQUIVALENT),
AND FULL PROTECTIVE GEAR.
Unusual Fire/Explosion Hazard:COMBUSTION GENERATES TOXIC FUMES.
CONTAINERS MAY EXPLODE IN THE HEAT OF A FIRE. COMBUSTIBLE
MATERIAL; EVEN THOUGH IT MAY TAKE SOME EFFORT TO IGNITE.

Spill Release Procedures:USE PROPER PERSONAL PROTECTIVE EQUIPMENT.
CLEAN UP SPILLS IMMEDIATELY, OBSERVING PRECAUTIONS IN THE
PROTECTIVE EQUIPMENT SECTION. SWEEP UP, THEN PLACE INTO A SUITABLE
CONTAINER FOR DISPOSAL. AVOID GENERATION DUSTY CONDITIONS.
REMOVE ALL SOURCES OF IGNITION. PROVIDE VENTILATION.

Handling and Storage Precautions:WASH AFTER HANDLING, USE WITH ADEQUATE
VENTILATION. MINIMIZE DUST GENERATION AND ACCUMULATION. AVOID
CONTACT WITH HEAT, SPARKS, FLAME. DO NOT INGEST OR INHALE. WASH
CLOTHING BEFORE REUSE. KEEP AWAY FR OM IGNITION SOURCES.
Other Precautions:STORE IN TIGHTLY CLOSED CONTAINER IN A COOL, DRY,
WELL VENTILATED AREA AWAY FROM INCOMPATABLE SUBSTANCES. KEEP AWAY
FROM FOOD, DRINKING WATER. KEEP FROM CONTACT WITH OXIDIZING
MATERIALS.

Respiratory Protection:FOLLOW OSHA RESPIRATOR REGULATIONS FOUND IN 29
CFR 1910.134 OR EUROPEAN STANDARD EN 149. ALWAYS USE A NIOSH OR
EUROPEAN STANDARD EN 149 APPROVED RESPIRATOR WHEN NECESSARY.
Ventilation:USE ADEQUATE VENTILATION TO KEEP AIRBORNE CONCENTRATIONS
LOW.
Protective Gloves:WEAR APPROPRIATE PROTECTIVE GLOVES TO PREVENT SKIN
EXPOSURE.
Eye Protection:SEE SUPPLEMENTAL SAFETY AND HEALTH FIELD.
Other Protective Equipment:WEAR APPROPRIATE PROTECTIVE CLOTHING TO
PREVENT SKIN EXPOSURE.
Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING. LAUNDER
CONTAMINATED CLOTHING BEFORE REUSE. MINIMIZE DUST GENERATION AND
ACCUMULATION.
Supplemental Safety and Health
WEAR APPROPRIATE PROTECTIVE EYEGLASSES OR CHEMICAL SAFETY GOGGLES AS
DESCRIBED BY OSHA'S EYE AND FACE PROTECTION REGULATIONS IN 29 CFR
1910.133 OR EUROPEAN STANDARD EN166.

HCC:T4
Boiling Pt:B.P. Text:DECOMPOSES (279C).
Melt/Freeze Pt:=113.4C, 236.1F
Decomp Temp:=279.C, 534.2F
Vapor Pres:.6MMHG @120 DEG
Vapor Density:4.8
Spec Gravity:1.479-1.495
Viscosity:NOT AVAILABLE
Evaporation Rate & Reference:NOT AVAILABLE
Solubility in Water:SLIGHTLY SOLUBLE IN WATER
Appearance and Odor:SOLID,YELLOW ,ODORLESS.

Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZING AGENTS, STRONG BASES, DIETHYL PHOSPHITE.
Stability Condition to Avoid:TEMPERATURES ABOVE 125C.
Hazardous Decomposition Products:NITROGEN OXIDES, CARBON MONOXIDE,
CARBON DIOXIDE.
Conditions to Avoid Polymerization:WILL NO OCCUR.

Waste Disposal Methods:DISPOSE OF IN A MANNER CONSISTENT WITH FEDERAL,
STATE, AND LOCAL REGULATIONS. RCRA U-SERIES: CAS# 100-02-7: WASTE
NUMBER U170. CAS# 100-02-7, P-NITROPHENOL IS BANNED FROM LAND
DISPOSAL ACCORDING TO R CRA.

Toxicological Information:P-NITROPHENOL, CAS# 100-02-7: ORAL MOUSE,
LD50: = 380 MG/KG. ORAL RAT, LD50:=250 MG/KG. CARCINOGENICITY: NOT
LISTED BY ACGIH, IARC, NIOSH, NTP, OR OSHA. EPIDEMIOLOGY: HUMAN
MUTATION DATA HAS BEEN REPO RTED. NO DATA AVAILABLE FOR:
TERATOGENICITY, REPRODUCTIVES EFFECTS, NEUROTOXICITY, MUTAGENICITY,
OTHER STUDIES.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.

Ecological:NO DATA AVAILABLE FOR: ECOTOXICITY, ENVIRONMENTAL FATE,
PHYSICAL/CHEMICAL, OTHER.

Transport Information:US D.O.T. SHIPPING NAME: NITROPHENOL, CLASS 6.1.
UN 1663, PKG I I I. NO INFORMATION AVAILABLE FOR IMO, IATA,
RID/ADR. CANADIAN TDG SHIPPING NAME: NITROPHENOLS, CLASS 6.1 (9.2),
UN 1663.

SARA Title III Information:SECTION 302 (RQ): CAS# 100-02-7: FINAL RQ =
100 POUNDS (45.4KG) (LISTED UNDER NITROPHE. SECTION 302 (TPQ): NONE
OF THE CHEMICALS IN THIS PRODICT HAVE A TPQ. SARA CODES: CAS#
100-02-7: ACUTE, CHRONIC, REACTIVE. SECTION 313: THIS MATERIAL
CONTAINS P-NITROPHENOL (CAS# 100-02-7, 98%), WHICH IS SUBJECT TO
THE REPORTING REQUIREMENTS OF SECTION 313 OF SARA TITLE I I I AND
40 CFR PART 373. CLEAN AIR ACT: CAS# 100-02-7 IS LISTED AS A
HAZARDOUS AIR POLLUTANT (HAP). THIS MATERIAL DOES NOT CONTAINANY
CLASS 1 OZONE DEPLETORS. THIS MATERIAL DOES NOT CONTAIN ANY CLASS 2
OZONE DEPLETORS. CONT'D IN "OTHER INFO RMATION"
Federal Regulatory Information:TSCA: CAS# 100-02-7 IS LISTED ON THE
TSCA INVENTORY. HEALTH AND SAFETY REPORTING LIST: CAS# 100-02-7:
EFFECTIVE DATE: APRIL 13, 1989; SUNSET DATE: JUNE 30,1998. CHEMICAL
TEST RULES: NONE OF THE CHEMIC ALS IN THIS PRODUCT ARE UNDER A
CHEMICAL TEST RULE. SECTION 12B: CAS# 100-02-7: EXPORT NOTIFICATION
REQUIRED - SECTION 4. TSCA SIGNIFICANT NEW USE RULE: NONE OF THE
CHEMICALS IN THIS MATERIAL HAVE A S NUR UNDER TSCA.VG
State Regulatory Information:P-NITROPHENOL CAN BE FOUND ON THE
FOLLOWING STATE RIGHT TO KNOW LISTS: CALIFORNIA, NEW JERSEY,
FLORIDA, PENNSYLVANIA, MASSACHUSETTS. CALIFORNIA, NO SIGNIFICANT
RISK LEVEL. NONE OF THE CHEMICALS IN THI S PRODUCT ARE LISTED.
EUROPEAN/INTERNATIONAL REGULATIONS:EUROPEAN LABELING IN ACCORDANCE
WITH EC DIRECTIVES: HAZARD SYMBOLS: XN. RISK PHRASES: R 20/21/22
HARMFUL BY INHALATION, INCONTACT WITH SKIN AND IF SWALLOWED. R 33
DANGER OF CUMULATIVE EFFECTS. SAFETY PHRASES: S 28 AFTER CONTACT
WITH SKIN, WAS H IMMEDIATELY WITH PLENTY OF?.(TO BE SPECIFIED BY
THE MANUFACTURER). WGK (WATER DANGER/PROTECTION) CAS# 100-02-7: 2.