Product ID:A407-4, ETHYL ALCOHOL, DENATURED (A407)
MSDS Date:10/17/1997
FSC:6810
NIIN:01-447-4950
Status Code:A
MSDS Number: CKMMG

FISHER SCIENTIFIC CO. CHEMICAL MFG DIV

1 REAGENT LANE
FAIR LAWN, NJ 07410-2802
US

Emergency Phone: (800)424-9300

Info Phone: 201-796-7100

Cage: 1B464

FISHER SCIENTIFIC CO. CHEMICAL MFG DIV

FAIRLAWN, NJ 07410-2802 US

Telephone: 201-796-7100

Cage: 1B464

ETHYL ALCOHOL

CAS: 64-17-5

RTECS: KQ6300000

OSHA PEL 1900 MG/M3;1000 PPM

ACGIH TLV: 1880 MG/M3;1000 PPM

METHYL ALCOHOL

CAS: 67-56-1

RTECS: PC1400000

OSHA PEL 260 MG/M3;200 PPM

ACGIH TLV: 262 MG/M3;200 PPM

EPA Report Quantity: 5000 LBS

DOT Report Quantity: 5000 LBS

ISOPROPYL ALCOHOL

CAS: 67-63-0

RTECS: NT8050000

Fraction By Weight: 25% PPM

OSHA PEL 980 MG/M3;400 PPM

ACGIH TLV: 983 MG/M3;400 PPM

ACETONE

CAS: 67-64-1

RTECS: AL3150000

Fraction By Weight: 2% PPM

OSHA PEL 2400 MG/M3;1000 PPM

ACGIH TLV: 1780 MG/M3;750 PPM

EPA Report Quantity: 5000 LBS

DOT Report Quantity: 5000 LBS

BENZENE

CAS: 71-43-2

RTECS: CY1400000

Fraction By Weight: TRACE

OSHA PEL see 1910.1028

ACGIH TLV: 32 MG/M3;10 PPM

EPA Report Quantity: 10 LBS

DOT Report Quantity: 10 LBS

ACETALDEHYDE

CAS: 75-07-0

RTECS: AB1925000

Fraction By Weight: 10% PPM

OSHA PEL 360 MG/M3;200 PPM

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

METHYL ISOBUTYL KETONE

CAS: 108-10-1

RTECS: SA9275000

OSHA PEL 410 MG/M3;100 PPM

ACGIH TLV: 205 MG/M3;50 PPM

EPA Report Quantity: 5000 LBS

DOT Report Quantity: 5000 LBS

TOLUENE

CAS: 108-88-3

RTECS: XS5250000

OSHA PEL see Table Z-2

ACGIH TLV: 188 MG/M3;50 PPM

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

ETHYL ACETATE

CAS: 141-78-6

RTECS: AH5425000

OSHA PEL 1400 MG/M3;400 PPM

ACGIH TLV: 1440 MG/M3;400 PPM

EPA Report Quantity: 5000 LBS

DOT Report Quantity: 5000 LBS

WATER

CAS: 7732-18-5

RTECS: ZC0110000

LIGHT ALIPHATIC SOLVENT NAPHTHA (PETROLEUM)

CAS: 64742-89-8

LD50 LC50 Mixture:NOT GIVEN FOR PRODUCT AS A WHOLE.
Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:YES
Health Hazards Acute and Chronic:MAY CAUSE SKIN IRRITATION. MAY BE
FATAL IF SWALLOWED. MAY CAUSE CENTRAL NERVOUS SYSTEM DEPRESSION.
MAY BE ABSORBED THROUGH THE SKIN. MAY CAUSE BLINDNESS IF
SWALLOWED.CAUSES SEVERE EYE IRRITATION. MAY CAUSE LIVER AND KIDNEY
DAMAGE. MAY CAUSE REPRODUCTIVE AND FETAL EFFECTS.
Explanation of Carcinogenicity:CAS# 71-43-2: ACGIH: A1-CONFIRMED HUMAN
CARCINOGEN; CALIFORNIA: CARCINOGEN - INITIAL DATE 2/27/87; NIOSH :
OCCUPATIONAL CARCINOGEN; NTP: KNOWN CARCINOGEN; OSHA POSSIBLE SELCT
CARCINOGEN; IARC: GROUP 1 CARCINOGEN.
Effects of Overexposure:EYES: IRRITATION, BURNING SENSATION, REDNESS,
TEARING, INFLAMMATION, CORNEAL INJURY. SKIN: IRRITATION, DEFATTING
OF SKIN, DERMATITIS. IINGESTION: BLINDNESS, DEATH, SYSTEMIC
TOXICITY WITH ACIDOSIS, LIV ER & KIDNEY DAMAGE, CNS DEPRESSION,
EXCITEMENT, HEADACHE, DIZZINESS, DROWSINESS, NAUSEA, COLLAPSE,
UNCONSCIOUSNESS, COMA. INHALATION: CNS EFFECTS, HEADACHE,
DIZZINESS, UNCONSCIOUSNESS, COMA, RESPIRATO RY TRACT IRRITATION,
DROWSINESS, UNCONSCIOUSNESS, CNS DEPRESSION.
Medical Cond Aggravated by Exposure:NO DATA PROVIDED BY RESPONSIBLE
PARTY

First Aid:EYES: IMMEDIATELY FLUSH WITH PLENTY OF WATER FOR AT LEAST 15
MINUTES, OCCASIONALLY LIFTING LIDS. GET MEDICAL AID IMMEDIATELY.
SKIN: GET MEDICAL AID. IMMEDIATELY FLUSH WITH PLENTY OF SOAP AND
WATER FOR AT LEAST 15 MINUTES WHILE REMOVING CONTAMINATED CLOTHING
AND SHOES. INGESTION: IF VICTIM IS CONSCIOUS AND ALERT, GIVE 2-4
CUPFULS OF MILK OR WATER. NEVER GIVE ANYTHING BY MOUTH TO AN
UNCONSCIOUSS PER SON. GET MEDICAL AID. INDUCE VOMITING BY GIVING 1
TEASPOON SYRUP OF IPECAC. INHALATION: GET MEDICAL AID IMMEDIATELY.
REMOVE TO FRESH AIR IMMEDIATELY. IF NOT BREATHING GIVE ARTIFICIAL
RESPIRATION. IF B REATHING DIFFICULT, GIVE OXYGEN.

Flash Point:=13.9C, 57.F
Autoignition Temp:=362.8C, 685.F
Lower Limits:3.3
Upper Limits:19
Extinguishing Media:FIRE: USE WATER, DRY CHEMICAL, CHEMICAL FOAM,
ALCOHOL-RESISTANT-FOAM. DO NOT USE STRAIGHT STREAMS OF WATER. LARGE
FIRE: DRY CHEMICAL, CARBON DIOXIDE, ALCOHOL-RESISTANT FOAM.
Fire Fighting Procedures:WEAR SELF-CONTAINED BREATHING APPARATUS IN
PRESSURE-DEMAND, MSHA/NIOSH (APPROVED OR EQUIVALENT) AND FULL
PROTECTIVE GEAR. USE WATER SPRAY TO COOL FIRE-EXPOSED CONTAINERS.
Unusual Fire/Explosion Hazard:VAPORS MAY FORM AN EXPLOSIVE MIXTURE WITH
AIR. VAPORS CAN TRAVEL TO A SOURCE OF IGNITION AND FLASSH BACK. USE
WATER SPRAY TO KEEP FIRE-EXPOSED CONTAINERS COOL. CONTAINERS MAY
EXPLODE IN HEAT OF FIRE. FLAMMABLE LIQUID. MAY FORM EXPLOSIVE
PEROXIDES. VAPORS ARE HEAVIER THAN AIR.

Spill Release Procedures:USE PROPER PERSONAL PROTECTIVE EQUIPMENT.
ABSORB SPILL WITH INERT MATERIAL ( E.G. DRY SAND OR EARTH), THEN
PLACE INTO A CHEMICAL WASTE CONTAINER. REMOVE ALL SOURCES OF
IGNITION. A VAPOR SUPPRESSING F OAM MAY BE USED TO REDUCE VAPORS.
Neutralizing Agent:NO DATA PROVIDED BY RESPONSIBLE PARTY

Handling and Storage Precautions:WASH THOROUGHLY AFTER HANDLING. USE
WITH ADEQUATE VENTILATION. GROUND AND BOND CONTAINERS WHEN
TRANSFERRING MATERIAL. AVOID CONTACT WITH EYES, SKIN AND CLOTHING.
EMPTY CONTAINERS RETAIN PRODUCT RESIDU E AND CAN BE DANGEROUS. KEEP
CONTAINER TIGHTLY CLOSED.AVOID CONTACT WITH HEAT, SPARKS AND FLAME.
Other Precautions:DO NOT PRESSURIZE, CUT, WELD, BRAZE, SOLDER, DRILL,
GRIND OR EXPOSE EMPTY CONTAINERS TO HEAT SPARKS OR OPEN FLAMES.
STORAGE: KEEP AWAY FROM HEAT, SPARKS AND FLAME. KEEP AWAY FROM
SOURCES OF IGNITION. STORE IN A TIGHTLY CLOSED CONTAINER. STORE IN
A COOL, DRY, WELL-VENTILATED AREA AWAY FROM INCOMPATIB LE
SUBSTANCES.

Respiratory Protection:FOLLOW THE OSHA RESPIRATOR REGULATIONS FOUND IN
29 CFR 1910.134 OR EUROPEAN STANDARD EN 149. ALWAYS USE A NIOSH OR
EUROPEAN STANDARD EN 149 APPROVED RESPIRATOR.
Ventilation:USE ADEQUATE GENERAL OR LOCAL EXHAUST VNTILATION TO KEEP
AIRBORNE CONCENTRATIONS BELOW THE PERMISSABLE EXPOSURE LIMITS.
Protective Gloves:APPROPRIATE PROTECTIVE GLOVES TO PREVENT SKIN
EXPOSURE.
Eye Protection:APPROPRIATE PROTECTIVE EYEGLASSES OR CHEMICAL SAFETY
GOGGLES (29 CFR 1910.133).
Other Protective Equipment:WEAR APPROPRIATE PROTECTIVE CLOTHING TO
PREVENT SKIN EXPOSURE.
Work Hygienic Practices:WASH THOROUGHTLY AFTER HANDLING.
Supplemental Safety and Health
ADDITIONAL US REGULATORY, TOXICOLOGICAL AND INTERNATIONAL REGULATORY
INFORMATION IS AVAILABLE FROM DARTVIEW IMAGE OF MSDS AVAILABLE AT
DSCR.

HCC:F2
Boiling Pt:=78.5C, 173.3F
Melt/Freeze Pt:=-90.C, -130.F
Decomp Temp:Decomp Text:NOT AVAILABLE
Vapor Pres:25 MM HG
Vapor Density:1.6
Spec Gravity:0.7905
pH:NO DATA
Viscosity:NOT AVAILABLE
Solubility in Water:SOLUBLE IN WATER
Appearance and Odor:CLEAR, COLORLESS LIQUID; AROMATIC ODOR.

Stability Indicator/Materials to Avoid:YES
NON-OXIDIZING MINERAL ACIDS; OXIDIZING MINERAL ACIDS; ORGANIC ACIDS;
AZO, DIAZO HYDRAZINES; ISOCYANATES; METALS; NITRIDES; PEROXIDES &
HYDROPEROXIDES; EPOXIDES; OXIDIZING AGENTS; REDUCING AGENTS; WATER
REACTIVE SUBSTANCES.
Stability Condition to Avoid:THIS MATERIAL MAY BE SENSITIVE TO PEROXIDE
FORMATION, INCOMPATIBLE MATERIALS, IGNITION SOURCES.
Hazardous Decomposition Products:CARBON MONOXIDE, CARBON DIOXIDE.
Conditions to Avoid Polymerization:HAS NOT BEEN REPORTED.

Waste Disposal Methods:DISPOSE OF IN ACCORDANCE WITH LOCAL, STATE &
FEDERAL REGULATIONS. RCRAA D-SERIES MAXIMUM CONCENTRATION OF
CONTAMINANTS: CAS# 71-43-2: WASTE NUMBER D018; REGULATORY LEVEL =
0.5 MG/L. RCRA D-SERIES CHRO NIC TOXICITY REFERENCE LEVELS: CAS #
71-43-2: CHRONIC TOXICITY REFERENCE LEVEL = 0.005 MG/L. RCRA F OR
P SERIES: NONE LISTED.

Toxicological Information:LD50/LC50:CAS# 64-17-5:ORAL, RAT LD50=5628
MG/KG; CAS# 67-63-0:ORAL, RAT LD50=5045 MG/KG; CAS# 67-64-1:ORAL,
RAT LD50=5800 MG/KG; CAS# 71-43-2:ORAL, RAT LD50=930 MG/KG; CAS#
75-07-0:ORAL, RAT LD50=661 MG/KG; CAS# 108-10-1:ORAL, RAT
LD50=2080 MG/KG; CAS# 108-88-3:ORAL, RAT LD50=636 MG/KG; CAS#
141-78-6:ORAL, RAT=5620 MG/KG; CAS# 7732-18-5:ORAL, RAT LD50= >90
ML/KG; CAS# 64742-89-8: NO DATA GIVEN. E PIDEMIOLOGY:NO DATA
AVAILABLE. TERATOGENICITY:NO DATA AVAILABLE. OTHER STUDIES:NO DATA
AVAILABLE.REPRODUCTIVE:PRENATAL EXPOSURE TO ETHANOL IS ASSOCIATED
WITH A DISTINCT PATTERN OF CONGENITAL MALFORMAT IONS TERMED FETAL
ALCOHOL SYNDROM.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.

Ecological:ECOTOXICITY: 250 PPM/6HR/GOLDFISH/LETHAL/FRESH AIR.
ENVIRONMENTAL FATE: ETHANOL: IN WATER, WILL VOLITILIZE AND PROBABLY
DEGRADE. PHYSICA/CHEMICAL: NOT AVAILABLE. OTHER: NOT EXPECTED TO
BIOCONCENTRATE IN FISH.

Transport Information:SHIPPING NAME: US DOT: ETHANOL SOLUTIONS, HAZARD
CLASS: 3, UN NUMBER: UN1170, PACKING GROUP: II; IATA:NO INFORMATION
AVAILABLE; RID/ADR: NO INFORMATION AVAILABLE; IMO:NO INFORMATION
AVAILABLE; CANADA TDG: ALCOHOLS TOXIC NOS (ETHANOL, METHANOL
MIXTURE), CLASS: 3, 6.1, UN NUMBER: UN 1986, PACKING GROUP: II,
ADDITIONAL INFO: FLASH POINT: 18C.

SARA Title III Information:SARA 302 (RQ): ALL INGREDIENTS EXCEPT FOR
THE FOLLOWING HAVE AN RQ OF 5000 LBS (2270 KG): CAS# 71043-2: 10
LBS (4.54 KG); CAS# 75-07-0/CAS# 108-88-3: 1000 LBS; SECTION 302
(TPQ): NONE OF THE CHEMICAL S IN THIS PRODUCT HAVE A TPQ. SECTION
313: THIS MATERIAL CONTAINS METHANOL (CAS# 67-56-1, 6%) WHICH IS
SUBJECT THE REPORTING REQUIREMENTS OF SECTION 313 AND 40 CFR PART
373. THIS MATERIAL CONTAINS AC ETALDEHYDE (CAS# 75-07-0, 10%) WHICH
IS SUBJECT THE REPORTING REQUIREMENTS OF SECTION 313 AND 40 CFR
PART 373.
Federal Regulatory Information:CLEAN AIR ACT:CAS# 67-56-1 IS LISTED AS
A HAZARDOUS AIR POLLUTANT (HAP).CAS# 75-07-0 IS LISTED AS A
HAZARDOUS AIR POLLUTANT (HAP).CAS#108-10-1 IS LISTED AS A HAZARDOUS
AIR POLLUTANT (HAP).CAS# 108-88- 3 IS LISTED AS A HAZARDOUS AIR
POLLUTANT(HAP).THIS MATERIAL DOES NOT CONTAIN ANY CLASS 1 OR CLASS
2 OZONE DEPLETORS.CLEAN WATER ACT:CAS# 71-43-2 IS LISTED AS A
HAZARDOUS SUBSTANCE UNDER THE CWA.CAS# 7 5-07-0 IS LISTED AS A
HAZARDOUS SUBSTANCE UNDER THE CWA.CAS# 71-43-2 IS LISTED AS A
PRIMARY POLLUTAN T UNDER THE CWA.CAS# 108-88-3 IS LISTED AS A
PRIMARY POLLUTANT UNDER THE CWACAS# 71-43-2 IS LISTED AS A PTOXIC
POLLUTANT UNDER THE CWA.
State Regulatory Information:CAS NUMBERS
64-17-5,67-56-1,67-63-0,67-64-1,71-43-2,
75-07-0,108-10-1,108-88-3,141-78-6 ARE FOUND ON THE FOLLOWING STATE
R-T-K LISTS:CA, NJ, FL, PA, MN, MA. CAS NUMBERS 7732-18-5 &
64742-89-8 ARE NOT FOUND ON STATE LISTS FROM CA, PA, MN, MA, FL OR
NJ. WARNING:THIS PRODUCT CONTAINS BENZENE, A CHEMICAL KNOWN TO THE
STATE OF CALIFORNIA TO CAUSE CANCER & BIRTH DEFECTS OR OTHER
REPRODUCTIVE HARM. WARNI NG: THIS PRODUCT CONTAINS ACETALDEHYDE, A
CHEMICAL KNOWN TO THE STATE OF CALIFORNIA TO CAUSE CANCER.
WARNING: THIS PRODUCT CONTAINS ETHYL ALCOHOL, A CHEMICAL KNOWN TO
THE STATE OF CALIFORNIA TO CAUSE BIRTH DEFECTS & OTHER REPRODUCTIVE
HARM