Product ID:RISTON 9000D SERIES PHOTOPOLYMER FILMS VAPORS
MSDS Date:10/27/1994
FSC:NIIN:Submitter:F BT
Status Code:A
MSDS Number: CKSBW

E.I. DUPONT DE NEMOURS & CO (INC)

1007 MARKET STREET
WILMINGTON, DE 19898
US

Emergency Phone: 1-800-441-3637

Info Phone: 800-441-7515

Cage: 18873

E.I. DUPONT DE NEMOURS & CO

WILMINGTON, DE 19898 US

Telephone: 800-441-7515;800-441-9442

Cage: 18873

BENZOPHENONE

CAS: 119-61-9

RTECS: DI9950000

HYDROXY ETHYL ACRYLATE

CAS: 818-61-1

RTECS: AT1750000

UNKNOWN ACRYLATES

DIHYDRO - 4,4 - DIMETHYL -2 (3H) - FURANONE

CAS: 13861-97-7

METHYL - 4 - (TRICHOROMETHYL) - 2, - CYCLOHEXADIENONE

CAS: 3274-12-2

ETHYL 4-(DIMETHYLAMINO)BENZOATE

CAS: 10287-53-3

2 - OXEPHANONE

CAS: 502-44-3

UNKNOWN HYDROCARBONS

POLYOL ACRYLATE MONOMER

Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO
Health Hazards Acute and Chronic:CONTROL OF RESIST VAPORS WITH A DUPONT
LAMINATOR THAT IS INSTALLED, OPERATED AND MAINTAINED IN ACCORDANCE
WITH PUBLISHED INSTRUCTIONS ASSURES THAT AIRBORN CONCENTRATIONS
WILL BE MAINTAINED AT EXTREMEL Y LOW LEVELS AND CAPABLE OF
PROVIDING A SAFE ENVIRIONMENT FOR WORKERS. OTHER LAMINATORS AND
DESIGNS SHOULD BE TESTED FOR THE ADEQUACY OF VENTILATION. SKIN:
IRRITATION WITH DISCOMFORT OR RASH, OR ALLER GIC SKIN RASHES. EYE:
IRRITATION WITH DISCOMFORT, TEARING, OR BLURRING OF VISION.
INHALATION: IRRITATION TO UPPER REPIRATORY PASSAGES WITH COUGHING
AND DISCOMFORT.
Effects of Overexposure:PROLONGED INHALTION OF VAPROS MAY PRODUCE
NONSPECIFIC DISCOMFORT, SUCH AS NAUSEA, HEADACHE, OR WEAKNESS, OR
TEMPORARY NERVOUS SYSTEM DEPRESSION WITH ANAESTHETIC EFFECTS SUCH
AS DIZZINESS, HEADACHE, CO NFUSTION AND INCOORDINATION. CONDENSATE
WILL CONTAIN HIGHER % OF LESS VOLATILE COMPONENTS INCLUDING POLYOL
ACRYLATE MONOMERS WHICH MAY CAUSE DELAYED SKIN BURNS AND MAY CAUSE
SKIN SENSITIZATION. AVOID CONTACT WITH EYE, SKIN, CLOTHING,
BREATHING MIST/VAPORS.

Extinguishing Media:DRY CHEMICAL, FOAM, CARBON DIOXIDE
Fire Fighting Procedures:WEAR SELF CONTAINED BREATHING APPARATUS
Unusual Fire/Explosion Hazard:THERMAL DECOMPOSITION CAN LEAD TO
EVOLUTION OR IRRITATING VAPORS OR GASES

Spill Release Procedures:USE APPROPRIATE PERSONAL PROTECTIVE EQUIPMENT
DURING CLEAN-UP. FOR CONDENSATE, SOAK UP WITH INERT ABSORBANT
MATERIAL AND PLACE IN WASTE CONTAINER FOR DISPOSAL

Handling and Storage Precautions:AVOID BREATHING VAPORS OR MIST. AVOID
CONTACT WITH EYES, SKIN, OR CLOTHING. WASH THOROUGHLY AFTER
HANDLING
Other Precautions:LAMINATORS USED TO APPLY RISTON (R) FILM SHOULD BE
DESIGNED W/ ADEQUATE VENTILATION TO EXHAUST VAPOR FROM WORKPLACE.
VAPOR MAY CONDENSE ON COLD SURFACE NEAR AREA WHERE FILM IS HEATED/
LAMINATOR EXHAU ST DUCT. CHECK SURFACES FOR CONDENSATE BUILD-UP.
CLEAN OFTEN W/ CLOTH BARELY MOISTENED W/ISOPROPYL A LCOHOL

Respiratory Protection:SELF CONTAINED BREATHING APPARATUS FOR FIRE
FIGHTING AND MIST OR SPRAY EXPOSURES IF NECESSARY
Ventilation:USE SUFFICIENT EXHAUST ON LAMINATORS TO KEEP EXPOSURES
BELOW REC LIMITS. LAMINATOR TEMPERATURE SHOULD BE MAINTEINED BELOW
125 C TO MINIMIZE VAPOR GENERATION
Protective Gloves:NEOPRENE, DECONTAMINATE BY WASHING WITH SOAP AND
WATER BEFORE REMOVING GLOVES
Supplemental Safety and Health
THE CONCENTRATIONS SHOWN IN THE INGREDIENTS ARE BASED ON GC/MS ANALYSES
OF FILM VAPORS. THE QUANTITY OF VAPORS IS ESTIMATED TO BE 10-30
POUNDS/MILLION FT2 OF RESIST FILM. VAPORS ARE NORMALLY COLORLESS ,
BUT MAY APPEAR AS WHITE SMOKE IN ABSENCE OF EXHAUST VENTILATION.
VAPORS MAY CONDENSE AS CLEAR YELLOW LIQUID

Evaporation Rate & Reference:<1 (BUTYL ACETATE=1)
Solubility in Water:INSOLUBLE
Appearance and Odor:MILD ACRYLATE ODOR, VAPORS NORMALLY COLORLESS

NONE
Hazardous Decomposition Products:CARBON MONOXIDE, CARBON DIOXIDE AND
OXIDATION INTERMEDIATES FOR INCOMPLETE COMBUSTION OR BURNING

Waste Disposal Methods:WHEN REQUIRED, VAPOR DISCHARGE TO ATMOSPHERE
SHOULD BE PROPERLY PERMITTED

Toxicological Information:BENZOPHENONE-SKIN ABSORPTION LD50:3535MG/KG
IN RABBITS. MAY CAUSE SKIN/EYE/NOSE/THROAT IRRITATION. SKIN CONTACT
MAY CAUSE RASH. SKIN PERMEATION MAY OCCUR IN TOXIC AMOUNTS. HYDROXY
ETHYL ACRYLATE-SKIN ABSORBTION LD50: 154MG/KG IN RABBITS. IRRITATE
NOSE/THROAT AS VAPOR/MIST. SEVERLY IRRITATING TO SKIN AND EYE WITH
CORNEAL INJURY POSSIBLE PERMANENT INJURY.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.

Ecological:NOT PROVIDED

Transport Information:NOT PROVIDED

SARA Title III Information:NOT UNDER CLASS I OR II OZONE DEPLETING
SUBSTANCES
State Regulatory Information: