Product ID:KROVAR I DF HERBICIDE
MSDS Date:06/17/1998
FSC:6840
NIIN:00-001-7710
Status Code:A
MSDS Number: CKVHS

E.I. DUPONT DE NEMOURS & CO (INC)

1007 MARKET STREET
WILMINGTON, DE 19898
US

Emergency Phone: (800)424-9300

Info Phone: 800-441-7515

Cage: 18873

TIMBERLAND ENTERPRISES INC

557 MONTICELLO, AR 71655 US

Telephone: 501-367-8561

Cage: 1HB45

BROMACIL (5-BROMO-3-SEC-BUTYL-6-METHYLURACIL)

CAS: 314-40-9

RTECS: YQ9100000

ACGIH TLV: 10 MG/M3, 8HR TWA

DIURON (3-(3,4-DICHLOROPHENYL)-1,1-DIMETHYLUREA)

CAS: 330-54-1

RTECS: YS8925000

ACGIH TLV: 10 MG/M3

EPA Report Quantity: 100 LBS

DOT Report Quantity: 100 LBS

LD50 LC50 Mixture:ORAL RAT LD50 >2,500 MG/KG
Reports of Carcinogenicity:NTP:NO IARC:UNKNOWN OSHA:NO
Health Hazards Acute and Chronic:BROMOCIL: SKIN CONTACT MAY INITIALLY
CAUSE IRRITATION OR RASH. EYE CONTACT MAY INITIALLY INCLUDE
IRRITATION, TEARING OR BLURRING OF VISION. SIGNIFIGANT SKIN
PERMEATION & SYSTEMIC TOXICITY, AFTER SKIN CONTACT SEEMS UNLIKELY.
THERE ARE NO REPORTS OF HUMAN SENSITIZATION. DIURON: SKIN
IRRITATION WITH DISCOMFORT OR RASH. EYE IRRITATION WITH DISCOMFORT
, TEARING, OR BLURRING OF VISION; LIVER ENLARGEMENT ; SPLEEN AND
THYROID EFFECTS; RED BLOOD CELL DESTRUCTION; OR REDUCTION OF THE
BLOOD'S OXYGEN CARRYING CAPACITY. SIGNIFIGANT SKIN PERMEATION AFTER
CONTACT SEEMS UNLIKELY. THERE ARE NO REPORTS OF HUMAN
SENSITIZATION.
Explanation of Carcinogenicity:NONE OF THE COMPONENTS PRESENT IN THIS
MATERIAL AT CONCENTRATIONS EQUAL TO OR GREATER THAN 0.1% ARE LISTED
BY IARC, NTP, OSHA OR ACGIH AS A CARCINOGEN.
Effects of Overexposure:BROMOCIL: SKIN CONTACT MAY INITIALLY CAUSE
IRRITATION OR RASH. EYE CONTACT MAY INITIALLY INCLUDE IRRITATION,
TEARING OR BLURRING OF VISION. DIURON: SKIN IRRITATION WITH
DISCOMFORT OR RASH. EYE IRRITAT ION WITH DISCOMFORT , TEARING, OR
BLURRING OF VISION; LIVER ENLARGEMENT; SPLEEN AND THYROID EFFECTS;
RED BLOOD CELL DESTRUCTION; OR REDUCTION OF THE BLOOD'S OXYGEN
CARRYING CAPACITY (CAUSING CYANOSIS OR BLUE-TINTED SKIN).
Medical Cond Aggravated by Exposure:NOT PROVIDED BY MANUFACTURER

First Aid:INHALATION: IF INHALED, REMOVE TO FRESH AIR. IF NOT
BREATHING, GIVE ARTIFICIAL RESPIRATION. IF BREATHING IS DIFFICULT,
GIVE OXYGEN. CALL A PHYSICIAN. SKIN: IN CASE OF CONTACT,
IMMEDIATELY WASH SKIN WI TH SOAP AND WATER. WASH CONTAMINATED
CLOTHING BEFORE REUSE. EYE: IN CASE OF CONTACT, IMMEDIATELY FLUSH
EYES WITH PLENTY OF WATER FOR AT LEAST 15 MINUTES. CALL A
PHYSICIAN. INGESTION: IF SWALLOWED, IMM EDIATELY GIVE 2 GLASSES OF
WATER AND INDUCE VOMITING. NEVER GIVE ANYTHING BY MOUTH TO AN
UNCONSCIOUS PERSON. CALL A PHYSICIAN.

Autoignition Temp:=420.C, 788.F
Lower Limits:0.135 G/L
Extinguishing Media:WATER SPRAY, FOAM, DRY CHEMICAL, CO2.
Fire Fighting Procedures:WEAR SELF-CONTAED BREATHING APPARATUS. WEAR
FULL PROTECITVE EQUIPMENT. USE WATER SPRAY. RUNOFF FROM FIRE
CONTROL MAY BE A POLLUTION HAZARD. IF AREA IS HEAVILY EXPOSED TO
FIRE AND IF CONDITIONS PERMIT . LET FIRE BURN ITSELF OUT SINCE
WATER MAY INCREASE THE CONTAMINATION HAZARD.
Unusual Fire/Explosion Hazard:MAY BE IGNITED BY HEAT OR OPEN FLAME.
LIKE MOST ORGANIC POWDERS OR CRYSTALS, UNDER SEVERE DUSTING
CONDITIONS, THIS MATERIAL MAY FORM EXPLOSIVE MIXTURES IN AIR.

Spill Release Procedures:NOTE: REVIEW FIRE FIGHTING MEASURES AND
HANDLING (PERSONNEL) SECTIONS BEFORE PROCEEDING WITH CLEAN-UP. USE
APPROPRIATE PERSONAL PROTECTIVE EQUIPMENT DURING CLEAN-UP. SHOVEL
OR SWEEP UP. NEVER RETURN T O CONTAINER FOR REUSE. SCOOP INTO BAGS
OR BOXES WITH PLASTIC OR ALUMINUM SHOVEL. IF SPILL AREA IS ON
GROUND NEAR VALUABLE PLANTS OR TREES, REMOVE TOP 2 INCHES OF SOIL
AFTER INITIAL CLEAN UP.
Neutralizing Agent:NOT PROVIDED BY MANUFACTURER

Handling and Storage Precautions:HANDLING: AVOID BREATHING VAPORS OR
MIST AVOID BREATHING DUST. AVOID CONTACT WITH EYES, SKIN, OR
CLOTHING. WASH THOROUGHLY AFTER HANDLING. WASH CLOTHING AFTER USE.
DO NOT STORE OR CONSUME FOOD, DRINK OR TOBACCO IN AREAS WHERE THEY
MAY BECOME CONTAMINATED WITH WHIS MATERIAL. USERS SHOULD: WASH
HANDS
Other Precautions:HANDLING CONTINUED: BEFORE EATING, DRINKING, CHEWING
GUM, USING TABACCO OR USING THE TOILET. STORAGE: STORE IN A WELL
VENTILATED PLACE. KEEP CONTAINER TIGHTLY CLOSED. DO NOT STORE OR
CONSUME FOOD, DRI NK OR TOBACCO IN AREAS WHERE THEY MAY BECOME
CONTAMINATED WITH THIS MATERIAL.

Respiratory Protection:USE ONLY WITH ADEQUATE VENTILATION. KEEP
CONTAINER TIGHTLY CLOSED. ALWAYS FOLLOW LABEL INSTRUCTIONS WHEN
USING THIS PRODUCT.
Ventilation:USE ONLY WITH ADEQUATE VENTILATION.
Protective Gloves:WATERPROOF GLOVES.
Other Protective Equipment:LONG-SLEEVED SHIRT AND LONG PANTS, SHOES
PLUS SOCKS, COVERALLS.
Work Hygienic Practices:DO NOT STORE OR CONSUME FOOD, DRINK OR TOBACCO
IN AREAS WHERE THEY MAY BECOME CONTAMINATED WITH THIS MATERIAL.
Supplemental Safety and Health
USERS SHOULD: WASH HANDS BEFORE EATING, DRINKING, CHEWING GUM, USING
TABACCO OR USING THE TOILET.

HCC:T5
Solubility in Water:DISPERSIBLE
Appearance and Odor:BROWN SOLID, NO ODOR.

Stability Indicator/Materials to Avoid:YES
NONE REASONABLY FORESEEABLE.
Stability Condition to Avoid:STABLE AT NORMAL TEMPRATURES AND STORAGE
CONDITIONS.
Conditions to Avoid Polymerization:POLYMERIZATION WILL NOT OCCUR.

Waste Disposal Methods:TREATMENT, STORAGE, TRANSPORTATION, AND DISPOSAL
MUST BE IN ACCORDANCE WITH APPLICABLE FEDERAL, STATE/PROVINCIAL,
AND LOCAL REGULATIONS. REMOVE NONUSABLE SOLID MATERIAL AND/OR
CONTAMINATED SOIL, FOR D ISPOSAL IN AN APPROVED AND PERMITTED
LANDFILL. DO NOT FLUSH TO SURFACE WATER OR SANITARY SEWER SYSTE M.

Toxicological Information:CHRONIC STUDIES (BROMOCIL): THE COMPOUND IS A
MODERATE SKIN IRRITANT, IS A MILD TO MODERATE EYE IRRITANT, BUT IS
NOT A SKIN SENSITIZER. RABBITS ACUTELY EXPOSED VIA DERMAL ROUTE
DEMONSTATED NO CLINICAL SIGNS OF TOXICITY, AND NO GROSS TISSUE
CHANGES WERE OBSERVED, AT THE HIGHEST DOSE, 5,000 MG/KG. CHRONIC
STUDIES (DIURON): THE COMPOUNB IS A SKIN IRRITANT, IS AN EYE
IRRITANT AND IS NOT A SKIN SENSITI ZER IN ANIMALS. TOXIC EFFECTS
DESCRIBED IN ANIMALS FROM SHORT EXPOSURES BY INHALATION, INGESTION
OR SKIN CONTACT INCLUDE: BLOOD EFFECTS, SPLEEN EFFECTS, THYROID
EFFECTS, METHEMGLOBINEMIA.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.

Ecological:THIS PRODUCT IS REGISTERED AND CONTROLLED UNDER EPA/FIFRA.
EPA REGISTRY NUMBER: 352-505.

Transport Information:DOT/IMO PROPER SHIPPING NAME: NOT REGULATED *
*IF 100 POUNDS OF DIURON OR MORE PER PKG: OTHER REGULATED
SUBSTANCE, LIQUID, N.O.S. (DIURON), 9, NA3082, PG III. (NOTE FROM
DLA-HMIS STAFF THIS IS NOT TH E CASE FOR THIS NSN WHICH CONTAINS 6
LBS OF PRODUCT, NET WEIGHT).

SARA Title III Information:TITLE III SARA, SECTION 311/312 HAZARD
CLASSIFICATION SYSTEM: ACUTE-YES; CHRONIC-YES; FIRE-NO;
REACTIVITY-NO; PRESSURE; NO. SARA/CERCLA REPORTABLE QUANTITY:
DIURON (100 LBS).
Federal Regulatory Information:NOT PROVIDED BY MANUFACTURER
State Regulatory Information:NOT PROVIDED BY MANUFACTURER