Product ID:WKG SOL,KODAK K-LAB FIRST DEVELOPER (SEE SUPPL DATA)
MSDS Date:05/29/1998
FSC:NIIN:Submitter:D DG
Status Code:A
MSDS Number: CKVPH

EASTMAN KODAK COMPANY

343 STATE STREET
ROCHESTER, NY 14650
US

Emergency Phone: 716 722-5151

Info Phone: 716-722-5151/(800) 242-2424

Preparer: NOT PROVIDED

Cage: 19139

EASTMAN KODAK CO GOVERNMENT MARKETS CONTRACTS

ROCHESTER, NY 14650-1115 US

Telephone: 716-722-5151/(800) 242-2424

Cage: 19139

WATER

CAS: 7732-18-5

RTECS: ZC0110000

SODIUM SULFITE

CAS: 7757-83-7

RTECS: WE2150000

OSHA PEL NOT PROVIDED

ACGIH TLV: NOT PROVIDED

SODIUM CARBONATE

CAS: 497-19-8

RTECS: VZ4050000

OSHA PEL NOT PROVIDED

ACGIH TLV: NOT PROVIDED

SODIUM BICARBONATE

CAS: 144-55-8

RTECS: VZ0950000

OSHA PEL NOT PROVIDED

ACGIH TLV: NOT PROVIDED

HYDROQUINONE

CAS: 123-31-9

RTECS: MX3500000

OSHA PEL 2 MG/M3

ACGIH TLV: 2 MG/M3

EPA Report Quantity: 1 LB

DOT Report Quantity: 1 LB

LD50 LC50 Mixture:NOT PROVIDED
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:EFFECTS OF EXPOSURE: INHALATION:
EXPECTED TO BE A LOW HAZARD FOR RECOMMENDED HANDLING. IN CONTACT
WITH STRONG ACIDS OR IF HEATED, SULFITES MAY LIBERATE SULFUR
DIOXIDE GAS. SULFUR DIOXIDE GAS IS IRRIT ATING TO THE RESPIRATORY
TRACT. SOME ASTHMATICS OR HYPERSENSITIVE INDIVIDUALS MAY
EXPERIENCE DIFFICULT BREATHING. EYES: CAUSES IRRITATION. SKIN: MAY
CAUSE ALLERGIC SKIN REACTION. INGESTION: MAY BE HARMFUL IF
SWALLOWED. SOME ASTHMATICS OR SULFITE-SENSITIVE INDIVIDUALS MAY
EXPERIENCE WHEEZING, CHEST TIGHTNESS, STOMACH UPSET, HIVES,
FAINTNESS, WEAKNESS AND DIARRHEA.
Explanation of Carcinogenicity:CARCINOGENICITY CLASSIFICATION
(COMPONENTS PRESENT AT 0.1% OR MORE): - INTERNATIONAL AGENCY FOR
RESEARCH ON CANCER (IARC): NONE - AMERICAN CONFERENCE OF
GOVERNMENTAL INDUSTRIAL HYGIENISTS (ACGIH): NON E - NATIONAL
TOXICOLOGY PROGRAM (NTP): NONE - OCCUPATIONAL SAFETY AND HEALTH
ADMINISTRATION (OSHA): NONE
Effects of Overexposure:INHALATION: IN CONTACT WITH STRONG ACIDS OR IF
HEATED, SULFITES MAY LIBERATE SULFUR DIOXIDE GAS. SULFUR DIOXIDE
GAS IS IRRITATING TO THE RESPIRATORY TRACT. SOME ASTHMATICS OR
HYPERSENSITIVE INDIVIDUA LS MAY EXPERIENCE DIFFICULT BREATHING.
EYES: CAUSES IRRITATION. SKIN: MAY CAUSE ALLERGIC SKIN REACTION.
INGESTION: SOME ASTHMATICS OR SULFITE-SENSITIVE INDIVIDUALS MAY
EXPERIENCE WHEEZING, CHEST TIGHT NESS, STOMACH UPSET, HIVES,
FAINTNESS, WEAKNESS AND DIARRHEA.
Medical Cond Aggravated by Exposure:SOME ASTHMATICS, HYPERSENSITIVE OR
SULFITE-SENSITIVE INDIVIDUALS MAY EXPERIENCE DIFFICULT BREATHING,
WHEEZING, CHEST TIGHTNESS, STOMACH UPSET, HIVES, FAINTNESS,
WEAKNESS AND DIARRHEA.

First Aid:INHALATION: IF SYMPTOMATIC, MOVE TO FRESH AIR. TREAT
SYMPTOMATICALLY. GET MEDICAL ATTENTION IF SYMPTOMS PERSIST. EYES:
IMMEDIATELY FLUSH WITH PLENTY OF WATER FOR AT LEAST 15 MINUTES. GET
MEDICAL ATTEN TION IF SYMPTOMS OCCUR. SKIN: IMMEDIATELY REMOVE
CONTAMINATED CLOTHING AND SHOES AND WASH WITH SOAP AND PLENTY OF
WATER. GET MEDICAL ATTENTION IF SYMPTOMS OCCUR. WASH CONTAMINATED
CLOTHING BEFORE REU SE. DESTROY OR THOROUGHLY CLEAN CONTAMINATED
SHOES. INGESTION: DRINK 1-2 GLASSES OF WATER. SEEK MEDICAL
ATTENTION. NEVER GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS PERSON.

Flash Point:NONE
Extinguishing Media:USE APPROPRIATE AGENT FOR ADJACENT FIRE.
Fire Fighting Procedures:WEAR SELF-CONTAINED BREATHING APPARATUS AND
PROTECTIVE CLOTHING. FIRE OR EXCESSIVE HEAT MAY PRODUCE HAZARDOUS
DECOMPOSITION PRODUCTS.
Unusual Fire/Explosion Hazard:NONE

Spill Release Procedures:FLUSH TO SEWER WITH LARGE AMOUNTS OF WATER.
OTHERWISE, ABSORB SPILL WITH VERMICULITE OR OTHER INERT MATERIAL,
THEN PLACE IN A CONTAINER FOR CHEMICAL WASTE. CLEAN SURFACE
THOROUGHLY TO REMOVE RESIDUAL CONTAMINATION.
Neutralizing Agent:NOT PROVIDED

Handling and Storage Precautions:KEEP CONTAINER CLOSED. KEEP AWAY FROM
INCOMPATIBLE SUBSTANCES (SEE INCOMPATIBILITY SECTION)
Other Precautions:AVOID BREATHING MIST OR VAPOR. AVOID CONTACT WITH
EYES, SKIN, AND CLOTHING. USE WITH ADEQUATE VENTILATION. WASH
THOROUGHLY AFTER HANDLING. THE ROUTINE USE OF A NONALKALINE (ACID)
TYPE OF HAND CLEANER AND REGULAR CLEANING OF WORKING SURFACES,
GLOVES, ETC. WILL HELP MINIMIZE THE POSSIBILITY OF A SKIN
REACTION.

Respiratory Protection:NONE SHOULD BE NEEDED. A RESPIRATOR SHOULD BE
WORN IF HAZARDOUS DECOMPOSITION PRODUCTS ARE LIKELY TO BE OR HAVE
BEEN RELEASED. RESPIRATOR TYPE: ACID GAS. SEE STABILITY AND
REACTIVITY SECTION. IF RESP IRATORS ARE USED, A PROGRAM SHOULD BE
INSTITUTED TO ASSURE COMPLIANCE WITH OSHA STANDARD 29 CFR 1910.134.
Ventilation:GOOD GENERAL VENTILATION (TYPICALLY 10 AIR CHANGES PER
HOUR) SHOULD BE USED. VENTILATION RATES SHOULD BE MATCHED TO
CONDITIONS.
Protective Gloves:WEAR IMPERVIOUS GLOVES AND PROTECTIVE CLOTHING
APPROPRIATE FOR RISK OF EXPOSURE
Eye Protection:WEAR SAFETY GLASSES WITH SIDE SHIELDS (OR GOGGLES).
Other Protective Equipment:EYE BATH, WASHING FACILITIES, SAFETY SHOWER
Work Hygienic Practices:NOT PROVIDED
Supplemental Safety and Health
CONTINUED FROM PRODUCT ID: REPLENISHER, PROCESS K-14M. WORKING
SOLUTION: CONTAINS PCD 6047; PCD 6056; PCD 6071(PART A, PART B, AND
PART C).

HCC:B3
NRC/State Lic Num:NOT RELEVANT
Boiling Pt:>100.C, 212.F
Melt/Freeze Pt:M.P/F.P Text:NOT PROVIDED
Decomp Temp:Decomp Text:NOT PROVIDED
Vapor Pres:(68F): 24 MBAR (18 MM HG)
Vapor Density:0.6
Spec Gravity:1.06-1.07
pH:9.6-9.8
Viscosity:NOT PROVIDED
Evaporation Rate & Reference:NOT PROVIDED
Solubility in Water:COMPLETE
Appearance and Odor:COLORLESS, ODORLESS, LIQUID.
Percent Volatiles by Volume:90-95 WT
Corrosion Rate:NOT PROVIDED

Stability Indicator/Materials to Avoid:YES
STRONG ACIDS
Stability Condition to Avoid:NOT PROVIDED
Hazardous Decomposition Products:SULFUR DIOXIDE

Waste Disposal Methods:DISCHARGE, TREATMENT, OR DISPOSAL MAY BE SUBJECT
TO NATIONAL, STATE, OR LOCAL LAWS. FLUSH TO SEWER WITH LARGE
AMOUNTS OF WATER. SINCE EMPTIED CONTAINERS RETAIN PRODUCT RESIDUE,
FOLLOW LABEL WARNINGS E VEN AFTER CONTAINER IS EMPTIED.

Toxicological Information:EFFECTS OF EXPOSURE: INHALATION: EXPECTED TO
BE A LOW HAZARD FOR RECOMMENDED HANDLING. IN CONTACT WITH STRONG
ACIDS OR IF HEATED, SULFITES MAY LIBERATE SULFUR DIOXIDE GAS.
SULFUR DIOXIDE GAS IS IRRIT ATING TO THE RESPIRATORY TRACT. SOME
ASTHMATICS OR HYPERSENSITIVE INDIVIDUALS MAY EXPERIENCE DIFFICULT
BREATHING. EYES: CAUSES IRRITATION. SKIN: MAY CAUSE ALLERGIC SKIN
REACTION. INGESTION: MAY BE HAR MFUL IF SWALLOWED. SOME ASTHMATICS
OR SULFITE-SENSITIVE INDIVIDUALS MAY EXPERIENCE WHEEZING, CHEST
TIGHTNESS, STOMACH UPSET, HIVES, FAINTNESS, WEAKNESS AND DIARRHEA.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.

Ecological:IT IS EXPECTED TO HAVE THE FOLLOWING PROPERTIES: A LOW
BIOCHEMICAL OXYGEN DEMAND AND LITTLE POTENTIAL TO CAUSE OXYGEN
DEPLETION IN AQUEOUS SYSTEMS, A HIGH POTENTIAL TO AFFECT SOME
AQUATIC ORGANISMS, A LOW POTENTIAL TO AFFECT SECONDARY WASTE
TREATMENT MICROBIAL METABOLISM, A LOW POTENTIAL TO AFFECT THE
GERMINATION AND/OR EARLY GROWTH OF SOME PLANTS, A LOW POTENTIAL TO
PERSIST IN THE ENVIRONMEN T, A LOW POTENTIAL TO BIOCONCENTRATE.
AFTER DILUTION WITH A LARGE AMOUNT OF WATER, FOLLOWED BY SECONDARY
WASTE TREATMENT, THIS MATERIAL IS NOT EXPECTED TO CAUSE ADVERSE
ENVIRONMENTAL EFFECTS.

Transport Information:FOR TRANSPORTATION INFORMATION REGARDING THIS
PRODUCT CALL THE KODAK WORLDWIDE TRANSPORTATION HAZMAT HOT LINE:
(716) 722-2400 BETWEEN 8 A.M. AND 5 P.M. (EASTERN STANDARD TIME),
MONDAY THROUGH FRIDAY .

SARA Title III Information:CHEMICAL(S) SUBJECT TO THE REPORTING
REQUIREMENTS OF SECTION 313 OR TITLE III OF THE SUPERFUND
AMENDMENTS AND REAUTHORIZATION ACT (SARA) OF 1986 AND 40 CFR
PART 372: NONE
Federal Regulatory Information:NOT PROVIDED
State Regulatory Information:MATERIAL(S) KNOWN TO THE STATE OF
CALIFORNIA TO CAUSE CANCER: NONE - MATERIAL(S) KNOWN TO THE STATE
OF CALIFORNIA TO CAUSE ADVERSE REPRODUCTIVE EFFECTS: NONE