Product ID:SODIUM BISULFATE MONOHYDRATE
MSDS Date:09/30/1997
FSC:NIIN:Submitter:D DG
Status Code:A
MSDS Number: CKVXR

Emergency Phone: 201-796-7100

Info Phone: 201-796-7100

Cage: 1B464

Telephone: 201-796-7100

Cage: 1B464

SODIUM BISULFATE MONOHYDRATE

CAS: 10034-88-5

RTECS: VZ1870000

LD50 LC50 Mixture:NOT AVAILABLE.
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:ACUTE: EYES: CAUSES EYE BURNS. SKIN:
CONTACT WITH SKIN CAUSES IRRITATION AND POSSIBLE BURNS, ESPECIALLY
IF THE SKIN IS WET OR MOIST. INGESTION: MAY CAUSE SEVERE
GASTROINTESTINAL TRACT IRRITATION WITH NAUSEA, VOMITING, AND
POSSIBLE BURNS. INHALATION: CAUSES SEVERE IRRITATION OF UPPER
RESPIRATORY TRACT WITH COUGHING, BURNS, BREATHING DIFFICULTY, AND
POSSIBLE COMA. CAUSES CHEMICAL BURNS TO THE RESPIR ATORY TRACT.
CHRONIC: CHRONIC INHALATION AND INGESTION MAY CAUSE EFFECTS SIMILAR
TO THOSE OF ACUTE INHALATION AND INGESTION.
Explanation of Carcinogenicity:NOT LISTED BY ACGIH, IARC, NTP, OR OSHA.
Effects of Overexposure:EYES: BURNS. SKIN: IRRITATION, BURNS.
INGESTION: SEVERE GI TRACT IRRITATION, NAUSEA, VOMITING, BURNS.
INHALATION: SEVERE IRRITATION OF UPPER RESPIRATORY TRACT, COUGHING,
BURNS, BREATHING DIFFICULTY, C OMA, CHEMICAL BURNS TO RESPIRATORY
TRACT.

First Aid:EYES: IMMEDIATELY FLUSH WITH PLENTY OF WATER FOR AT LEAST 15
MINUTES, OCCASIONALLY LIFTING UPPER AND LOWER EYELIDS. GET MEDICAL
AID IMMEDIATELY. SKIN: GET MEDICAL AID IMMEDIATELY. FLUSH WITH
PLENTY OF SOAP AND WATER FOR AT LEAST 15 MINUTES WHILE REMOVING
CONTAMINATED CLOTHING AND SHOES. SPEEDY ACTION IS CRITICAL.
INGESTION: DO NOT INDUCE VOMITING. IF VICTIM IS CONSCIOUS AND
ALERT, GIVE 2-4 CUPFU LS OF MILK OR WATER. GET MEDICAL AID
IMMEDIATELY. INHALATION: GET MEDICAL AID IMMEDIATELY. REMOVE FROM
EXPOSURE TO FRESH AIR IMMEDIATELY. IF NOT BREATHING, GIVE
ARTIFICIAL RESPIRATION. IF BREATHING IS DIFFICULT, GIVE OXYGEN.

Flash Point:NOT AVAILABLE
Extinguishing Media:DO NOT USE WATER DIRECTLY ON FIRE. USE WATER SPRAY
TO COOL FIRE-EXPOSED CONTAINERS. USE DRY CHEMICAL TO FIGHT FIRE.
Fire Fighting Procedures:WEAR APPROPRIATE PROTECTIVE CLOTHING TO
PREVENT CONTACT WITH SKIN AND EYES. WEAR A SELF-CONTAINED BREATHING
APPARATUS (SCBA) TO PREVENT CONTACT WITH THERMAL DECOMPOSITION
PRODUCTS.
Unusual Fire/Explosion Hazard:CONTACT WITH WATER CAN CAUSE VIOLENT
LIBERATION OF HEAT AND SPLATTERING OF THE MATERIAL.

Spill Release Procedures:USE PROPER PERSONAL PROTECTIVE EQUIPMENT.
VACUUM OR SWEEP UP MATERIAL AND PLACE INTO A SUITABLE DISPOSAL
CONTAINER. CLEAN UP SPILLS IMMEDIATELY, OBSERVING ALL PRECAUTIONS
IN THE MSDS.

Handling and Storage Precautions:HANDLING: WASH THOROUGHLY AFTER
HANDLING. REMOVE CONTAMINATED CLOTHING AND WASH BEFORE REUSE. DO
NOT GET INTO EYES, ON SKIN, OR ON CLOTHING. KEEP CONTAINER TIGHTLY
CLOSED. DO NOT ALLOW CONTACT WITH WA TER. USE ONLY IN A CHEMICAL
FUME HOOD.
Other Precautions:STORAGE: KEEPCONTAINER CLOSED WHEN NOT INUSE. STORE
IN A COOL, DRY, WELL-VENTILATED AREA AWAY FROM INCOMPATIBLE
SUBSTANCES. DO NOT STORE NEAR ALKALINE SUBSTANCES.

Respiratory Protection:FOLLOW THE OSHA RESPIRATOR REGULATIONS FOUND IN
29 CFR 1910.134 OR EUROPEAN STANDARD EN 149. ALWAYS USE A NIOSH OR
EUROPEAN STANDARD EN 149 APPROVED RESPIRATOR WHEN NECESSARY.
Ventilation:USE PROCESS ENCLOSURE, LOCAL EXHAUST VENTILATION, OR OTHER
ENGINEERING CONTROLS TO CONTROL AIRBORNE LEVELS BELOW RECOMMENDED
EXPOSURE LIMITS.
Protective Gloves:WEAR APPROPRIATE GLOVES TO PREVENT SKIN EXPOSURE.
Eye Protection:WEAR PROTECTIVE EYEGLASSES OR CHEMICAL SAFETY GOGGLES,
AND FACE PROTECTION.
Other Protective Equipment:WEAR APPROPRIATE PROTECTIVE CLOTHING TO
PREVENT SKIN EXPOSURE.
Work Hygienic Practices:WEAR APPRPRIATE PROTECTIVE EYEGLASSES OR
CHEMICAL SAFETY GOGGLES AS DESCRIBED BY OSHA'S EYE AND FACE
PROTECTION REGULATIONS IN 29 CFR 1910.133 OR EUROPEAN STANDARD
EN166.
Supplemental Safety and Health
SYNONYMS: SODIUM HYDROGEN SULFATE. CATALOG NOS: S80175, S240 3, S240
500, S240-3, S240-500, S2403, S240500

HCC:C1
Boiling Pt:B.P. Text:DECOMPOSES
Melt/Freeze Pt:=58.5C, 137.3F
Decomp Temp:Decomp Text:NOT AVAILABLE.
Spec Gravity:2.103 @ 13C.
pH:1.4 (0.1 SOL)
Viscosity:NOT APPLICABLE.
Evaporation Rate & Reference:NOT APPLICABLE.
Solubility in Water:67%
Appearance and Odor:SOLID, COLOURLESS; ODORLESS.

Stability Indicator/Materials to Avoid:YES
INCOMPATIBLE MATERIALS, CALCIUM HYPOCHLORITE, MOISTURE, WATER.
Stability Condition to Avoid:STABLE UNDER NORMAL TEMPERATURES AND
PRESSURES. AVOID INCOMPATIBLE MATERIALS, MOISTURE, CONTACT WITH
WATER.
Hazardous Decomposition Products:OXIDES OF SULFUR.
Conditions to Avoid Polymerization:HAS NOT BEEN REPORTED.

Waste Disposal Methods:DISPOSE OF IN A MANNER CONSISTENT WITH FEDERAL,
STATE, AND LOCAL REGULATIONS. RCRA P-SERIES: NONE LISTED. RCRA
U-SERIES: NONE LISTED.

Toxicological Information:LD50 / LC50: NOT AVAILABLE. CARCINOGENICITY:
SODIUM BISULFATE MONOHYDRATE: NOTLISTED BY ACGIH, IARC, NIOSH, OR
OSHA. EPIDEMIOLOGY: WORKERS EXPOSED TO INDUSTRIAL SULFURIC ACID
MIST SHOWED A STSTISTICAL INCREASE IN LARNGEAL CANCER. THIS DATA
SUGGESTS A POSSIBLE RELATIONSHIP BETWEEN CARCINOGENISIS AND
INHALATION OF SULFURIC ACID MIST. NO DATA AVAILABLE FOR FOLLOWING:
TERATOGENICITY, REPRODUCTIVE EFFE CTS, NEUROTOXICITY, MUTAGENICITY,
OTHER STUDIES.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.

Ecological:ECOTOXICITY: SULFURIC ACID IS HARMFUL TO AQUATIC LIFE IN
VERY LOW CONCENTRATIONS. IT MAY BE DANGEROUS IF IT ENTERS WATER
INTAKES. THE AQUATIC TOXICITY FOR BLUEGILL IN FRESH WATER WAS 24.5
PPM / 24 HR, WHICH WAS LETHAL. ENVIRONMENTAL FATE: NOT AVAILABLE.
PHYSICAL / CHEMICAL: NOT AVAILABLE. OTHER: NOT AVAILABLE. RCRA
P-SERIES: NONE LISTED. RCRA U-SERIES: NONE LISTED. CLEAN AIR ACT:
THIS MATERIAL DOE S NOT CONTAIN ANY HAZARDOUS AIR POLLUTANTS, NOR
ANY CLASS 1 OZONE DEPLETORS, NOR ANY CLASS 2 OZONE DEPLETORS. OSHA:
NONE OF THE CHEMICALS IN THIS PRODUCT ARE CONSIDERED HIGHLY
HAZARDOUS BY OSHA. (CON TINUED TO REGULATORY STATE).

Transport Information:US DOT: NO INFORMATION AVAILABLE. IMO: SHIPPING
NAME: CORROSIVE SOLID, NOS; HAZARD CLASS: 8;UN 1759; PACKING GROUP
I I. IATA: SHIPPING NAME: CORROSIVE SOLID, NOS; HAZARD CLASS: 8;
UN 1759; PACKING GR OUP: I I. RID/ADR: SHIPPING NAME: CORROSIVE
SOLID, NOS; DANGEROUS GOODS CODE: 8; UN 1759. CANADIAN TGD:
SHIPPING NAME: CORROSIVE SOLID NOS (SODIUM BISULFATE); HAZARD
CLASS: 8 (9.2); UN 1759.

SARA Title III Information:SARA: SECTION 302 (RQ): NONE OF THE
CHEMICALS IN THIS MATERIAL HAVE AN RQ. SECTION 302 (TPQ): NONE OF
THE CHEMICALS IN THIS PRODUCT HAVE A TPQ. SARA CODES: CAS#
10034-88-5: ACUTE, REACTIVE. SECTION 31 3: NO CHEMICALS ARE
REPORTABLE UNDER SECTION 313. CANADA: THIS PRODUCT HAS A WHMIS
CLASSIFICATION OF E. CAS# 10034-88-5 IS NOT LISTED ON CANADA'S
INGREDIENT DISCLOSURE LIST.
Federal Regulatory Information:TSCA: CAS# 10034-88-5 IS NOT ON THE TSCA
INVENTORY. IT IS A HYDRATE AND EXEMPT FROM TSCA INVENTORY
REQUIREMENTS (40 CFR 720.3(U)(2). HEALTH & SAFETY REPORTING LIST:
NONE OF THE CHEMICALS ARE ON THE HE ALTH & SAFETY REPORTING LIST.
CHEMICAL TEST RULES: NONE OF THE CHEMICALS IN THIS PRODUCT ARE
UNDER A CHEMICAL TEST RULE. SECTION 12B: NONE OF THE CHEMICALS ARE
LISTED UNDER TSCA SECTION 12B. TSCA SIGN IFICANT NEW RULE: NONE OF
THE CHEMICALS IN THIS MATERIAL HAVE A SNUR UNDER TSCA.
State Regulatory Information:(CONTD FROM ECOLOGICAL) CLEAN WATER ACT:
NONE OF THE CHEMICALS IN THIS PRODUCT ARE LISTED AS HAZARDOUS
SUBSTANCES UNDER THE CWA. NONE OF THE CHEMICALS IN THIS PRODUCT ARE
LISTED AS PRIORITY POLLUTANT S UNDR THE CWA. NONE OF THE CHEMICALS
INTHIS PRODUCT ARE LISTED AS TOXIC POLLUTANTS UNDER THE CWA. STATE
REGULATORY INFORMATION:SODIUM BISULFATE MONOHYDRATE IS NOT PRESENT
ON STATE LISTS FROM CA, PA, MN, MA, FL, OR NJ. CALIFORNIA NO
SIGNIFICANT RISK LEVEL: NONE OF THE CHEMICALS IN THIS PRODUCT ARE L
ISTED.