Product ID:848 0246,KODAK STARMATE 500 TONER CARTRIDGE (SEE SUPPL DATA)
MSDS Date:08/06/1999
FSC:NIIN:Submitter:D DG
Status Code:A
Kit Part:Y
MSDS Number: CKWHF

EASTMAN KODAK COMPANY

343 STATE STREET
ROCHESTER, NY 14650
US

Emergency Phone: 716-722-5151

Info Phone: 800- 242-2424

Preparer: NOT PROVIDED

Cage: 19139

EASTMAN KODAK CO US CUSTOMER SERVICE/GOVERNMENT SALES

ROCHESTER, NY 14650-3129 US

Telephone: 800-828-6203

Cage: 5K871

STYRENE-ACRYLATE COPOLYMER

CAS: 27136-15-8

OSHA PEL NOT PROVIDED

ACGIH TLV: NOT PROVIDED

CARBON BLACK

CAS: 1333-86-4

RTECS: FF5800000

OSHA PEL 3.5 MG/M3

ACGIH TLV: 3.5 MG/M3

IRON OXIDE

CAS: 1309-37-1

RTECS: NO7400000

OSHA PEL 10 MG/M3

ACGIH TLV: 5 MG/M3;2 PPM

BIS(1-((2-HYDROXY-4-NITROPHENYL)AZO)-2-NAPHTHALENOLATO(2-))

CAS: 32517-36-5

OSHA PEL NOT PROVIDED

ACGIH TLV: NOT PROVIDED

LD50 LC50 Mixture:NOT PROVIDED
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:EFFECTS OF EXPOSURE: INHALATION:
EXPECTED TO BE A LOW HAZARD FOR RECOMMENDED HANDLING. EYES: NO
SPECIFIC HAZARD KNOWN. MAY CAUSE TRANSIENT IRRITATION. SKIN:
EXPECTED TO BE A LOW HAZARD FOR RECOMMENDE D HANDLING. INGESTION:
EXPECTED TO BE A LOW INGESTION HAZARD.
Explanation of Carcinogenicity:INTERNATIONAL AGENCY FOR RESEARCH ON
CANCER (IARC) (CARBON BLACK): 2B - AMERICAN CONFERENCE OF
GOVERNMENTAL INDUSTRIAL HYGIENISTS (ACGIH): CHROMIUM (III)
COMPOUNDS, NOT CLASSIFIABLE AS HUMAN CARCINOGE N (A4) IRON OXIDE,
NOT CLASSIFIABLE HUMAN CARCINOGEN (A4) - NATIONAL TOXICOLOGY
PROGRAM (NTP): NONE - OCCUPATIONAL SAFETY AND HEALTH ADMINISTRATION
(OSHA): NONE
Effects of Overexposure:EYES: MAY CAUSE TRANSIENT IRRITATION.
Medical Cond Aggravated by Exposure:NOT PROVIDED

First Aid:INHALATION: IF SYMPTOMATIC, MOVE TO FRESH AIR. GET MEDICAL
ATTENTION IF SYMPTOMS PERSIST. EYES: ANY MATERIAL THAT CONTACTS
THE EYE SHOULD BE WASHED OUT IMMEDIATELY WITH WATER. GET MEDICAL
ATTENTION I F SYMPTOMS OCCUR. SKIN: WASH WITH SOAP AND WATER. GET
MEDICAL ATTENTION IF SYMPTOMS OCCUR. INGESTION: DRINK 1-2 GLASSES
OF WATER. SEEK MEDICAL ATTENTION. NEVER GIVE ANYTHING BY MOUTH TO
AN UNCONSCIOU S PERSON.

Flash Point:NONE
Extinguishing Media:WATER SPRAY, CARBON DIOXIDE (CO2), DRY CHEMICAL
Fire Fighting Procedures:WEAR SELF-CONTAINED BREATHING APPARATUS AND
PROTECTIVE CLOTHING. FIRE OR EXCESSIVE HEAT MAY PRODUCE HAZARDOUS
DECOMPOSITION PRODUCTS.
Unusual Fire/Explosion Hazard:POWDERED MATERIAL MAY FORM EXPLOSIVE
DUST-AIR MIXTURES.

Spill Release Procedures:DO NOT USE A VACUUM CLEANER TO CLEAN UP SPILLS
OF POWDERED TONERS. THE VERY FINE PARTICLES CAN CAUSE A FIRE OR
EXPLOSION. SWEEP MATERIAL ONTO PAPER AND PLACE IN A FIBER CARTON.
AVOID GENERATING DUST. CLEAN SURFACE THOROUGHLY TO REMOVE RESIDUAL
CONTAMINATION.
Neutralizing Agent:NOT RELEVANT

Handling and Storage Precautions:KEEP CONTAINER CLOSED. POWDERED
MATERIAL MAY FORM EXPLOSIVE DUST-AIR MIXTURES. MINIMIZE DUST
GENERATION AND ACCUMULATION. USE WITH ADEQUATE VENTILATION. KEEP
AWAY FROM SOURCES OF IGNITION. KEEP FROM C ONTACT WITH OXIDIZING
MATERIALS.
Other Precautions:AVOID BREATHING DUST. AVOID CONTACT WITH EYES AND
PROLONGED OR REPEATED CONTACT WITH SKIN. USE WITH ADEQUATE
VENTILATION. WASH THOROUGHLY AFTER HANDLING. REFER TO NFPA
PAMPHLET NO. 654, "PREVENTION O F FIRE AND DUST EXPLOSIONS IN THE
CHEMICAL, DYE, PHARMACEUTICAL, AND PLASTICS INDUSTRIES."

Respiratory Protection:NONE SHOULD BE NEEDED.
Ventilation:GOOD GENERAL VENTILATION (TYPICALLY 10 AIR CHANGES PER
HOUR) SHOULD BE USED. VENTILATION RATES SHOULD BE MATCHED TO
CONDITIONS.
Protective Gloves:FOR PROLONGED OR REPEATED SKIN CONTACT: IMPERVIOUS
GLOVES SHOULD BE WORN.
Eye Protection:MINIMIZE EYE CONTACT
Other Protective Equipment:WASHING FACILITIES.
Work Hygienic Practices:IT IS A GOOD INDUSTRIAL HYGIENE PRACTICE TO
MINIMIZE EYE CONTACT.
Supplemental Safety and Health
CONTINUED FROM PRODUCT ID: KIT/BIMODE (BOTTLE OF TONER). ABBREVIATION:
N/A=NOT APPLICABLE OR NOT AVAILABLE. N/K=UNKNOWN. N/P=NOT PROVIDED.
N/R=NOT RELEVANT. N/D=NOT DETERMINED. N/E=NOT ESTABLISHED. CN
S=CENTRAL NERVOUS SYSTEM. GI=GASTROINTESTINAL.

HCC:N1
Melt/Freeze Pt:>150.C, 302.F
Decomp Temp:Decomp Text:NOT PROVIDED
Vapor Pres:NEGLIGIBLE
Vapor Density:NEGLIGIBLE
Spec Gravity:1.15
Solubility in Water:NEGLIGIBLE
Appearance and Odor:BLACK SOLID (POWDER). ODOR: ODORLESS.
Percent Volatiles by Volume:NEGLIGIBLE
Corrosion Rate:NOT PROVIDED

Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZING AGENTS.
Stability Condition to Avoid:NOT PROVIDED
Hazardous Decomposition Products:CARBON DIOXIDE, CARBON MONOXIDE,
OXIDES OF NITROGEN, OXIDES OF SULFUR

Waste Disposal Methods:INCINERATE OR LANDFILL. CAN BE LANDFILLED WHEN
IN COMPLIANCE WITH LOCAL REGULATIONS. DISCHARGE, TREATMENT, OR
DISPOSAL MAY BE SUBJECT TO NATIONAL, STATE, OR LOCAL LAWS.

Toxicological Information:IN 1996 THE INTERNATIONAL AGENCY FOR RESEARCH
ON CANCER (IARC) REEVALUATED CARBON BLACK AS A GROUP 2B
CARCINOGEN (POSSIBLE HUMAN CARCINOGEN), BASED UPON THE
DEVELOPMENT OF LUNG TUMORS IN RATS RE CEIVING CHRONIC INHALATION
EXPOSURES TO FREE CARBON BLACK. THE EFFECTS WERE OBSERVED ONLY IN
ANIMALS EXPOSED TO HIGH CONCENTRATIONS OF CARBON BLACK AT LEVELS
THAT INDUCE PARTICLE OVERLOAD OF THE LUNG.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.

Ecological:IT IS EXPECTED TO HAVE THE FOLLOWING PROPERTIES: A LOW
BIOCHEMICAL OXYGEN DEMAND AND LITTLE POTENTIAL TO CAUSE OXYGEN
DEPLETION IN AQUEOUS SYSTEMS, A MODERATE POTENTIAL TO AFFECT SOME
AQUATIC ORGANI SMS, A MODERATE POTENTIAL TO AFFECT THE GROWTH OF
SOME PLANT SEEDLINGS, A MODERATE POTENTIAL TO AFFECT ALGAL GROWTH,
A LOW POTENTIAL TO BIODEGRADE (HIGH PERSISTENCE) WITH UNACCLIMATED
MICROORGANISM S FROM ACTIVATED SLUDGE, A LOW POTENTIAL TO
BIOCONCENTRATE. AFTER DILUTION WITH A LARGE AMOUNT OF WATER,
FOLLOWED BY SECONDARY WASTE TREATMENT, THIS MATERIAL IS NOT
EXPECTED TO CAUSE ADVERSE ENVIRO NMENTAL EFFECTS.

Transport Information:FOR TRANSPORTATION INFORMATION REGARDING THIS
PRODUCT CALL THE KODAK WORLDWIDE TRANSPORTATION HAZMAT HOT LINE:
(716) 722-2400 BETWEEN 8 A.M. AND 5 P.M. (EASTERN STANDARD
TIME), MONDAY THROUGH FR IDAY.

SARA Title III Information:CHEMICAL(S) SUBJECT TO THE REPORTING
REQUIREMENTS OF SECTION 313 OR TITLE III OF THE SUPERFUND
AMENDMENTS AND REAUTHORIZATION ACT (SARA) OF 1986 AND 40 CFR
PART 372: BIS(1-((2-HYDROXY-4-NITROPHE
NYL)AZO)-2-NAPHTHALENOLATO(2-)) HYDROGEN CHROMATE(1-)
Federal Regulatory Information:NOT PROVIDED
State Regulatory Information:MATERIAL(S) KNOWN TO THE STATE OF
CALIFORNIA TO CAUSE CANCER: NONE - MATERIAL(S) KNOWN TO THE STATE
OF CALIFORNIA TO CAUSE ADVERSE REPRODUCTIVE EFFECTS: NONE