Product ID:EC-612
MSDS Date:08/26/1996
FSC:8030
NIIN:00-275-8114
Status Code:A
MSDS Number: CKXNJ

3M, INDUSTRIAL TAPE AND SPECIALTIES DIVISION

3M CENTER
ST PAUL, MN 55144-1000
US

Emergency Phone: 651-737-6501

Info Phone: 1-800-364-3577

Cage: 52152

MINNESOTA MINING & MFG CO INDUSTRIAL TAPE & SPECIALTIES

ST PAUL, MN 55144-1000 US

Telephone: 1-800-364-3577

Cage: 52152

POLYSULFIDE

CAS: 68611-48-3

OSHA PEL NONE ESTABLISHED

ACGIH TLV: NONE ESTABLISHED

CARBON BLACK

CAS: 1333-86-4

RTECS: FF5800000

OSHA PEL 3.5 MG/M3

ACGIH TLV: 3.5 MG/M3

ZINC OXIDE

CAS: 1314-13-2

RTECS: ZH4810000

OSHA PEL 10 MG/M3 D,5 MG/M3 F

ACGIH TLV: 10 MG/M3 D,5 MG/M3 F

2,2'-DITHIOBISBENZOTHIAZOLE

CAS: 120-78-5

RTECS: DL4550000

OSHA PEL NONE ESTABLISHED

ACGIH TLV: NONE ESTABLISHED

Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:YES OSHA:NO
Health Hazards Acute and Chronic:EYE CONTACT: MODERATE EYE IRRITATION:
SIGNS/SYMPTOMS CAN INCLUDE REDNESS, SWELLING, PAIN, TEARING, AND
HAZY VISION. SKIN CONTACT: MILD SKIN IRRITATION (AFTER PROLONGED OR
REPEATED CONTACT): SIGNS/SYMP TOMS CAN INCLUDE REDNESS, SWELLING,
AND ITCHING. INHALATION: IRRITATION (UPPER RESPIRATORY):
SIGNS/SYMPTOMS CAN INCLUDE SORENESS OF THE NOSE AND THROAT,
COUGHING AND SNEEZING. IF SWALLOWED: INGESTION MAY CAUSE:
IRRITATION OF GASTROINTESTINAL TISSUES: SIGNS/YMPTOMS CAN INCLUDE
PAIN, VOMITING, ABDOMINAL TENDERNESS, NAUSEA, BLOOD IN VOMITUS, AND
BLOOD IN FECES.
Explanation of Carcinogenicity:CARBON BLACK: IARC GROUP 2B, VOL 65, P.
149, 1996.

First Aid:EYE CONTACT: IMMEDIATELY FLUSH EYES WITH LARGE AMOUNTS OF
WATER. GET IMMEDIATE MEDICAL ATTENTION. SKIN CONTACT: FLUSH SKIN
WITH LARGE AMOUNTS OF WATER. IF IRRITATION PERSISTS, GET MEDICAL
ATTENTION. I NHALATION: IF SIGNS/SYMPTOMS OCCUR, REMOVE PERSON TO
FRESH AIR. IF SIGNS/SYMPTOMS CONTINUE, CALL A PHYSICIAN. IF
SWALLOWED: DO NOT INDUCE VOMITING. DRINK TWO GLASSES OF WATER. CALL
A PHYSICIAN.

Autoignition Temp:Autoignition Temp Text:N/D
Extinguishing Media:WATER, CARBON DIOXIDE, DRY CHEMICAL, FOAM.
Fire Fighting Procedures:WEAR FULL PROTECTIVE CLOTHING, INCLUDING
HELMET, SELF-CONTAINED, POSITIVE PRESSURE OR PRESSURE DEMAND
BREATHING APPARATUS (NIOSH APPROVED - ), BUNKER COAT AND PANTS,
BANDS AROUND ARMS, WAIST AND L EGS, FACE MASK, AND PROTECTIVE
COVERING FOR EXPOSED AREAS OF THE HEAD.
Unusual Fire/Explosion Hazard:NONE KNOWN.

Spill Release Procedures:OBSERVE PRECAUTIONS FORM OTHER SECTIONS.
VENTILATE AREA. COLLECT SPILLED MATERIAL. CLEAN UP RESIDUE WITH AN
APPROPRIATE ORGANIC SOLVENT. READ AND FOLLOW SAFETY PRECAUTIONS ON
THE SOLVENT LABEL AND MSD S. PLACE IN AN APPROVED METAL CONTAINER.
IN THE EVENT OF AN UNCONTROLLED RELEASE OF THIS MATERIAL, THE USER
SHOULD DETERMINE IF THE RELEASE QUALIFIES AS A REPORTABLE QUANTITY.

Handling and Storage Precautions:PREVENTION OF ACCIDENTAL INGESTION:
WASH HANDS AFTER HANDLING AND BEFORE EATING. DO NOT INGEST.
RECOMMENDED STORAGE: KEEP CONTAINER CLOSED WHEN NOT IN USE. KEEP
OUT OF THE REACH OF CHILDREN. FIR E AND EXPLOSION AVOIDANCE:
KEEP CONTAINER TIGHTLY CLOSED.

Respiratory Protection:AVOID BREATHING OF VAPORS CREATED DURING THE
CURE CYCLE. AVOID BREATHING OF DUST CREATED BY CUTTING, SANDING OR
GRINDING. SELECT ONE OF THE FOLLOWING NIOSH APPROVED RESPIRATORS
BASED ON AIRBORNE CONCE NTRATION OF CONTAMINANTS AND IN ACCORDANCE
WITH OSHA REGULATIONS: HALF-MASK DUST RESPIRATOR.
Ventilation:PROVIDE APPROPRIATE LOCAL EXHAUST FOR GRINDING, CUTTING OR
SANDING CURED MATERIAL. CURING OVENS MUST BE EXHAUSTED TO OUTDOORS
OR TO A (SUPP SAFETY & HEALTH)
Protective Gloves:WEAR APPROPRIATE GLOVES WHEN HANDLING THIS MATERIAL
(SUPPLEMEN SAFETY & HEALTH)
Eye Protection:WEAR VENTED GOGGLES (ANSI APPROVED - ).
Other Protective Equipment:EYEWASH AND DELUGE SHOWER MEETING ANSI
DESIGN CRITERIA .
Work Hygienic Practices:AVOID EYE CONTACT. WASH HANDS AFTER HANDLING
AND BEFORE EATING. DO NOT INGEST. AVOID PROLONGED OR REPEATED SKIN
CONTACT.
Supplemental Safety and Health
VENTILATION (CONT): SUITABLE EMISSION CONTROL DEVICE. IF EXHAUST IS
NOT ADEQUATE, USE APPROP RESP PROTECTION. GLOVES (CONT): A PAIR
OF GLOVES MADE FROM THE FOLLOWING MATERIAL(S) ARE RECOMMENDED:
POLYETHYLENE / ETHYLENE VINYL ALCOHOL, POLYVINYL ALCOHOL,
POLYTETRAFLUOROETHYLENE (TEFLON), OR FLUOROELASTOMER (VITON).

Melt/Freeze Pt:M.P/F.P Text:N/D
Spec Gravity:1.460 WATER=1.
Viscosity:PUTTY.
Solubility in Water:VERY SLIGHT.
Appearance and Odor:PUTTY, BLACK, STRONG SULFIDE ODOR.
Percent Volatiles by Volume:0.00% BY WT.

Stability Indicator/Materials to Avoid:YES
NOT APPLICABLE.
Hazardous Decomposition Products:CARBON MONOXIDE AND CARBON DIOXIDE,
OXIDES OF SULFUR, ALDEHYDES, KETONES, HYDROCARBONS, OXIDES OF ZINC,
HYDROGEN SULFIDE.

Waste Disposal Methods:INCINERATE UNCURED WASTE IN AN INDUSTRIAL OR
COMMERCIAL INCINERATOR. DISPOSE OF COMPLETELY CURED (OR
POLYMERIZED) MATERIAL IN A SANITARY LANDFILL. DISPOSE OF IN
ACCORDANCE WITH APPLICABLE FEDERAL, ST ATE AND LOCAL REGULATIONS .

Toxicological Information:SKIN NOTATION: LISTED SUBSTANCES INDICATED
WITH A "Y" UNDER SKIN REFER TO THE POTENTIAL CONTRIBUTION TO THE
OVERALL EXPOSURE BY THE CUTANEOUS ROUTE, INCLUDING MUCOUS MEMBRANE
AND EYE, EITHER BY AIRBOR NE OR, MORE PARTICULARY, BY DIRECT
CONTACT WITH THE SUBSTANCE. VEHICLES CAN ALTER SKIN ABSORPTION. (NO
SUBSTANCES INDICATED - ). EXPOSURE LIMITS: ZINC OXIDE: OSHA
PEL: 10 MG/M3 AS DUST, 5 MG/ M3 AS FUME; ACGIH TWA: 10 MG/M3 AS
DUST, 5 MG/M3 AS FUME.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.

Ecological:U.S. EPA HAZARDOUS WASTE NUMBER = NONE (NOT U.S. EPA
HAZARDOUS). ENVIRONMENTAL DATA: NOT DETERMINED.

SARA Title III Information:THIS PRODUCT CONTAINS THE FOLLOWING TOXIC
CHEMICAL SUBJECT TO THE REPORTING REQUIREMENTS OF SECTION 313 OF
TITLE III OF THE EMERGENCY PLANNING AND COMMUNITY RIGHT-TO-KNOW ACT
OF 1986 AND 40 CFR 372: Z INC OXIDE.
Federal Regulatory Information:VOLATILE ORGANIC COMPOUNDS: N/A. VOC
LESS H20 & EXEMPT SOLVENTS: N/A. SINCE REGULATIONS VARY, CONSULT
APPLICABLE REGULATIONS OR AUTHORITIES BEFORE DISPOSAL. IN THE
EVENT OF AN UNCONTROLLED RELEASE O F THIS MATERIAL, THE USER SHOULD
DETERMINE IF THE RELEASE QUALIFIES AS A REPORTABLE QUANTITY.
EPCRA HAZARD CLASS: FIRE HAZARD: NO. PRESSURE: NO. REACTIVITY: NO.
ACUTE: YES. CHRONIC: NO.